摘要:
The present invention relates to a binder for composite materials comprising cellulose- or lignocellulose-containing materials, which is based on the components (i) at least one binder from the series consisting of organic resins, isocyanates, natural or near-natural binders and (ii) at least one composition based on an aminoalkylsilane. The invention furthermore relates to a composite material which is at least based on a cellulose- or lignocellulose-containing material and the abovementioned binder, a process for the production of such a composite material and the use of the binder system according to the invention for the production of wood-based materials.
摘要:
The present invention provides a composition based on the reaction at least of the following components: (i) a glycidyloxypropylalkoxysilane, (ii) an aqueous silica sol having an SiO2 content of >20% by weight, (iii) an organic acid hydrolysis catalyst, and (iv) n-propyl zirconate, butyl titanate or titanium acetylacetonate as crosslinker, a process for its preparation, and the use thereof, particularly as a composition for scratch resistant coatings, and also provides articles thus coated.
摘要:
The invention relates to a composition containing olefinically functionalized siloxane oligomers which are derived from olefinically functionalized alkoxy silanes and optionally alkoxy silanes functionalized with saturated hydrocarbons and optionally a tetra alkoxysilane, at most comprising an olefinic group on the silicon atom and which has a reduced chloride content and a weight average molecular mass (Mw) of more than 315 g/mol.
摘要:
The present invention relates to a composite material based on (a) a cellulose- or lignocellulose-containing material and (b) a composite as a binder, the composite resulting from the reaction of at least the components (i) a glycidyloxypropylalkoxysilane, (ii) an aqueous silica sol having a solids content of >20% by weight, (iii) an organic acid as a hydrolysis catalyst and (iv) n-propyl zirconate, butyl titanate or titanium acetylacetonate as a crosslinking agent. The present invention furthermore relates to a process for the production of said composite materials and the use of a composite (b) as a binder for the production of wood-based materials.
摘要:
The invention concerns solutions of alkoxides containing titanium and/or zirconium and/or hafnium and magnesium and/or calcium and/or strontium and/or barium of general formula (I): [MII(OR)2-y(OR1)y]n.[MIV(OR1)4-z(OR)2], in which: MII means magnesium and/or calcium and/or strontium and/or barium; MIV titanium and/or zirconium and/or hafnium; R is an alkyl group with 1 to 18 carbon atoms; R1 is an alkyl group with 1 to 18 carbon atoms, y has a value of between 0 to 2; z has a value of 0 and 4; and n is a number between 0.001 and 3, with the exception that n cannot be 1 when y is 2 and z is 0, or when y is 0 and z is 4. The invention further concerns the production of these alkoxides and their use.
摘要:
A mixture of organoalkoxysiloxanes of formula I: wherein R and R″ are identical or different and are methyl, ethyl, vinyl, n-propyl, i-propyl, &ggr;-chloropropyl, n-butyl, i-butyl, n-pentyl, i-pentyl, n-hexyl, i-hexyl, n-heptyl, i-heptyl, n-octyl, i-octyl, hexadecyl, octadecyl or alkoxy, R′ represents methyl or ethyl, n and m are identical or different and each is 0 or an integer ranging from 1 to 20, on the condition that (n+m)≧2, is prepared by: reacting in a first stage the constituents of (i) an organotrichlorosilane or a mixture of organotrichlorosilanes or a mixture of at least one organotrichlorosilane and tetrachlorosilane, (ii) water and (iii) alcohol, combined in a molar ratio (i):(ii):(iii) of 1:(0.59 to 0.95):(0.5 to 100), at a temperature of 0 to 150° C., which produces hydrogen chloride as a product which is removed from the system and the crude organoalkoxysiloxane product is transferred proportionately to the reaction distillation column of a subsequent second stage after an average dwell time of 0.5 to 180 minutes; and conducting reaction and distillation in the reaction distillation column in a second stage in which volatile constituents are withdrawn from the top of the column and the organoalkoxysiloxane product is withdrawn as a bottom product, wherein the reaction-distillation column is operated at a bottom temperature of 50 to 200° C.
摘要:
The invention relates to a process for dechlorinating alkylsilanes and siloxanes, and also to the use of basic anion exchanger resins for dechlorinating alkyl silanes and alkylsiloxanes.
摘要:
The present invention relates to a hydraulically setting mixture comprising: a) 6% to 25% by weight of cement, b) 50% to 90% by weight of at least one aggregate, and c) 0.01% to 8% by weight of at least one fluoroorganyl-substituted silicon compound, and also to materials produced from this mixture, more particularly components, concrete articles or mouldings. The invention further relates to the use of a hydraulically setting mixture of the invention for producing materials, more particularly components, concrete articles or mouldings, for example as facing concrete, where the surface of the materials exhibits only relatively low soiling tendency (“easy-to-clean” property) even on abrasion.
摘要:
The present invention relates to a curable mixture suitable for obtaining “easy-to-clean” properties in the cured mixture, comprising at least one mineral binder, a powder comprising at least one fluoroorganyl-substituted silicon compound encapsulated in a water-soluble polymer, the amount of the silicon compound being 0.001% to 8% by weight, based on the present mixture, and optionally further adjuvants, and also to a process for preparing the mixture and to the use thereof. The invention further relates to a water-redispersible powder and also to a corresponding intermediate for use in the curable mixture in order to obtain “easy-to-clean” properties in the cured mixture. Also claimed, furthermore, is a process for preparing the powder, and the use thereof.