Abstract:
The present invention relates to a super absorbent polymer having a controlled degree of internal crosslinking and thereby having simultaneously improved basic absorption capacity and absorbency under pressure, and a method for producing the same. The super absorbent polymer may comprise a base polymer powder including a cross-linked polymer of a monomer containing a water-soluble ethylenically unsaturated compound or its salt; and a surface cross-linked layer that is formed on the base polymer powder and is further cross-linked from the cross-linked polymer, wherein a glass hollow particle having a micron-scale particle size is included in the cross-linked structure of the cross-linked polymer of the base polymer powder.
Abstract:
The present disclosure relates to a preparation method of a porous super absorbent polymer including the steps of preparing a monomer neutralized solution by adding an internal cross-linking agent, an initiator, an inorganic filler, and a nonionic surfactant to a neutralized solution obtained by neutralizing at least 80 mol % of a water soluble ethylene-based unsaturated monomer containing acidic groups; high-shear mixing the monomer neutralized solution; preparing a hydrogel polymer from the high-shear mixed monomer neutralized solution by thermal polymerization or photopolymerization; and preparing a base resin powder by drying, pulverizing, and classifying the hydrogel polymer.
Abstract:
The present invention relates to a method for superabsorbent polymer that has a crosslinking density gradient increasing from the inside toward the outside, and thus, exhibits excellent properties with simultaneously improved centrifuge retention capacity and absorbency under load.
Abstract:
The present invention relates to a superabsorbent polymer having excellent short time free absorbency. The superabsorbent polymer may exhibit excellent centrifuge retention capacity and absorbency under load, as well as excellent short time free absorbency. Thus, it can fundamentally solve the problems of the existing superabsorbent polymer and technical requirement of the art, and can provide various hygienic goods exhibiting more excellent properties.
Abstract:
The present invention relates to a method for preparing superabsorbent polymer. According to the preparation method of the present invention, by maintaining the hydrophilicity of superabsorbent polymer and appropriately controlling the crosslinking density, superabsorbent polymer with excellent properties can be prepared though homogeneous surface crosslinking. Thus, superabsorbent polymer with improved absorption speed can be provided without decrease in absorbency under load.
Abstract:
The present invention relates to a superabsorbent polymer that has more improved gel strength and is improved in both water retention capacity (centrifuge retention capacity, CRC) and absorption ability under pressure (AUP) because of an optimized cross-linked structure of a base resin powder inside a cross-linked surface layer, and a preparation method thereof. The superabsorbent polymer includes a base resin powder including a 1st cross-linked polymer of a water-soluble ethylenic unsaturated monomer having acid groups of which at least a part is neutralized, and a cross-linked surface layer that includes a 2nd cross-linked polymer further cross-linked from the 1st cross-linked polymer and is formed on the base resin powder, wherein an inorganic particle is chemically bonded to the 1st cross-linked polymer by the medium of a cross-linking bond, an oxygen-containing bond (—O—), or a nitrogen-containing bond (—NR—, where R is hydrogen or a C1-C3 alkyl or an amide bond).
Abstract:
The present invention relates to a method for preparing a super absorbent polymer. The method for preparing a super absorbent polymer according to the present invention comprises the steps of: carrying out a thermal polymerization or a photopolymerization of a monomer composition including a water-soluble ethylene-based unsaturated monomer and a polymerization initiator to form a hydrogel polymer; drying the hydrogel polymer; pulverizing the dried polymer; mixing a fine powder having a particle diameter of 180 μm or less and a polymer having a particle diameter of 300 μm or more among the pulverized polymer; and adding steam to the mixture to carry out a reassembling. According to the present invention, the super absorbent polymer having a high fine powder aggregation strength can be obtained.
Abstract:
A method of preparing a super absorbent polymer (SAP) includes the steps of preparing a first hydrogel polymer by carrying out a thermal polymerization or photo polymerization of a monomer composition including a water-soluble ethylene-based unsaturated monomer and a polymerization initiator; preparing a second hydrogel polymer by carrying out a thermal polymerization or photo polymerization of a monomer composition including a water-soluble ethylene-based unsaturated monomer and a polymerization initiator; drying and milling the first hydrogel polymer and distributing the first hydrogel polymer into a fine powder having a particle diameter below 150 μm and a base resin having a particle diameter of 150 μm to 850 μm; fabricating a reassembled body of the fine powder by mixing the fine powder and the second hydrogel polymer; and mixing the reassembled body of the fine powder with the first hydrogel polymer, and drying and milling the same.
Abstract:
The present disclosure relates to a preparation method for a super absorbent polymer sheet and a super absorbent polymer sheet prepared therefrom. According to the preparation method of the present disclosure, a porous super absorbent polymer sheet can be prepared by a simplified process.