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41.发明授权Process for removing organic oxygen-containing impurities from an organic composition 失效从有机组合物中去除有机含氧含量的方法
公开(公告)号：US4117021A
公开(公告)日：1978-09-26
申请号：US801050
申请日：1977-05-27
CPC分类号： C07C15/46 , C07C2/76 , C07C6/04 , C07C7/005 , C07C7/148 , C07C2521/06 , C07C2523/745 , C07C2523/755
摘要： The amount of oxygen-containing impurities in an organic composition is reduced at an elevated temperature by contact with a supported metal oxide. For example, the amount of oxygen-containing organic impurities in a crude stilbene product obtained by oxidatively dehydrocoupling toluene using a solid oxidant is decreased by contact with zinc oxide supported on alumina at an elevated temperature and the resulting purified stilbene product is reacted with ethylene to form styrene.
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42.发明授权Process for removing organic oxygen-containing impurities from an organic composition in the presence of steam 失效在蒸汽存在下从有机组合物中除去有机含氧杂质的方法
公开(公告)号：US4104318A
公开(公告)日：1978-08-01
申请号：US801038
申请日：1977-05-27
摘要： The amount of oxygen-containing impurities in an organic composition is reduced at an elevated temperature in the presence of steam using a catalyst comprising a Group VIb or Group VIII metal oxide or phosphate. For example, the amount of oxygen-containing organic impurities in a crude stilbene product obtained by the oxidative dehydrocoupling of toluene is catalytically reduced at high temperatures in the presence of steam and an iron oxide catalyst and the resulting stilbene product is reacted with ethylene to form styrene.
摘要翻译： 使用包含VIb族或VIII族金属氧化物或磷酸盐的催化剂，在蒸汽存在下，有机组合物中的含氧杂质的量在升高的温度下降低。 例如，在蒸汽和氧化铁催化剂的存在下，通过甲苯的氧化脱氢键合得到的粗芪产物中含氧有机杂质的量在高温下被催化还原，所得的1,2-二苯乙烯产物与乙烯反应形成 苯乙烯。
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43.发明授权Hydrocarbon conversion process using a Ni and/or CO substituted synthetic aluminosilicate catalyst 失效使用Ni和/或CO取代的合成硅铝酸盐催化剂的烃转化方法
公开(公告)号：US4022684A
公开(公告)日：1977-05-10
申请号：US680028
申请日：1976-04-26
CPC分类号： B01J21/16 , B01J23/75 , B01J23/755 , B01J23/892 , B01J37/031 , B01J37/10 , C10G49/08 , C07C2521/12 , C07C2527/045
摘要： The conversion of hydrocarbons in the presence of hydrogen occurs under hydrocarbon conversion conditions in the presence of a subgroup of a certain class of metal-substituted semi-crystalline aluminosilicates which are synthetic and which are predominantly ordered in two directions, that is, which are laminar or have a layered or stacked sheet structure. The metal substituted for the aluminum in the trioctahedral sites is nickel, cobalt, or mixtures thereof. The catalysts are preferably used in hydroisomerization and hydrocracking processes.
摘要翻译： 在氢气存在下，碳氢化合物的转化是在烃转化条件下，在合成的一类金属取代的半结晶硅铝酸盐的亚组存在下进行的，其主要是沿两个方向排列，即层流 或具有层状或层叠的片状结构。 取代三八面体位置的铝的金属是镍，钴或其混合物。 催化剂优选用于加氢异构化和加氢裂化方法。
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公开(公告)号：US3966642A
公开(公告)日：1976-06-29
申请号：US461907
申请日：1974-04-18
CPC分类号： B01J23/892 , B01J21/16 , B01J23/755 , B01J35/002 , B01J37/031 , C07C4/06 , C07C5/2791 , C10G47/12 , C07C2521/12 , C07C2527/045
摘要： The conversion of hydrocarbons in the presence of hydrogen occurs under hydrocarbon conversion conditions in the presence of a subgroup of a certain class of metal-substituted semi-crystalline aluminosilicates which are synthetic and which are predominantly ordered in two directions, that is, which are laminar or have a layered or stacked sheet structure. The metal substituted for the aluminum in the trioctahedral sites is nickel, cobalt, or mixtures thereof. Hydrocarbon conversion catalysts are also claimed comprising the metal-substituted laminar 2:1 layer lattice aluminosilicate minerals containing in addition a hydrogenation component such as palladium. The catalysts are preferably used in hydroisomerization and hydrocracking processes.
摘要翻译： 在氢气存在下，碳氢化合物的转化是在烃转化条件下，在合成的一类金属取代的半结晶硅铝酸盐的亚组存在下进行的，其主要是沿两个方向排列，即层流 或具有层状或层叠的片状结构。 取代三八面体位置的铝的金属是镍，钴或其混合物。 还要求的是烃转化催化剂，其还包含另外含有氢化组分如钯的金属取代的层状2层晶格硅铝酸盐矿物。 催化剂优选用于加氢异构化和加氢裂化方法。
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公开(公告)号：US3947483A
公开(公告)日：1976-03-30
申请号：US532848
申请日：1974-12-16
CPC分类号： B01J21/16 , B01J23/755 , B01J23/892 , C07C1/0435 , C07C2521/16
摘要： The conversion of carbon monoxide and hydrogen to produce methane is catalyzed by a layered complex metal silicate composition characterized as having repeating units of the structural formula[(1-x)Ni.sup.a + xRu.sup.b ].sub.n (OH).sub.4 Si.sub.2 O.sub.5.wH.sub.2 Owhere x is a number from 0 to 1, this number expressing the atomic fraction of the metals nickel and ruthenium, a is the valence of nickel, b is the valence of ruthenium, n is a number equal in value to that defined by the ratio6/[a(1-x) + bx]And w is a number ranging from 0 to 4. Nickel chrysotile is the preferred catalyst.
摘要翻译： 通过层状复合金属硅酸盐组合物催化一氧化碳和氢气转化产生甲烷的催化剂，其特征在于具有结构式[（1-X）N y + x（OH）4 Si 2 O 5·wH 2 O的重复单元，其中x是数 从0到1，这个数字表示金属镍和钌的原子分数，a是镍的化合价，b是钌的化合价，n是数值等于6 / [A（ 1-X）+ BX]，W是从0到4的范围。镍温石棉是优选的催化剂。
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公开(公告)号：US07253224B2
公开(公告)日：2007-08-07
申请号：US10208863
申请日：2002-08-01
CPC分类号： B41M5/5218 , B01D19/0409 , B01J20/103 , B01J20/28004 , B01J20/28016 , B01J20/28026 , B01J20/28033 , B01J20/28057 , C01B33/18 , C01B33/193 , C01P2002/54 , C01P2004/61 , C01P2006/12 , C01P2006/90 , C08K3/36 , C08K9/06 , C09C1/3054 , C09C1/3081 , C09D7/42 , C09D7/43 , C09D7/62 , C09D7/69 , C08L21/00
摘要： A silica-based particulate material that may contain less than 5 wt. % of a multivalent cation and a method of preparing such a silica-based particulate material. The silica-based particulate material may be characterized as having a median particle size of at least 20 μm, a BET surface area of at least 90 m2/g, and a pH of at least 9.5; or as having a median particle size of up to 20 μm and a pH of at least 10. The silica-based particulate material may be used to make hydrophobic silica-based particulates, which may be characterized as having a pH of at least 10.5.
摘要翻译： 二氧化硅基颗粒材料可以含有小于5wt。 ％的多价阳离子和制备这种二氧化硅基颗粒材料的方法。 二氧化硅基颗粒材料的特征在于中值粒径至少为20μm，BET表面积至少为90m 2 / g，pH值至少为9.5; 或具有至多20μm的中值粒径和至少为10的pH。二氧化硅基颗粒材料可用于制备疏水性二氧化硅基颗粒，其可以表征为具有至少10.5的pH。
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公开(公告)号：US6086669A
公开(公告)日：2000-07-11
申请号：US58393
申请日：1998-04-09
CPC分类号： C08K9/12 , C01B33/18 , C09C1/3063 , C01P2006/20
摘要： Describes a free flowing particulate composition comprising, in combination, particulate amorphous precipitated silica, e.g., in the form of granules, hydrocarbon process oil, e.g., an aromatic process oil, and organic carboxylic acid having from 2 to 30 carbon atoms, e.g., stearic acid. The hydrocarbon process oil and organic carboxylic acid are sorbed on the silica and are present in amounts sufficient to measurably improve the dispersibility of the particulate amorphous precipitated silica into an elastomer as measured by percent white area. Optionally, an organosilane coupling agent may also be present in said composition. The free flowing particulate composition of the present invention is useful in reinforcing elastomers, e.g., rubbers used in vehicle tires and the soles of athletic foot wear.
摘要翻译： 描述了一种自由流动的颗粒组合物，其组合包含颗粒状无定形沉淀二氧化硅，例如颗粒形式的烃工艺油，例如芳族加工油和具有2-30个碳原子的有机羧酸，例如硬脂酸 酸。 烃工艺油和有机羧酸在二氧化硅上吸附，并且以足以可测量地提高颗粒状无定形沉淀二氧化硅在弹性体中的分散性的量存在于白色面积百分比上。 任选地，有机硅烷偶联剂也可以存在于所述组合物中。 本发明的自由流动的颗粒组合物可用于增强弹性体，例如车辆轮胎中使用的橡胶和运动鞋底的鞋底。
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48.发明授权
公开(公告)号：US5739197A
公开(公告)日：1998-04-14
申请号：US769969
申请日：1996-12-19
IPC分类号： C01B33/193 , C08K3/36
CPC分类号： C01B33/193 , C08K3/36 , C01P2002/02 , C01P2004/51 , C01P2004/61 , C01P2006/12 , C01P2006/14 , C01P2006/16
摘要： Amorphous precipitated silica is characterized by a standard white area of less than 0.8 percent. The low standard white area is a characteristic of the silica which is indicative of high (i.e., very effective) dispersion when the silica is incorporated into organic rubber compositions which are cured. Cured organic rubber compositions comprising amorphous precipitated silica exhibit low white areas which indicate high dispersion of the silica in the compositions.
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公开(公告)号：US4409399A
公开(公告)日：1983-10-11
申请号：US328639
申请日：1981-12-09
IPC分类号： B01J23/755 , B01J23/78 , C07C85/06 , C07C85/08
CPC分类号： B01J23/755 , B01J23/78
摘要： A process for producing aliphatic amines which comprises reacting an aliphatic alcohol or an aliphatic aldehyde with an aminating agent selected from the group consisting of ammonia, a primary amine and a secondary amine in the liquid phase in the presence of an unsupported catalyst consisting essentially of (1) copper oxide or copper hydroxide (2) nickel oxide or nickel hydroxide, and, optionally, (3) an oxide or an hydroxide of a Group II A metal.
摘要翻译： 一种制备脂族胺的方法，其包括使脂族醇或脂族醛与在液相中的氨，胺和仲胺的胺化剂在无载体催化剂存在下反应，所述催化剂基本上由（ 1）氧化铜或氢氧化铜（2）氧化镍或氢氧化镍，和任选的（3）IIA族金属的氧化物或氢氧化物。
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公开(公告)号：US4394296A
公开(公告)日：1983-07-19
申请号：US289456
申请日：1981-08-03
申请人： Ajay M. Madgavkar , Harold E. Swift
发明人： Ajay M. Madgavkar , Harold E. Swift
CPC分类号： B01J27/12 , C07C2527/1213
摘要： A three-component catalyst is prepared comprising a particulate silica adsorbent with boron trifluoride and water adsorbed on the silica. The silica-water-boron trifluoride catalyst is used in hydrocarbon conversion reactions such as the oligomerization of 1-decene to a product predominating in the trimer and tetramer.
摘要翻译： 制备三分子催化剂，其包含三氟化硅颗粒状二氧化硅吸附剂和吸附在二氧化硅上的水。 二氧化硅 - 水 - 三氟化硼催化剂用于烃转化反应，例如1-癸烯的低聚反应，以三聚体和四聚体为主的产物。
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