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41.
公开(公告)号:US20190330129A1
公开(公告)日:2019-10-31
申请号:US16271451
申请日:2019-02-08
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Tan-Jen Chen
Abstract: A process is described for producing paraxylene, in which an aromatic hydrocarbon feedstock comprising benzene and/or toluene is contacted with an alkylating reagent comprising methanol and/or dimethyl ether in an alkylation reaction zone under alkylation conditions in the presence of an alkylation catalyst to produce an alkylated aromatic product comprising xylenes. The alkylation catalyst comprises a molecular sieve having a Constraint Index≤5, and the alkylation conditions comprise a temperature less than 500° C. The alkylation catalyst may be selectivated to produce a higher than equilibrium amount of paraxylene by using a molar ratio of alkylating agent to aromatic of at least 1:4.
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公开(公告)号:US10259765B2
公开(公告)日:2019-04-16
申请号:US15743367
申请日:2016-06-17
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Jihad M. Dakka , Ashley J. Malik , Christopher L. Becker , Jason D. Davis , Kirk C. Nadler , Jose M. Vargas , Tan-Jen Chen , Seth M. Washburn , Jörg F. W. Weber
IPC: C07C45/00 , C07C2/74 , C07C407/00 , B01J23/96 , B01J38/04 , B01J38/06 , B01J38/12 , B01J38/52 , B01J38/56 , B01J23/44 , B01J35/00 , B01J8/06 , B01J38/10 , B01J38/50 , B01J38/64 , C07C49/403 , B01J23/58 , C07C37/00
Abstract: Disclosed are novel processes for making cyclohexanone compositions, from a mixture comprising phenol, cyclohexanone, and cyclohexylbenzene. The process includes hydrogenation of a feed stream comprising phenol, cyclohexanone, and cyclohexylbenzene. The feed stream may be subjected to one or more pre-hydrogenation treatments, such as passing through one or more sorbents, addition of basic chemical agents, and/or addition of water, so as to improve catalyst activity, minimize undesired side reactions, and/or remove catalyst poisons from the feed stream. The feed stream may be provided to a hydrogenation reaction zone in the vapor phase, with periodic alterations to hydrogenation reaction conditions such that the feed is provided in mixed liquid and vapor phase in order to carry out liquid washing of a hydrogenation catalyst bed within the hydrogenation reaction zone.
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公开(公告)号:US20180099913A1
公开(公告)日:2018-04-12
申请号:US15702337
申请日:2017-09-12
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Tan-Jen Chen , Seth M. Washburn
Abstract: A process is described for producing paraxylene, in which an aromatic hydrocarbon feedstock comprising benzene and/or toluene is contacted with an alkylating reagent comprising methanol and/or dimethyl ether in an alkylation reaction zone under alkylation conditions in the presence of an alkylation catalyst to produce an alkylated aromatic product comprising xylenes. The alkylation catalyst comprises a molecular sieve having a Constraint Index≤5, and the alkylation conditions comprise a temperature less than 500° C. Paraxylene may then be recovered from the alkylated aromatic product.
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公开(公告)号:US09321704B2
公开(公告)日:2016-04-26
申请号:US14438638
申请日:2013-12-02
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: James R. Lattner , Christopher L. Becker , Tan-Jen Chen
IPC: C07C45/00 , C07C37/80 , C07C2/74 , C07C5/367 , C07C5/31 , C07C13/28 , C07C15/04 , C07C37/58 , C07C45/28
CPC classification number: C07C5/367 , C07C2/74 , C07C5/31 , C07C13/28 , C07C15/04 , C07C37/58 , C07C45/28 , C07C2601/14
Abstract: A cyclohexane dehydrogenation process comprising a step of providing, as a benzene-containing stream, a vapor phase in equilibrium with a liquid phase at a condensation separation system; supplying benzene, hydrogen, and cyclohexane into a dehydrogenation reactor where at least part of the benzene supplied is from the benzene-containing stream. The use of a condensation separation system enables the control of the partial pressure of benzene in the material fed into the dehydrogenation reactor by controlling the temperature of the vapor phase, and hence the control of hydrogen to benzene molar ratio in the dehydrogenation reactor. The process results in a long life of the dehydrogenation catalyst due to reduced coking.
Abstract translation: 环己烷脱氢方法包括在冷凝分离系统下提供与液相平衡的气相作为含苯物流的步骤; 将苯,氢和环己烷供应到脱氢反应器中,其中供应的至少一部分苯来自含苯物流。 通过使用冷凝分离系统,能够通过控制蒸发相的温度来控制进入脱氢反应器的材料中的苯分压,从而控制脱氢反应器中氢与苯的摩尔比。 该方法由于焦化减少导致脱氢催化剂的长寿命。
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公开(公告)号:US09233890B2
公开(公告)日:2016-01-12
申请号:US14402273
申请日:2013-07-09
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Hari Nair , Christopher L. Becker , Ryan A. Sothen , Charles Morris Smith , Tan-Jen Chen
IPC: C07C45/53 , C07C37/08 , C07C2/66 , C07C2/74 , C07C13/28 , C07C7/12 , C07C7/13 , C07C37/50 , C07C45/00 , C07C407/00
CPC classification number: C07C2/74 , C07C7/12 , C07C7/13 , C07C13/28 , C07C37/08 , C07C37/50 , C07C45/00 , C07C45/53 , C07C407/00 , C07C2529/70 , C07C2601/14 , C07C49/403 , C07C39/04 , C07C15/04
Abstract: Provided is a process for producing cyclohexylbenzene, in which a benzene feed stream is subjected to each of the following treatment steps: treating the feed stream with at least one adsorbent and fractionating the feed stream to remove components having a different boiling point than benzene. The treatment steps are carried out in any order and produce a treated benzene feed stream. The treated benzene feed stream is then contacted with hydrogen in the presence of a hydroalkylation catalyst in a hydroalkylation unit under conditions effective to produce a reaction product containing cyclohexylbenzene.
Abstract translation: 提供一种生产环己基苯的方法,其中苯进料流经受以下每个处理步骤:用至少一种吸附剂处理进料流并分馏进料流以除去沸点不同于苯的组分。 处理步骤以任何顺序进行并产生经处理的苯进料流。 然后在加氢烷基化催化剂存在下,在加氢烷基化单元的有效产生含有环己基苯的反应产物的条件下,将经处理的苯进料流与氢气接触。
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公开(公告)号:US09169172B2
公开(公告)日:2015-10-27
申请号:US14394524
申请日:2013-04-10
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Tan-Jen Chen , Travis A. Reine , Keith H. Kuechler , Terry E. Helton , Jihad M. Dakka
IPC: C07C45/53 , C07C37/08 , C07C2/66 , C07C5/05 , C07C2/74 , C07C5/03 , C07C407/00 , C07C7/163 , B01J23/44 , B01J23/46 , B01J23/75 , B01J23/755 , B01J35/00 , B01J35/08 , B01J37/00 , C07C409/14 , B01J21/04
CPC classification number: C07C5/05 , B01J21/04 , B01J23/44 , B01J23/462 , B01J23/75 , B01J23/755 , B01J35/008 , B01J35/08 , B01J37/0009 , C07C2/74 , C07C5/03 , C07C7/163 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2521/04 , C07C2523/44 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
Abstract: The present invention relates to hydrogenation processes including: contacting a first composition with hydrogen under hydrogenation conditions, in the presence of an eggshell hydrogenation catalyst, wherein the first composition has: (i) greater than about 50 wt % of cyclohexylbenzene, the wt % based upon the total weight of the first composition; and (ii) greater than about 0.3 wt % of cyclohexenylbenzene, the wt % based upon the total weight of the first composition; and thereby obtaining a second composition having less cyclohexenylbenzene than the first composition. Other hydrogenation processes are also described.
Abstract translation: 本发明涉及氢化方法,包括:在加氢条件下,在蛋壳氢化催化剂存在下使第一组合物与氢接触,其中第一组合物具有:(i)大于约50重量%的环己基苯,基于重量% 基于第一组合物的总重量; 和(ii)大于约0.3重量%的环己烯基苯,所述wt%基于第一组合物的总重量; 从而获得比第一组合物少的环己烯基苯的第二组合物。 还描述了其它氢化方法。
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公开(公告)号:US20220153660A1
公开(公告)日:2022-05-19
申请号:US17433040
申请日:2020-03-18
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Seth M. Washburn , Hsu Chiang , Tan-Jen Chen
Abstract: This disclosure provides improved processes for converting benzene/toluene via methylation with methanol/dimethyl ether for producing, e.g., p-xylene. In an embodiment, a process comprises contacting a methylation agent feed with an aromatic hydrocarbon feed in the presence of a methylation catalyst in a methylation reactor at increased pressure. Reduced methylation catalyst deactivation can be achieved with increased pressure in the methylation reactor.
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公开(公告)号:US11053176B2
公开(公告)日:2021-07-06
申请号:US16979751
申请日:2019-03-15
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Tan-Jen Chen , Wenyih F. Lai , Anthony Go
Abstract: Disclosed is a process for producing mixed xylenes and C9+ hydrocarbons in which an aromatic hydrocarbon feedstock comprising benzene and/or toluene is contacted with an alkylating agent comprising methanol and/or dimethyl ether under alkylation conditions in the presence of an alkylation catalyst to produce an alkylated aromatic product stream comprising the mixed xylenes and C9+ hydrocarbons. The mixed xylenes are subsequently converted to para-xylene, and the C9+ hydrocarbons and its components may be supplied as motor fuels blending components. The alkylation catalyst comprises a molecular sieve having a Constraint Index in the range from greater than zero up to about 3. The molar ratio of aromatic hydrocarbon to alkylating agent is in the range of greater than 1:1 to less than 4:1.
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公开(公告)号:US09464011B2
公开(公告)日:2016-10-11
申请号:US14770657
申请日:2014-03-06
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Gabor Kiss , Thomas E. Green , Terry E. Helton , William C. Horn , William A. Lamberti , Tan-Jen Chen
IPC: C07C45/53 , C07C37/08 , C07C2/66 , B01J37/00 , B01J35/00 , C07C2/74 , C07C407/00 , B01J29/74 , B01J35/02 , C07C409/14 , B01J37/02 , B01J35/10
CPC classification number: C07C2/74 , B01J29/7476 , B01J35/0006 , B01J35/0073 , B01J35/008 , B01J35/026 , B01J35/1019 , B01J37/0009 , B01J37/02 , B01J37/0201 , B01J37/0223 , B01J2229/20 , B01J2229/42 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
Abstract: A process for producing an alkylated aromatic compound comprises contacting an aromatic starting material and hydrogen with a plurality of catalyst particles under hydroalkylation conditions to produce an effluent comprising the alkylated aromatic compound, the catalyst comprising a composite of a solid acid, an inorganic oxide different from the solid acid and a hydrogenation metal, wherein the distribution of the hydrogenation metal in at least 60 wt % of the catalyst particles is such that the average concentration of the hydrogenation metal in the rim portion of a given catalyst particle is Crim, the average concentration of the hydrogenation metal in the outer portion of a given catalyst particle is Couter, the average concentration of the hydrogenation metal in the center portion of the given catalyst particle is Ccenter, where Crim/Ccenter≧2.0 and/or Couter/Ccenter2.0. Also disclosed are rimmed catalyst and process for making phenol and/or cyclohexanone using the catalyst.
Abstract translation: 一种制备烷基化芳族化合物的方法包括在加氢烷基化条件下使芳族起始原料和氢气与多个催化剂颗粒接触以产生包含烷基化芳族化合物的流出物,所述催化剂包含固体酸,不同于 固体酸和氢化金属,其中氢化金属在至少60重量%催化剂颗粒中的分布使得给定催化剂颗粒的边缘部分中的氢化金属的平均浓度为Crim,平均浓度 在给定催化剂颗粒的外部部分的氢化金属是Couter,给定催化剂颗粒的中心部分的氢化金属的平均浓度是Ccenter,其中Crim /Ccenter≥2.0和/或Couter / Ccenter2.0。 还公开了边缘催化剂和使用催化剂制备苯酚和/或环己酮的方法。
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公开(公告)号:US09364819B2
公开(公告)日:2016-06-14
申请号:US14771140
申请日:2014-03-06
Applicant: ExxonMobil Chemical Patents Inc.
Inventor: Gabor Kiss , Thomas E. Green , Terry E. Helton , William C. Horn , William A. Lamberti , Tan-Jen Chen
IPC: C07C2/66 , B01J29/74 , B01J23/44 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , B01J29/03 , B01J35/02 , B01J35/10 , B01J29/70 , B01J35/00 , B01J29/76
CPC classification number: B01J29/7476 , B01J23/44 , B01J29/0325 , B01J29/0333 , B01J29/7038 , B01J29/7676 , B01J35/0006 , B01J35/0073 , B01J35/023 , B01J35/026 , B01J35/1019 , B01J2229/20 , B01J2229/42 , C07C2/66 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/44 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C409/14 , C07C13/28 , C07C49/403 , C07C39/04
Abstract: A process for producing an alkylated aromatic compound comprises contacting an aromatic starting material and hydrogen with a plurality of catalyst particles under hydroalkylation conditions to produce an effluent comprising the alkylated aromatic compound, the catalyst comprising a composite of a solid acid, an inorganic oxide different from the solid acid and a hydrogenation metal, wherein the distribution of the hydrogenation metal in at least 60 wt % of the catalyst particles is such that the average concentration of the hydrogenation metal in the rim portion of a given catalyst particle is Crim, the average concentration of the hydrogenation metal in the center portion of the given catalyst particle is Ccenter, where 0.2≦Crim/Ccenter
Abstract translation: 一种制备烷基化芳族化合物的方法包括在加氢烷基化条件下使芳族起始原料和氢气与多个催化剂颗粒接触以产生包含烷基化芳族化合物的流出物,所述催化剂包含固体酸,不同于 固体酸和氢化金属,其中氢化金属在至少60重量%催化剂颗粒中的分布使得给定催化剂颗粒的边缘部分中的氢化金属的平均浓度为Crim,平均浓度 在给定的催化剂颗粒的中心部分的氢化金属是Ccenter,其中0.2&lt; lI; Crim / Ccenter <2.0。 还公开了加氢烷基化催化剂和使用该催化剂制备苯酚和/或环己酮的方法。
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