Abstract:
An activated carbon sorbent composition comprising activated carbon and a passivation agent, wherein the activated carbon sorbent composition exhibits reduced self-heating or auto-ignition properties as compared to the activated carbon. The activated carbon sorbent composition may be utilized to sequester contaminants such as mercury from a flue gas stream. The passivation agent includes a sulfur species, and may be a sulfur oxide compound, a sulfide compound, or an organic sulfur compound. Methods for the manufacture of the activated carbon sorbent composition and for the sequestration of contaminants in a flue gas stream using the composition are also disclosed.
Abstract:
An activated carbon sorbent composition comprising activated carbon and a passivation agent, wherein the activated carbon sorbent composition exhibits reduced self-heating or auto-ignition properties as compared to the activated carbon. The activated carbon sorbent composition may be utilized to sequester contaminants such as mercury from a flue gas stream. The passivation agent includes a sulfur species, and may be a sulfur oxide compound, a sulfide compound, or an organic sulfur compound. Methods for the manufacture of the activated carbon sorbent composition and for the sequestration of contaminants in a flue gas stream using the composition are also disclosed.
Abstract:
A process for the elimination of heavy metals, in particular mercury and possibly arsenic and lead, present in a gaseous or liquid effluent by means of a fixed bed process using an adsorbent in the form of monolithic or supported extrudates, said extrudates being characterized by a length h and a section comprising at least three lobes. The adsorbent is composed of at least one active phase based on sulphur in the elemental form or in the form of a metallic sulphide. The process is advantageously applicable to the treatment of gas of industrial origin, synthesis gas, natural gas, gas phase condensates and liquid hydrocarbon feeds.
Abstract:
An adsorbent for carbon dioxide may include a mesoporous inorganic oxide having a crystalline halide of an alkali metal or alkaline earth metal supported thereto and a chemical species containing phosphorous (P), sulfur(S), or boron (B) supported thereto.
Abstract:
An adsorbent for carbon dioxide may include a composite metal oxide including a divalent first metal (M1), a trivalent second metal (M2), and an element (A) with an electronegativity of about 2.0 to about 4.0. The composite metal oxide may have an amorphous structure. A method of manufacturing the adsorbent for carbon dioxide and a capture module for carbon dioxide including the adsorbent for carbon dioxide are also disclosed.
Abstract:
The present invention is a method and material for using a sorbent material to capture and stabilize mercury. The method for using sorbent material to capture and stabilize mercury contains the following steps. First, the sorbent material is provided. The sorbent material, in one embodiment, is nano-particles. In a preferred embodiment, the nano-particles are unstabilized nano-Se. Next, the sorbent material is exposed to mercury in an environment. As a result, the sorbent material captures and stabilizes mercury from the environment. In the preferred embodiment, the environment is an indoor space in which a fluorescent has broken.
Abstract:
An adsorbent suitable for heavy metal absorption is described, comprising a thiol functionalised support containing a stabilising amount of an alkaline metal reacted with said thiol functionality. The adsorbent may be used to remove heavy metals e.g. mercury and/or arsenic, from wastewater streams such as produced water or flue gas scrubber waters.
Abstract:
The use of a sulfur-impregnated organoclay provides a mercury or arsenic removal media having increased reactivity, stability, and mercury removal ability. The Hg/As removal media described herein is prepared by impregnating an organophilic clay with elemental (free state) sulfur. Alternatively, the clay can be made organophilic by onium ion reaction prior to or simultaneously with impregnating the organoclay with sulfur.
Abstract:
A flue gas control system of a coal combustion boiler according to the present invention includes: an HCI atomizer (32) that sprays hydrogen chloride (33) to flue gas from a coal combustion boiler (11) that uses coal as a fuel (F); NOx removing apparatus (13) that removes nitrogen oxides by ammonia denitration by adding ammonia (12) to the flue gas after spraying hydrogen chloride and oxidizes mercury; an air preheater (14) that recovers heat in the gas after removal of nitrogen oxides; a precipitator (15) that removes particulates in the gas; an activated carbon atomizer (22) that sprays activated carbon (22a) into the gas after particulate collection; a bag filter (21) that collects activated carbon having adsorbed mercury; a desulfurizer (16) that removes sulfur oxides in the flue gas after removal of activated carbon; a stack (17) that discharges the gas which has undergone desulfurization to outside; and an ORP meter (19) that measures an oxidation reduction potential for feeding air to a slurry absorbent in the desulfurizer (16).