摘要:
There is provided a sample preparation device and method for preparing a sample of liquid for detection of impurities. First (40) and second (38) electrodes are provided, located for immersion in a liquid under test. A semipermeable membrane (42) is positioned to protect the first electrode (40) from a body of liquid under test (32). The semipermeable membrane allows the liquid under test to pass therethrough to reach the first electrode, while preventing solids carried in the liquid from reaching the first electrode, the first electrode being positioned to affect the liquid under test in the vicinity of a sensor (36). Particular embodiments feature a hydrophilic membrane to protect the electrodes from suspended solids in the sample, a thin electrode assembly to achieve a faster response and the addition of a heater for temperature control to achieve consistent detection conditions and improved anti-fouling properties.
摘要:
A method for determining the reducing agent concentration (NH3) in the exhaust-gas flow of an internal combustion engine, using a zeolitic NH3 gas sensor that supplies a base measuring value, which is initially corrected by an offset value and a correction value that depends on the H2O concentration of the exhaust gas to form an intermediate value. The intermediate value is subsequently corrected by an additional value that depends on the NOx and NH3 concentration of the exhaust gas. In particular at or above the limits for the operating range, the accuracy of the method increases for one of the following conditions: gas compositions with NOx concentrations >500 ppm, extremely low NH3 concentrations 100 ppm.
摘要:
Method and apparatus for measuring a water concentration in ammonia, comprising using ammonia having a water concentration of 10 ppm or less as a reference gas, introducing the ammonia at a constant flow rate into a multi-reflection long optical path gas cell, and measuring infrared absorption intensity of water at at least one measurement wave number in the range of from 3,500 to 4,000 cmnull1, from 2,600 to 3,100 cmnull1, or from 1,900 to 2,400 cmnull1 at which infrared absorptions of ammonia and water do not overlap. According to the present invention, analysis of water in a low concentration range of 10 ppm or less in ammonia gas and liquefied ammonia can be performed in a simple and convenient manner.
摘要:
The present invention provides an ammonia sensor having a pH sensitive fluorophore immobilized in a hydrophobic polymer, wherein the fluorophore can react quantitatively with ammonia and the transducing moiety of the fluorophore is neutrally charged when deprotonated. The present invention also provides a method for detecting ammonia using the ammonia sensor and optical sensing devices that include the ammonia sensor.
摘要:
A device for sensing ammonia (NH.sub.3) and nitrogen oxide (NO.sub.x) gases comprising: a sensor for detecting said ammonia and said nitrogen oxide gases, said sensor including a substrate and a layer consisting of cuprate material for detection of said ammonia and said nitrogen oxide gases, wherein said layer of cuprate material is selected from the group consisting of Y:Ba:Cu:O (YBCO) and Bi:Sr:Ca:Cu:O (BSCCO); a sensor holder for supporting said sensor; a perforated cap positioned over said sensor, said perforated cap having openings for passage of said ammonia and said nitrogen oxide gases to said sensor; a detection circuit communicating with said sensor for measuring output from said sensor; and a display or recording device connected to said detection circuit for displaying or recording a concentration of said ammonia and said nitrogen oxide gases based on the output from said sensor.
摘要:
There are described a simple examination method of infection with Helicobacter pylori possibly presenting in a gastric mucosa, and a device therefor. The examination is conducted by collecting gas in gastric cavity, and measuring mainly ammonia and additionally organic amines which are generated due to activities of the bacilli. The measurement is carried out by leading the gas in gastric cavity into oral cavity by vomiting-reflex, and sucking the gas by a metering suction pump through a gas detection tube to read-out a length of color-changed area in the gas detection tube.
摘要:
For the measurement of gas, vapor, or aerosol fractions of a measured gas, the fraction to be determined is absorbed in a reaction solution, and a change of resistance from a reaction between the fraction and the reaction solution is determined as the measured variable by an ohmmeter, using electrodes in the reaction solution. The measured gas entering a test container through a sealing unit tight to the reaction solution and passing the medium to be determined, is improved with regard to all-purpose use and convenient measurement. This is done pursuant to the invention by placing the reaction solution in a disposable test container that can be inserted or connected interchangeably to the measuring device which has electrodes. The test container is sealed, at least at one end, with a sealing unit that is permeable to the medium to be determined and impermeable to the reaction solution.
摘要:
The invention is directed to an electrochemical measuring cell for determining ammonia and its derivatives in a gaseous or liquid measuring sample. The measuring cell has at least one anode and at least one cathode which are disposed in an electrolyte chamber filled with a soluble electrolyte. The electrolyte chamber is closed off in the direction facing toward the measuring sample by a permeable membrane. The measuring cell provides a more selective ammonia sensor having the following advantages: a short response time, a linear response and exhibits the lowest possible tendency toward drift. The electrolyte of the measuring cell is so configured that the reaction products of the measuring reaction do not affect subsequent measurements. For this purpose the measuring cell, which operates in an amperometric measuring mode, contains a soluble non-oxidizable reagent in the electrolyte which reacts completely with ammonia to form an oxidizable product which is convertible by its oxidation into non-oxidizable soluble secondary products which are chemically and electrochemically inert.
摘要:
An object of the present invention is to detect ammonia with high sensitivity and high selectivity using a nanomechanical sensor with a structure that is as simple as possible. A method for detecting ammonia according to an embodiment of the present invention comprises supplying a sample gas possibly containing ammonia to a nanomechanical sensor that detects a stress or a displacement using poly(methyl vinyl ether-alt-maleic anhydride) as a material of a receptor layer, and detecting presence or absence of ammonia or a content of ammonia in the sample gas based on an output signal from the nanomechanical sensor, in which the sample gas is a humidified sample gas with controlled relative humidity.
摘要:
An exhaust stream monitoring system for a photolithography track of an IC fabrication process comprises a reaction chamber including a housing, an inflow port and an outflow port, the housing containing a thermal plate for heating a semiconductor process wafer for a predetermined amount of time. An influent pipe coupled to the inflow port supplies a photoresist adhesion promoter in a gaseous form to the reaction chamber. An effluent pipe coupled to the outflow port is operative to remove byproducts from the reaction chamber as an exhaust stream. At least one gas sensor manifold assembly is coupled to the effluent pipe for monitoring the exhaust stream from the reaction chamber to detect presence of one or more byproducts of a reaction between the photoresist adhesion promoter and the semiconductor process wafer.