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95 条记录 (耗时 0.026 秒)

    Oxidation of hydrocarbons using crystalline manganese (II/III) phosphate compositions
    42.
    发明授权
    Oxidation of hydrocarbons using crystalline manganese (II/III) phosphate compositions 失效
    使用结晶锰（II / III）磷酸盐组合物对碳氢化合物进行氧化

    公开(公告)号：US06512144B1

    公开(公告)日：2003-01-28

    申请号：US09728536

    申请日：2000-12-01

    申请人： Gregory J. Lewis ,  Paula L. Bogdan ,  Feng Xu ,  Joseph A. Kocal

    发明人： Gregory J. Lewis ,  Paula L. Bogdan ,  Feng Xu ,  Joseph A. Kocal

    IPC分类号： C07C4500

    CPC分类号： B01J27/187 ,  B01J29/82 ,  C01B25/377 ,  C07C45/33 ,  C07C315/02

    摘要： Processes for oxidizing hydrocarbons using a new family of crystalline manganese phosphate compositions have been developed. These compositions have an extended network which network can be a one-, two-, or three-dimensional network. The composition has an empirical formula of: (Aa+)v(Mnb+)(Mc+)xPyOz where A is a structure directing agent such as an alkali metal, M is a metal such as Al, Fe3+ and “b” is the average manganese oxidation state and varies from greater than 2.0 to a maximum of 3.0. Specific oxidation processes are oxidative dehydrodimerization and oxidative dehydrogenation.

    摘要翻译： 已经开发了使用新的结晶磷酸锰组合物来氧化烃的方法。 这些组合物具有扩展网络，其网络可以是一维，二维或三维网络。 该组合物具有以下经验式：其中A是结构导向剂如碱金属，M是金属如Al，Fe 3+，“b”是平均锰氧化态，并且从大于2.0变化到最大值 3.0。 具体的氧化过程是氧化脱氢二聚化和氧化脱氢。

    Removal of sulfur-containing compounds from liquid hydrocarbon streams
    43.
    发明授权
    Removal of sulfur-containing compounds from liquid hydrocarbon streams 有权
    从液态烃流中除去含硫化合物

    公开(公告)号：US06368495B1

    公开(公告)日：2002-04-09

    申请号：US09689550

    申请日：2000-10-12

    申请人： Joseph A. Kocal ,  Timothy A. Brandvold

    发明人： Joseph A. Kocal ,  Timothy A. Brandvold

    IPC分类号： C10G2922

    CPC分类号： C10G27/04

    摘要： A novel process effective for the removal of organic sulfur compounds from liquid hydrocarbons is disclosed. The process more specifically addresses the removal of thiophenes and thiophene derivatives from a number of petroleum fractions, including gasoline, diesel fuel, and kerosene. In the first step of the process, the liquid hydrocarbon is subjected to oxidation conditions in order to oxidize at least some of the thiophene compounds to sulfones. Then, these sulfones can be catalytically decomposed to hydrocarbons (e.g. hydroxybiphenyl) and volatile sulfur compounds (e.g. sulfur dioxide). The hydrocarbon decomposition products remain in the treated liquid as valuable blending components, while the volatile sulfur compounds are easily separable from the treated liquid using well-known techniques such as flash vaporization or distillation.

    摘要翻译： 公开了一种有效从液态烃中除去有机硫化合物的新方法。 该方法更具体地涉及从许多石油馏分（包括汽油，柴油燃料和煤油）中除去噻吩和噻吩衍生物。 在该方法的第一步中，液态烃经受氧化条件以使至少一些噻吩化合物氧化成砜。 然后，这些砜可以催化分解成烃类（如羟基联苯）和挥发性硫化合物（如二氧化硫）。 烃分解产物保留在经处理的液体中作为有价值的共混组分，而使用众所周知的技术，例如闪蒸或蒸馏，挥发性硫化合物容易与处理液体分离。

    Production of alkyl aromatic compounds
    46.
    发明授权
    Production of alkyl aromatic compounds 失效
    烷基芳族化合物的生产

    公开(公告)号：US5034564A

    公开(公告)日：1991-07-23

    申请号：US507812

    申请日：1990-04-12

    申请人： Joseph A. Kocal

    发明人： Joseph A. Kocal

    IPC分类号： B01J21/16 ,  B01J29/04 ,  B01J37/00 ,  C07C20060101 ,  C07C2/66 ,  C07C2/86 ,  C07C15/02

    CPC分类号： B01J29/049 ,  B01J37/0009 ,  C07C2/66 ,  C07C2/861 ,  C07C2/864 ,  C07C2529/05 ,  Y02P20/582

    摘要： Alkyl aromatic compounds may be prepared by reacting an aromatic compound such as benzene with an alkylating agent such as an olefin, alkyl halide or alkyl alcohol in the presence of an alkylation catalyst. The alkylation catalyst of the present invention comprises a pillared clay and a binder which has been prepared by dispersing a clay in a metallic pillaring agent sol, separating the resultant pillared clay, washing and drying said pillared clay, forming a dough of said pillared clay and a binder compound, extruding said dough extudate. By utilizing this catalytic composite it is possible to obtain improved selectivity of the desired alkyl aromatic compound which may then be used in the preparation of biodegradable detergents.

    摘要翻译： 烷基芳族化合物可以通过芳族化合物如苯与烷基化剂如烯烃，烷基卤或烷基醇在烷基化催化剂的存在下反应来制备。 本发明的烷基化催化剂包括柱状粘土和粘合剂，其通过将粘土分散在金属柱状溶胶中，分离所得柱状粘土，洗涤和干燥所述柱状粘土，形成所述柱状粘土的生面团和 一种粘合剂化合物，挤出所述的面团。 通过利用该催化复合物，可以获得所需的烷基芳族化合物的改进的选择性，然后可以将其用于制备可生物降解的洗涤剂。

    Novel motor fuel alkylation process
    49.
    发明授权
    Novel motor fuel alkylation process 失效
    新型汽油燃料烷基化工艺

    公开(公告)号：US4677245A

    公开(公告)日：1987-06-30

    申请号：US927462

    申请日：1986-11-06

    申请人： Joseph A. Kocal ,  Tamotsu Imai

    发明人： Joseph A. Kocal ,  Tamotsu Imai

    IPC分类号： B01J27/12 ,  B01J31/02 ,  B01J31/40 ,  C07C2/62 ,  C07C2/58

    CPC分类号： B01J27/12 ,  B01J31/0204 ,  B01J31/40 ,  C07C2/62 ,  B01J2231/323 ,  C07C2527/1206 ,  C07C2531/02 ,  Y02P20/584

    摘要： A novel hydrocarbon alkylation process is disclosed wherein the feed hydrocarbons are dried to maintain the water content of the alkylation catalyst at less than 2.0 wt. %, where said alkylation catalyst is comprised of a mineral acid and an ether component selected from the group consisting of tert-butyl ether, methylphenyl ether, tert amylmethyl ether (TAME), or methyl tert-butyl ether (MTBE). This process also incorporates a method of regenerating at least a portion of the alkylation catalyst to prevent build-up of more than 15 wt. % of polymer products therein.

    摘要翻译： 公开了一种新的烃烷基化方法，其中进料烃被干燥以将烷基化催化剂的水含量保持在小于2.0wt。 ％，其中所述烷基化催化剂由无机酸和选自叔丁基醚，甲基苯基醚，叔戊基甲基醚（TAME）或甲基叔丁基醚（MTBE）的醚组分组成。 该方法还包括再生烷基化催化剂的至少一部分的方法，以防止累积超过15wt。 ％的聚合物产品。