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公开(公告)号：US5900520A
公开(公告)日：1999-05-04
申请号：US376257
申请日：1995-01-23
CPC分类号： C07C2/76 , C07C2529/08 , C07C2529/60 , C07C2529/70
摘要： Alkyl aromatic compounds are prepared by alkylating an alkylatable aromatic compound with a paraffin alkylating agent under alkylation reaction conditions in the presence of catalyst comprising synthetic porous crystalline material characterized by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07, and 3.42.+-.0.06 Angstroms.
摘要翻译： 烷基芳族化合物通过在烷基化反应条件下在烷烃化反应条件下在催化剂存在下烷基化烷基化芳族化合物来制备，所述催化剂包含合成多孔结晶材料，其特征在于X射线衍射图包括12.36 +/- 0.4的面间d-间距， 11.03 +/- 0.2,8.33 +/- 0.14 6.18 +/- 0.12,6.00 +/- 0.10,4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃。
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公开(公告)号：US5371312A
公开(公告)日：1994-12-06
申请号：US42430
申请日：1993-04-05
IPC分类号： B01J29/40 , B01J31/02 , B01J31/12 , C07C1/20 , C07C2/12 , C07C2/66 , C07C5/27 , C07C5/41 , C07C6/12 , C10G45/64 , C07C5/52
CPC分类号： C10G45/64 , B01J29/40 , B01J31/123 , C07C1/20 , C07C2/12 , C07C2/66 , C07C5/2708 , C07C5/41 , C07C6/123 , C07C6/126 , B01J2229/12 , B01J2229/26 , B01J2229/32 , B01J2229/36 , B01J2229/42 , C07C2529/06 , C07C2529/064 , Y02P20/52
摘要： A process for shape selective hydrocarbon conversion involves contacting a hydrocarbon feedstream under conversion conditions with a catalytic molecular sieve which has been modified by treatment with an amino silane polymer while molecular sieve acid sites are protected. When the process is toluene disproportionation, a toluene feedstream may also contain a second silicon source which is a high pxylene selectivating agent. The invention also includes the modification method and the shape selective catalyst which results from the modification.
摘要翻译： 用于形状选择性烃转化的方法包括在转化条件下使烃进料流与催化分子筛接触，催化分子筛在分子筛酸性位点受到保护时已用氨基硅烷聚合物进行改性。 当该方法是甲苯歧化反应时，甲苯进料流还可以含有第二硅源，其是高的吡咯啉选择性试剂。 本发明还包括由改性产生的改性方法和形状选择性催化剂。
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公开(公告)号：US5366945A
公开(公告)日：1994-11-22
申请号：US995091
申请日：1992-12-22
IPC分类号： B01J27/188 , B01J29/03 , B01J29/04 , C07C2/62 , B01J21/02 , B01J27/185 , B01J29/06
CPC分类号： B01J29/0341 , B01J27/188 , B01J29/041 , B01J29/043 , C07C2/62 , B01J29/0308 , C07C2527/188 , Y02P20/588
摘要： There is provided a catalyst comprising a heteropoly acid, such as phosphotungstic acid, supported on a mesoporous crystalline material, such as M41S. A particular form of this M41S support is designated as MCM-41. There is also provided a method for preparing this catalyst by impregnating the heteropoly acid on the support. There is also provided a process for using this catalyst to catalyze acid catalyzed reactions, such as the isomerization of paraffins and the alkylation of aromatics.
摘要翻译： 提供了一种催化剂，其包含负载在介孔结晶材料如M41S上的杂多酸如磷钨酸。 该M41S支持的特定形式被指定为MCM-41。 还提供了通过将杂多酸浸渍在载体上来制备该催化剂的方法。 还提供了一种使用该催化剂催化酸催化反应的方法，例如链烷烃的异构化和芳族化合物的烷基化。
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44.发明授权
公开(公告)号：US5296428A
公开(公告)日：1994-03-22
申请号：US929070
申请日：1992-08-12
申请人： Thomas F. Degnan , Kathleen M. Keville , Charles T. Kresge , David O. Marler , Brenda H. Rose , Wieslaw J. Roth , Kenneth G. Simons, deceased , Hye K. C. Timken , James C. Vartuli
发明人： Thomas F. Degnan , Kathleen M. Keville , Charles T. Kresge , David O. Marler , Brenda H. Rose , Wieslaw J. Roth , Kenneth G. Simons, deceased , Hye K. C. Timken , James C. Vartuli
CPC分类号： B01J29/049 , C01B39/026
摘要： There is provided a catalyst comprising MCM-36 and a hydrogenation/dehydrogenation component. A particular example of such a catalyst comprises MCM-36, nickel and tungsten.
摘要翻译： 提供了包含MCM-36和氢化/脱氢组分的催化剂。 这种催化剂的具体实例包括MCM-36，镍和钨。
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公开(公告)号：US5264116A
公开(公告)日：1993-11-23
申请号：US734999
申请日：1991-07-24
摘要： A process for producing high quality lubricants by the hydrocracking and hydroisomerization of petroleum waxes uses a catalyst which is based on an ultra-large pore crystalline material. The crystalline material exhibits unusually large pores of at least 13 .ANG. diameter and a high sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams at 50 torr and 25.degree. C. The crystalline material is characterized by an X-ray diffraction pattern with at least one d-spacing greater than about 18 .ANG. and in a particularly preferred form, a hexagonal arrangement of pores of at least 13 .ANG. diameter which can be indexed with a d.sub.100 value greater than about 18 .ANG.. The hydrocracking catalysts based on these materials are capable of producing lube products with a high VI of at least 120 and usually higher, values of 135 and higher e.g. 143. the lube products are produced in good yield from feeds which may contain down to about 30 percent wax content, although wax contents of at least 50 percent are preferred for the highest quality products. The catalysts achieve this result without the use of fluorine or other promoters.
摘要翻译： 通过石油蜡的加氢裂化和加氢异构化生产高品质润滑剂的方法使用基于超大孔结晶材料的催化剂。 结晶材料表现出非常大的至少13安格姆直径的孔，并且在50托和25℃下其苯吸附能力大于约15克苯/ 100克证明了高吸附能力。结晶材料的特征在于X 具有至少一个d-间距大于约18的射线衍射图案，并且在特别优选的形式中，具有至少13个ANGSTROM直径的孔的六边形排列，其可以以大于约18的d100值进行索引。 基于这些材料的加氢裂化催化剂能够生产具有至少120的高VI，通常较高的值135和更高的润滑油产品，例如， 143.润滑油产品从饲料中以良好的产率生产，其可含有至多约30％的蜡含量，尽管至少50％的蜡含量对于最高质量的产品是优选的。 催化剂在不使用氟或其它促进剂的情况下实现该结果。
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46.发明授权
公开(公告)号：US5254322A
公开(公告)日：1993-10-19
申请号：US927108
申请日：1992-08-10
IPC分类号： F01N3/24 , B01D53/56 , B01D53/86 , B01D53/94 , B01J29/40 , B01J29/44 , B01J29/46 , B01J29/48 , B01J8/00 , B01D47/00 , C01B21/00
CPC分类号： B01J29/46 , B01D53/9418 , B01J29/40 , B01D2251/208 , B01D2255/204 , B01D2255/20761 , B01D2255/504 , Y02T10/24
摘要： A method is provided for reducing NO.sub.x for high flow applications such as NO.sub.x abatement in an exhaust gas from an internal combustion engine operating under lean burn conditions wherein NO.sub.x is reduced by hydrocarbon reductants. The method employs a hydrothermally stable catalyst comprising transition metal-containing ZSM-5 which is prepared by in-situ crystallization of an aggregate comprising ZSM-5 seeds, silica, and a crystalline silicate.
摘要翻译： 提供了一种用于减少用于高流量应用的NOx的方法，例如来自在贫燃条件下运行的内燃机的废气中的NOx的减少，其中NOx由烃还原剂还原。 该方法采用包含含过渡金属的ZSM-5的水热稳定催化剂，其通过包含ZSM-5种子，二氧化硅和结晶硅酸盐的骨料的原位结晶而制备。
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47.发明授权Catalytic conversion over specially synthesized crystalline porous chalcogenides 失效特殊合成的结晶多孔硫族化合物的催化转化
公开(公告)号：US5233112A
公开(公告)日：1993-08-03
申请号：US901284
申请日：1992-06-19
CPC分类号： B01J29/06 , B01J29/65 , B01J29/7042 , B01J29/7046 , C01B33/2876 , C07C2/66 , C07C4/18 , B01J2229/20 , B01J2229/26 , B01J2229/42 , B01J29/40 , B01J29/70 , C07C2529/65 , C07C2529/70
摘要： This invention relates to catalytic conversion of feedstock organic compounds to conversion product by contacting the feedstock at conversion conditions with catalyst comprising a new form of crystalline porous chalcogenide, e.g., silicate or like material, synthesized by a particular method.
摘要翻译： 本发明涉及通过使转化条件下的原料与包含通过特定方法合成的新型结晶多孔硫族化物（例如硅酸盐或类似材料）的催化剂接触来将原料有机化合物催化转化成转化产物。
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公开(公告)号：US5182242A
公开(公告)日：1993-01-26
申请号：US896034
申请日：1992-06-02
申请人： David O. Marler
发明人： David O. Marler
CPC分类号： B01J37/0018 , B01J29/40 , B01J29/7007 , B01J2229/42 , B01J29/0308 , B01J29/65 , B01J29/70 , B01J29/85
摘要： Low acidity refractory oxide-bound molecular sieve, e.g., zeolite, compositions, for example, zirconia-bound zeolite Beta, possessing superior physical properties, e.g., crush strength, and the method for their manufacture are described. Since low acidity refractory oxide-bound catalysts are less active than alumina-bound zeolite catalysts, the former are particularly useful in hydrocarbon conversion processes in which reduced coke make increases catalyst cycle length. Due to their stability in acid environments, the low acidity refractory oxide-bound molecular sieve extrudate herein can be acid treated without unduly compromising its structural integrity.
摘要翻译： 描述具有优异的物理性质（例如压碎强度）的低酸度难熔氧化物结合分子筛，例如沸石，组合物，例如与氧化锆结合的沸石β，及其制造方法。 由于低酸度难熔氧化物结合的催化剂比氧化铝结合的沸石催化剂活性低，所以前者在烃转化方法中特别有用，其中减少的焦炭使催化剂循环长度增加。 由于它们在酸性环境中的稳定性，本文中低酸度难熔氧化物结合的分子筛挤出物可以进行酸处理，而不会不利地损害其结构完整性。
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公开(公告)号：US5173461A
公开(公告)日：1992-12-22
申请号：US497046
申请日：1990-03-21
申请人： Robert P. Absil , Scott Han , David S. Shihabi , David O. Marler , Clarence D. Chang , Donna M. Mitko
发明人： Robert P. Absil , Scott Han , David S. Shihabi , David O. Marler , Clarence D. Chang , Donna M. Mitko
CPC分类号： B01J29/40 , C07C6/126 , B01J2229/12 , B01J2229/26 , B01J2229/32 , B01J2229/42 , C07C2529/40
摘要： A catalyst comprising a molecular sieve having a lattice aluminum content in which the silica/alumina framework mole ratio is less than 55, and having a diffusion rate constant of less than about 150 sec.sup.-1 .times.10.sup.-6 is particularly useful for vapor-phase disproportionation of toluene.
摘要翻译： 包含具有格子铝含量的分子筛的催化剂，其二氧化硅/氧化铝骨架摩尔比小于55，并且具有小于约150秒-1×10 -6的扩散速率常数特别适用于气相歧化 甲苯。
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公开(公告)号：US5160500A
公开(公告)日：1992-11-03
申请号：US785361
申请日：1991-10-30
CPC分类号： C07C4/18 , B01J29/40 , B01J29/65 , B01J29/7046 , C01B39/48 , C07C2/66 , B01J2229/20 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C2529/65 , C07C2529/70
摘要： There is provided a method for preparing a zeolite other than ZSM-5 from a reaction mixture comprising a mixed organic directing agent which is a combination of (a) an organic nitrogen containing compound such as an amine or a quaternary ammonium compound and (b) an alcohol and/or diol. Particular zeolites synthesized by this method include ZSM-22 and ZSM-23. The use of an alcohol or a diol may inhibit the coformation of ZSM-5. Especially when used to prepare ZSM-23, this method enables the preparation of more catalytically active ZSM-23 of reduced crystallite size and also enables the use of lower crystallization temperatures. Particular mixed organic directing agents for the preparation of ZSM-23 are combinations of (a) pyrrolidine and (b) ethanol or ethylene glycol. Other factors which enhance the activity of ZSM-23 include the use of the following in the reaction mixtures for preparing ZSM-23: potassium ions; precipitated silica particles as sources of silica; and spray dried precipitated silica/alumina particles as sources of silica and alumina. The catalytic stability of alumina bound ZSM-23 catalysts is especially enhanced by steaming. Particular reactions which can be catalyzed by ZSM-23 made according to methods described herein include the dealkylation of ethylbenzene and the alkylation of benzene with ethylene.
摘要翻译： 提供了一种从含有（a）有机氮化合物如胺或季铵化合物的组合的混合有机导向剂的反应混合物制备ZSM-5以外的沸石的方法，（b） 醇和/或二醇。 通过该方法合成的特定沸石包括ZSM-22和ZSM-23。 使用醇或二醇可能会抑制ZSM-5的结构。 特别是当用于制备ZSM-23时，该方法能够制备更小的微晶尺寸的更具催化活性的ZSM-23，并且还能够使用较低的结晶温度。 用于制备ZSM-23的特殊的混合有机导向剂是（a）吡咯烷和（b）乙醇或乙二醇的组合。 提高ZSM-23活性的其他因素包括在制备ZSM-23：钾离子的反应混合物中使用以下物质： 沉淀二氧化硅颗粒作为二氧化硅源; 和喷雾干燥的沉淀二氧化硅/氧化铝颗粒作为二氧化硅和氧化铝的来源。 氧化铝结合的ZSM-23催化剂的催化稳定性通过蒸汽特别提高。 根据本文所述方法制备的可以由ZSM-23催化的特定反应包括乙苯的脱烷基化和苯与乙烯的烷基化。
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