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41.发明授权Polymers produced by using sulphur compounds in the form of transfer agents for controlled radical polymerisation of acrylic acid and the use thereof 有权通过使用用于丙烯酸受控自由基聚合的转移剂形式的硫化合物生产的聚合物及其用途公开(公告)号：US08053497B2
公开(公告)日：2011-11-08
申请号：US12909661
申请日：2010-10-21
IPC分类号： C08L33/14 , C08L43/02 , C08L53/00 , C08K3/26 , C08K3/30 , C08K3/34 , C08F2/00 , C08F20/00 , C08F118/02
CPC分类号： C08F20/06
摘要： The invention concerns the polymers obtained by the use of sulfur compounds in a process for controlled radical polymerization in water of acrylic acid and/or acrylic acid with hydrosoluble monomers. It concerns also their uses as dispersant agents or agents to aid grinding and/or co-grinding of mineral matters in aqueous suspensions, and as dispersant agents incorporated directly in aqueous formulations containing mineral matters. Finally, the invention concerns the formulations of mineral matters obtained in this manner.
摘要翻译： 本发明涉及通过在丙烯酸和/或丙烯酸与水溶性单体的水中控制自由基聚合的方法中使用硫化合物获得的聚合物。 它还涉及它们作为分散剂或试剂的用途，以帮助矿物质在水性悬浮液中的研磨和/或共研磨，以及直接掺入含有矿物质的含水制剂中的分散剂。 最后，本发明涉及以这种方式获得的矿物质的配方。
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42.发明授权Trithiocarbonate derivatives and the use thereof in the form of transfer agents for acrylic acid controlled radical polymerisation 有权三硫代碳酸酯衍生物及其用于丙烯酸控制自由基聚合的转移剂形式的用途公开(公告)号：US07956211B2
公开(公告)日：2011-06-07
申请号：US10594520
申请日：2005-03-23
IPC分类号： C07C327/36
CPC分类号： C07C329/00 , C04B24/161 , C04B24/2652 , C04B2103/40 , C08F2/38 , C08F4/00 , C08F220/06
摘要： The invention relates to novel sulphur compounds, to the production thereof by a method carried out in an aqueous medium and the use thereof in the form of transfer agents in a method for controlled radical polymerization of acrylic acid and/or acrylic acid with water-soluble monomers in water. The thus obtained polymers are usable in the form of dispersing agents or grinding aid agents and/or aid agents for combined grinding of mineral materials in an aqueous suspension and in the form of dispersing agents directly incorporated into aqueous formulations containing mineral materials.
摘要翻译： 本发明涉及新的硫化合物，通过在水性介质中进行的方法及其在转移剂形式中的用途在丙烯酸和/或丙烯酸与水溶性的自由基聚合方法中的应用 单体在水中。 由此获得的聚合物可以以分散剂或研磨助剂和/或辅助剂的形式用于矿物材料在水性悬浮液中的组合研磨，并以分散剂的形式直接掺入到含有矿物材料的水性制剂中。
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43.发明授权Polymers produced by using sulphur compounds in the form of transfer agents for controlled radical polymerisation of acrylic acid and the use thereof 有权通过使用用于丙烯酸受控自由基聚合的转移剂形式的硫化合物生产的聚合物及其用途公开(公告)号：US07851572B2
公开(公告)日：2010-12-14
申请号：US10594519
申请日：2005-03-23
IPC分类号： C08F2/00 , C08F20/00 , C08F118/02 , B32B17/10 , A61L24/00
CPC分类号： C08F2/38 , C08F20/06 , C08F220/06 , C08F220/26 , C08F220/34 , C08F220/56 , C08F220/58
摘要： The invention concerns the polymers obtained by the use of sulphur compounds in a process for controlled radical polymerization in water of acrylic acid and/or acrylic acid with hydrosoluble monomers. It concerns also their uses as dispersant agents or agents to aid grinding and/or co-grinding of mineral matters in aqueous suspensions, and as dispersant agents incorporated directly in aqueous formulations containing mineral matters. Finally, the invention concerns the formulations of mineral matters obtained in this manner.
摘要翻译： 本发明涉及通过在丙烯酸和/或丙烯酸与水溶性单体的水中控制自由基聚合的方法中使用硫化合物获得的聚合物。 它还涉及它们作为分散剂或试剂的用途，以帮助矿物质在水性悬浮液中的研磨和/或共研磨，以及直接掺入含有矿物质的含水制剂中的分散剂。 最后，本发明涉及以这种方式获得的矿物质的配方。
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44.发明申请Use of weakly anionic copolymers as dispersing and/or grinding aid agent of an aqueous suspension of mineral materials 审中-公开使用弱阴离子共聚物作为矿物材料的水悬浮液的分散和/或助磨剂公开(公告)号：US20050143511A1
公开(公告)日：2005-06-30
申请号：US11046887
申请日：2005-02-01
IPC分类号： B01F17/00 , B01F17/42 , B01F17/52 , B02C23/06 , C08F220/28 , C08F220/34 , C09C1/02 , C09C1/36 , C09C1/42 , C09C3/10 , C09D7/45 , C09K8/24 , D21H19/58 , D21H19/60 , C08K3/26
CPC分类号： B02C23/06 , B01F17/0028 , B01F17/005 , B01F17/0057 , B01F17/0064 , C01P2004/61 , C01P2004/62 , C01P2006/22 , C08F220/28 , C08F220/34 , C08F290/068 , C09C1/02 , C09C1/021 , C09C1/025 , C09C1/028 , C09C1/3676 , C09C1/42 , C09C3/10 , C09D17/004 , C09K8/24 , D21H19/58 , D21H19/60
摘要： The invention relates to the use of a slightly anionic and water-soluble copolymer, as a dispersing agent and/or an agent for assisting the grinding of pigments and/or mineral fillers in aqueous suspension giving on the one hand a low Zeta potential to the aqueous suspensions of the said fillers and/or pigments and on the other hand affording an electro-steric stabilization of the said suspensions. The invention also relates to the said aqueous suspensions of mineral pigments and/or fillers and their uses in the fields of paper, such as the manufacture or coating of paper, and drilling muds used for petroleum prospecting or extraction. The invention also relates to the use of the said dispersing agents and/or agent for assisting the grinding in the field of paints and plastic materials such as thermoplastic or thermosetting resins.
摘要翻译： 本发明涉及使用轻微阴离子和水溶性的共聚物作为分散剂和/或用于辅助在水性悬浮液中研磨颜料和/或矿物填料的试剂，一方面使低Zeta电位达到 所述填料和/或颜料的水性悬浮液，另一方面提供所述悬浮液的电 - 空间稳定化。 本发明还涉及所述矿物颜料和/或填料的水悬浮液及其在纸领域中的用途，例如纸的制造或涂布以及用于石油勘探或提取的钻井泥浆。 本发明还涉及所述分散剂和/或试剂在油漆和塑料材料领域中的研磨的使用，如热塑性或热固性树脂。
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45.发明授权Trithiocarbonate derivatives and the use thereof in the form of transfer agents for acrylic acid controlled radical polymerisation 有权三硫代碳酸酯衍生物及其用于丙烯酸控制自由基聚合的转移剂形式的用途公开(公告)号：US08227633B2
公开(公告)日：2012-07-24
申请号：US13084775
申请日：2011-04-12
IPC分类号： C07C327/12 , C07C329/14 , C08K5/36
CPC分类号： C07C329/00 , C04B24/161 , C04B24/2652 , C04B2103/40 , C08F2/38 , C08F4/00 , C08F220/06
摘要： The invention relates to novel sulphur compounds, to the production thereof by a method carried out in an aqueous medium and the use thereof in the form of transfer agents in a method for controlled radical polymerization of acrylic acid and/or acrylic acid with water-soluble monomers in water. The thus obtained polymers are usable in the form of dispersing agents or grinding aid agents and/or aid agents for combined grinding of mineral materials in an aqueous suspension and in the form of dispersing agents directly incorporated into aqueous formulations containing mineral materials.
摘要翻译： 本发明涉及新的硫化合物，通过在水性介质中进行的方法及其在转移剂形式中的用途在丙烯酸和/或丙烯酸与水溶性的自由基聚合方法中的应用 单体在水中。 由此获得的聚合物可以以分散剂或研磨助剂和/或辅助剂的形式用于矿物材料在水性悬浮液中的组合研磨，并以分散剂的形式直接掺入到含有矿物材料的水性制剂中。
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46.发明申请USE OF STRUCTURED WATER-SOLUBLE POLYMERS OBTAINED BY CONTROLLED RADICAL POLYMERIZATION AS A DISPERSANT AND AGENT FOR ASSISTING IN THE GRINDING OF MINERAL MATERIALS 审中-公开通过控制的自由基聚合获得的结构化可溶性聚合物作为分散剂和助剂在矿物材料研磨中的应用公开(公告)号：US20110160348A1
公开(公告)日：2011-06-30
申请号：US12938682
申请日：2010-11-03
IPC分类号： C08L33/14 , C08L43/02 , C08L51/06 , C08L53/00 , C08K3/30 , C08K3/26 , C08K3/34 , C04B26/06 , C08K3/22
CPC分类号： B01F17/0028 , B01F17/005 , B01F17/0057 , B01F17/0064 , C07F9/4006 , C08F4/00
摘要： The invention relates to the use, as a dispersant and/or a grinding aid agent for pigments and/or mineral fillers in aqueous suspension, of a water soluble polymer with a controlled structure obtained by a controlled free radical polymerization process putting into practice a particular alkoxyamine as a polymerization initiator.
摘要翻译： 本发明涉及在水性悬浮液中作为用于颜料和/或矿物填料的分散剂和/或研磨助剂的水溶性聚合物，其具有通过控制的自由基聚合方法获得的具有受控结构的水溶性聚合物， 烷氧基胺作为聚合引发剂。
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47.发明授权Alkali swellable acrylic emulsions without surfactants, use thereof in aqueous formulations, and formulations containing them 有权不含表面活性剂的碱性可溶胀丙烯酸乳液，其在水性配方中的用途，以及含有它们的制剂公开(公告)号：US09487597B2
公开(公告)日：2016-11-08
申请号：US13160558
申请日：2011-06-15
申请人： Jean-Marc Suau
发明人： Jean-Marc Suau
IPC分类号： A61K47/32 , C08L41/00 , C08L43/00 , C09D141/00 , C08F2/22 , C04B24/16 , C04B24/26 , C09D7/00 , C09D133/14 , C11D3/37 , D21H19/24 , C08F220/18 , A61Q19/00 , A61K8/81 , C04B103/00 , C04B103/44 , C08F220/06 , C08F220/58
CPC分类号： C08F2/22 , A61K8/8158 , A61K2800/10 , A61K2800/48 , A61Q19/00 , C04B24/163 , C04B24/2641 , C04B2103/005 , C04B2103/44 , C08F220/06 , C08F220/18 , C08F220/58 , C09D7/43 , C09D133/14 , C11D3/378 , D21H19/24
摘要： The present invention pertains to new alkali swellable thickening emulsions, free of surfactants and solvents other than water: as a result, all drawbacks related to the use of solvents, or to the formation of foam in the case of surfactants, are avoided. These new emulsions contain a certain quantity of 2-acrylamido-2-methylpropane sulfonic acid (or AMPS, CAS #: 40623-75-4). They have proven effective at thickening aqueous mediums, particularly water-based paints, paper coatings, aqueous suspensions of mineral materials, detergents, cosmetic formulations, or formulations containing a hydraulic binder.
摘要翻译： 本发明涉及不含水以外的表面活性剂和溶剂的新的碱溶胀性增稠乳液，因此避免了与使用溶剂有关的所有缺点或在表面活性剂的情况下形成泡沫。 这些新乳液含有一定量的2-丙烯酰氨基-2-甲基丙磺酸（或AMPS，CAS＃：40623-75-4）。 已经证明它们在增稠水性介质，特别是水性涂料，纸涂料，矿物材料的水性悬浮液，洗涤剂，化妆品配方或含有水硬性粘合剂的制剂中是有效的。
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48.发明授权Use of acrylic comb copolymers as a colour developing agent in cosmetic compositions 有权在化妆品组合物中使用丙烯酸梳状共聚物作为彩色显影剂公开(公告)号：US08778368B2
公开(公告)日：2014-07-15
申请号：US13456438
申请日：2012-04-26
申请人： Jean-Marc Suau , Olivier Guerret , Renaud Souzy , Yves Kensicher
发明人： Jean-Marc Suau , Olivier Guerret , Renaud Souzy , Yves Kensicher
IPC分类号： A61K9/00
CPC分类号： A61Q1/02 , A61K8/8152 , A61Q1/04 , A61Q1/08 , A61Q1/10
摘要： Cosmetic compositions for make-up containing acrylic comb copolymers having the advantage of increasing the intensity of the color produced by these compositions when they are applied to the skin or to keratin derivatives such as the hair or the eyelashes. Not only are the aesthetic properties conferred by these compositions thus improved, but their useful life is also increased, since they allow access to the desired shade (and good intensity) right from the first application.
摘要翻译： 用于补充含有丙烯酸梳理共聚物的化妆品组合物，其具有当将这些组合物施用于皮肤时产生的颜色的强度增加或角质素衍生物如头发或睫毛的优点。 不仅这些组合物赋予的美学特性得到改善，而且它们的使用寿命也增加了，因为它们允许从第一次应用获得所需的遮光（和良好的强度）。
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49.发明授权Method for making comb polymers by drying then functionalization of the meth(acrylic)polymer backbone, resulting polymers and uses thereof 有权通过干燥然后官能化甲基（丙烯酸）聚合物主链，得到的聚合物及其用途来制备梳形聚合物的方法公开(公告)号：US08742027B2
公开(公告)日：2014-06-03
申请号：US12299972
申请日：2007-05-04
申请人： Jean Moro , Jean-Marc Suau , Yves Kensicher
发明人： Jean Moro , Jean-Marc Suau , Yves Kensicher
CPC分类号： C08F220/28 , C04B26/06 , C08F220/58 , C08G81/025 , C04B7/02 , C04B14/06 , C04B14/28 , C04B14/30 , C04B14/365 , C04B14/368
摘要： The present invention relates to processes for manufacturing comb polymers having a principal (meth)acrylic chain and polyoxyalkylated lateral groupings, obtained by drying of a solution containing at least one homopolymer of (meth)acrylic acid and/or at least one copolymer of (meth)acrylic acid with at least one other monomer, followed by functionalisation of the intermediate dry product by esterification with at least one alkoxy polyoxyalkylene glycol, and/or amidification with at least one alkoxy polyoxyalkylene amine, or ethoxylation with at least one alkylene oxide.
摘要翻译： 本发明涉及制备具有主要（甲基）丙烯酸链和聚氧化烷基化侧面基团的梳状聚合物的方法，其通过干燥含有至少一种（甲基）丙烯酸的均聚物和/或至少一种（甲基）丙烯酸酯的共聚物的溶液 ）丙烯酸与至少一种其它单体反应，随后用至少一种烷氧基聚氧亚烷基二醇进行酯化，和/或用至少一种烷氧基聚氧化烯胺胺化，或用至少一种烯化氧进行乙氧基化，使中间体干燥产物官能化。
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50.发明授权Method for thickening a cosmetic formulation using an alkali swellable emulsion of a polymer with AMPS and which is rich in acrylic acid 有权使用具有AMPS并富含丙烯酸的聚合物的碱溶胀性乳液来增稠化妆品制剂的方法公开(公告)号：US08642056B2
公开(公告)日：2014-02-04
申请号：US13411809
申请日：2012-03-05
申请人： Renaud Souzy , Jean-Marc Suau , Yves Kensicher , Olivier Guerret
发明人： Renaud Souzy , Jean-Marc Suau , Yves Kensicher , Olivier Guerret
CPC分类号： A61K8/8158 , A61K8/06 , A61K8/068 , A61K8/8147 , A61K2800/10 , A61K2800/33 , A61K2800/48 , A61K2800/546 , A61Q19/00 , C08F220/06 , C08F220/12 , C08F220/28 , C08F220/58
摘要： Process for thickening a composition, through the use of a direct emulsion in water, which is alkali-swellable, of a polymer of the ASE or HASE type, which is both rich in acrylic acid and which has a certain quantity of AMPS. The use of such emulsions simultaneously allows there to be no obligation to use surfactants and organic solvents other than water, and allows the thickening phenomenon to be activated for pHs of less than 7: this latter characteristic is particularly advantageous for formulations intended to be used in contact with skin.
摘要翻译： 通过使用ASE或HASE型聚合物的水中的直接乳液（其是富含丙烯酸并且具有一定量的AMPS）而使组合物增稠的方法。 同时使用这种乳液使得除了水之外没有义务使用表面活性剂和有机溶剂，并且允许增稠现象在小于7的pH下被活化：后者的特征对于拟用于 接触皮肤。
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