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公开(公告)号：US4814543A
公开(公告)日：1989-03-21
申请号：US138749
申请日：1987-12-28
CPC分类号： C10G45/64 , B01J29/064 , B01J29/67 , B01J29/7484 , B01J29/7492 , C07C5/2791 , B01J2229/42
摘要： The present invention includes a process and catalyst composition for paraffinic isomerization of a hydrocarbon feedstock which has a paraffin content having no more than 20 carbon atoms per molecule. The feedstock is contacted with a crystalline aluminosilicate zeolite catalyst having pore openings defined by: (1) a ratio of sorption of n-hexane to o-xylene, on a volume percent basis, of greater than about 3, which sorption is determined at a P/P.sub.o of 0.1 and at a temperature of 50.degree. C. for n-hexane and 80.degree. C. for o-xylene and (2) by the ability of selectively cracking 3-methylpentane (3MP) in preference to the doubly branched 2,3-dimethylbutane (DMB) at 1000.degree. F. and 1 atmosphere pressure from a 1/1/1 weight ratio mixture of n-hexane/3-methyl-pentane/2,3-dimethylbutane, with the ratio of rate constants k.sub.3MP/ k.sub.DMB determined at a temperature of 1000.degree. F. being in excess of about 2, e.g., ZSM-22, ZSM-23, AXM-35 and mixtures thereof, in combination with a Group VIII metal, and having a zeolite SiO.sub.2 /Al.sub.2 O.sub.3 ratio of at least about 20:1 at a temperature and pressure suitable for isomerization.
摘要翻译： 本发明包括用于烃原料的链烷烃异构化的方法和催化剂组合物，其具有每分子具有不超过20个碳原子的链烷烃含量。 原料与具有孔开口的结晶铝硅酸盐沸石催化剂接触，所述沸石催化剂的定义如下：（1）正丁烷与邻二甲苯的吸附比例，以体积百分数计，大于约3，该吸附在 P / Po为0.1，温度为50℃，正己烷和80℃为邻二甲苯，（2）选择性裂解3-甲基戊烷（3MP）优于双支链2 ，三甲基丁烷（DMB）在1000°F和1大气压下，由正己烷/ 3-甲基戊烷/ 2,3-二甲基丁烷的1/1/1重量比混合物与速率常数比例k3MP / kDMB在1000°F的温度下测定为超过约2，例如ZSM-22，ZSM-23，AXM-35及其混合物，与VIII族金属组合，并具有SiO 2 / Al 2 O 3沸石 在适于异构化的温度和压力下至少约20:1的比例。
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52.发明授权Shape-selective conversion of organic feedstock using clathrate group tectosilicates 失效有机原料的形态选择性转化使用包合物组织硅酸盐
公开(公告)号：US4773987A
公开(公告)日：1988-09-27
申请号：US36825
申请日：1987-04-10
摘要： This invention relates to an efficient process for shape-selective conversion of organic feedstock with a catalyst comprising a Clathrate Group tectosilicate such as ZSM-39 and a highly siliceous, shape selective zeolite such as ZSM-5. In one embodiment, a stabilized, dewaxed lube stock is prepared by catalytically dewaxing a hydrocrackate.
摘要翻译： 本发明涉及一种用含有诸如ZSM-39的包合物组合硅酸盐催化剂和高度硅质的形状选择性沸石如ZSM-5的催化剂对有机原料进行形态选择性转化的有效方法。 在一个实施方案中，通过催化脱蜡加氢裂化剂制备稳定的脱蜡润滑剂原料。
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公开(公告)号：US4740649A
公开(公告)日：1988-04-26
申请号：US1134
申请日：1987-01-07
申请人： Pochen Chu , William E. Garwood
发明人： Pochen Chu , William E. Garwood
CPC分类号： C07C2/12 , B01J29/40 , C10G11/05 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/80 , C07C2529/40
摘要： Feedstock comprising aromatic compounds is converted by isomerization, alkylation, disproportionation or transalkylation to product comprising aromatic compounds which differs from the feedstock over catalyst having been prepared by reacting a high-silica zeolite with an acidic inorganic oxide in the presence of water.
摘要翻译： 包含芳族化合物的原料通过异构化，烷基化，歧化或烷基转移转化为含有芳族化合物的产物，其与原料相比，催化剂不同于通过在水存在下使高硅沸石与酸性无机氧化物反应而制备。
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公开(公告)号：US4717465A
公开(公告)日：1988-01-05
申请号：US915935
申请日：1986-10-06
申请人： Nai Y. Chen , William E. Garwood
发明人： Nai Y. Chen , William E. Garwood
CPC分类号： B01J29/7484 , C10G45/64 , B01J29/7284 , B01J29/7684
摘要： A novel process is disclosed for the production of high boiling jet fuels which comprises contacting a chargestock with an end boiling point of about 750.degree. F. with ZSM-22 under carefully controlled conditions of temperature and pressure and blending the 330.degree. F. plus fraction with a conventional jet fuel in order to obtain a product having acceptable jet fuel properties and having a high boiling range.
摘要翻译： 公开了一种用于生产高沸点喷气燃料的新方法，其包括在精心控制的温度和压力条件下将具有约750°F的终沸点的电荷料与ZSM-22接触，并将330°F加级分 使用常规的喷气燃料，以获得具有可接受的喷气燃料性能并具有高沸点范围的产品。
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公开(公告)号：US4665253A
公开(公告)日：1987-05-12
申请号：US792346
申请日：1985-10-29
申请人： Pochen Chu , William E. Garwood
发明人： Pochen Chu , William E. Garwood
CPC分类号： C07C2/12 , B01J29/40 , C10G11/05 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/80 , C07C2529/40
摘要： Feedstock comprising aromatic compounds is converted by isomerization, alkylation, disproportionation or transalkylation to product comprising aromatic compounds which differs from the feedstock over catalyst having been prepared by reacting a high-silica zeolite with an acidic inorganic oxide in the presence of water.
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56.发明授权Viscosity index improvement in dewaxed lube basestock by partial desulfurization in hydrotreat bed 失效加氢处理床部分脱硫脱蜡润滑油基础油的粘度指数提高
公开(公告)号：US4564440A
公开(公告)日：1986-01-14
申请号：US512510
申请日：1983-07-11
CPC分类号： C10G67/0409 , C10G2400/10
摘要： Partial desulfurization in the range of about 30-90% during hydrotreating of a dewaxed lube oil basestock provides an increase in viscosity index of up to five numbers with less than about 5 wt. % yield loss, a consequence of the desulfurized compounds staying in the lube boiling range.
摘要翻译： 在脱蜡润滑油基础油的加氢处理期间，约30-90％范围内的部分脱硫使粘度指数提高至多5个数量，少于约5wt。 产率损失百分比，这是脱硫化合物在润滑油沸腾范围内的结果。
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公开(公告)号：US4283271A
公开(公告)日：1981-08-11
申请号：US158980
申请日：1980-06-12
申请人： William E. Garwood , Murray R. Silk
发明人： William E. Garwood , Murray R. Silk
CPC分类号： C10G65/12 , C10G2400/10
摘要： Hydrocracked, low pour lubricating oils of good stability are manufactured by passing a suitable hydrocarbon feed sequentially through a hydrocracking zone, a catalytic dewaxing zone, and a hydrotreating zone, all at high pressure and in that order, and with separation of hydrocrackate from recycle hydrogen prior to dewaxing. Only clean makeup hydrogen is fed to the dewaxer, passed through the hydrotreater, and then on to the hydrocracker, thereby providing an exceptionally efficient process.
摘要翻译： 通过使合适的烃进料依次通过加氢裂化区，催化脱蜡区和加氢处理区，全部以高压和依次顺序，并将氢化裂解物从再循环氢气中分离出来制备具有良好稳定性的加氢裂化低倾点润滑油 脱蜡之前。 只有干净的补充氢气才能进入脱蜡机，通过加氢处理器，然后再加到加氢裂化器上，从而提供了非常有效的工艺。
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公开(公告)号：US4176050A
公开(公告)日：1979-11-27
申请号：US966419
申请日：1978-12-04
申请人： Nai Y. Chen , William E. Garwood , Alan W. Peters
发明人： Nai Y. Chen , William E. Garwood , Alan W. Peters
IPC分类号： C10G73/02 , B01J29/40 , B01J29/44 , C10G29/04 , C10G45/64 , C10G13/02 , B01J29/28 , C07C5/24
CPC分类号： B01J29/44 , B01J29/40 , C10G2400/10
摘要： Waxy distillate lubricating oil stocks suitable for the preparation, by conventional unit processes, of high V.I., low pour point lubricating oils, are advantageously catalytically dewaxed with macrocrystalline ZSM-5 (crystallites larger than 2 microns) preferably associated with a hydrogenation metal such as platinum or palladium.
摘要翻译： 适用于通过常规单元方法制备高VI，低倾点润滑油的蜡状馏出物润滑油原料有利地用优选与氢化金属如铂的微晶ZSM-5（晶体大于2微米）进行催化脱蜡 或钯。
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59.发明授权
公开(公告)号：US4172843A
公开(公告)日：1979-10-30
申请号：US926987
申请日：1978-07-21
CPC分类号： B01J29/46 , B01J29/40 , C07C1/044 , B01J2229/26 , B01J2229/42 , C07C2529/072
摘要： An improved method is disclosed for converting synthesis gas to hydrocarbon mixtures wherein the syngas is contacted with a special catalyst comprising a crystalline zeolite having a silica-to-alumina ratio of greater than 200 (including zeolites containing essentially no alumina) and an (R.sub.2 O+ M.sub.2 /.sub.n O): SiO.sub.2 ratio of less than 1.1:1 where M is a metal other than a metal of Group IIIA, n is the valence of said metal, and R is an alkyl ammonium radical, said organosilicate being characterized by a specified x-ray diffraction pattern. In a specific embodiment of this invention, synthesis gas is contacted with a catalyst comprising an intimate mixture of said crystalline zeolite catalyst and iron-containing, Fischer-Tropsch catalyst to produce a liquid hydrocarbon product having a boiling range of less than 400.degree. F. at a 90 percent overhead and being a predominantly olefinic product, wherein the structure of the olefins is substantially branched chain with internally-positioned double bonds.
摘要翻译： 公开了一种用于将合成气转化为烃混合物的改进方法，其中合成气与包含二氧化硅与氧化铝之比大于200的结晶沸石（包括基本上不含氧化铝的沸石）和（R2O + M2 / nO）：SiO 2比小于1.1:1，其中M是除IIIA族金属以外的金属，n是所述金属的化合价，R是烷基铵基团，所述有机硅酸盐的特征在于指定的x- 射线衍射图。 在本发明的具体实施方案中，使合成气与包含所述结晶沸石催化剂和含铁的费 - 托催化剂的紧密混合物的催化剂接触，以产生沸点低于400°F的液体烃产物。 在90％的开销下，并且主要是烯烃产物，其中烯烃的结构基本上是支链的，内部定位的双键。
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公开(公告)号：US4126644A
公开(公告)日：1978-11-21
申请号：US732235
申请日：1976-10-14
IPC分类号： C10G35/095 , C10G59/06 , C10L1/06 , C07C3/62 , C07C1/02
CPC分类号： C10G59/06 , C10G35/095 , C10L1/06 , Y10S208/95
摘要： The product of Fischer-Tropsch synthesis is separated to recover a C.sub.5 -400.degree. F liquid fraction which is thereafter upgraded to a higher octane gasoline fraction and a low-pour, high diesel index fuel oil by a "dense phase" process using HZSM-5 and related zeolites as catalysts.
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