公开(公告)号：US20160083835A1

公开(公告)日：2016-03-24

申请号：US14812562

申请日：2015-07-29

Applicant: CORNING INCORPORATED

Inventor： Kaveh Adib ,  Robert Alan Bellman ,  Charles Andrew Paulson ,  James Joseph Price

IPC: C23C16/30 ,  C23C16/40 ,  C23C16/32 ,  C23C16/34 ,  C23C16/36

CPC classification number: C23C16/308 ,  C23C16/30 ,  C23C16/325 ,  C23C16/345 ,  C23C16/36 ,  C23C16/402

Abstract: Embodiments of this disclosure pertain to a coating material comprising silicon and/or aluminum, hydrogen and any two or more of oxygen, nitrogen, carbon, and fluorine. The coating material exhibits a hardness of about 17 GPa or greater and an optical band gap of about 3.5 eV or greater. In some embodiments, the coating material includes, in atomic %, silicon and/or aluminum in an amount of about 40 or greater, hydrogen in an amount in the range from about 1 to about 25, nitrogen in an amount of about 30 or greater, oxygen in an amount in the range from about 0 to about 7.5, and carbon in an amount in the range from about 0 to about 10. The coating material may optionally include fluorine and/or boron. Articles including the coating material are also described and exhibit an average transmittance of about 85% or greater over an optical wavelength regime in the range from about 380 nm to about 720 nm and colorlessness.

Abstract translation: 本公开的实施方案涉及包含硅和/或铝，氢和氧，氮，碳和氟中的任何两种或更多种的涂料。 涂层材料表现出约17GPa或更大的硬度和约3.5eV或更大的光学带隙。 在一些实施方案中，涂层材料以原子％包含约40或更大量的硅和/或铝，其量为约1至约25，氮为约30或更大 ，量为约0至约7.5的量的氧，以及约0至约10的量的碳。涂层材料可任选地包括氟和/或硼。 还描述了包括涂料的制品，并且在约380nm至约720nm范围内的光波长范围内呈现约85％或更大的平均透射率和无色性。

公开(公告)号：US20140001076A1

公开(公告)日：2014-01-02

申请号：US13827732

申请日：2013-03-14

Applicant: CORNING INCORPORATED

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky ,  Robert Anthony Schaut ,  Paul Steven Danielson ,  Melinda Ann Drake ,  Robert Michael Morena ,  Kaveh Adib

IPC: B65D1/40

CPC classification number: B65D23/0814 ,  A61J1/1468 ,  B32B17/06 ,  B65D1/40 ,  B65D25/14 ,  C03C3/087 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/3405 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C08G73/105 ,  C08G73/1071 ,  C09D179/08 ,  C08K5/544

Abstract: Delamination resistant glass containers with heat-tolerant coatings are disclosed. In one embodiment, a glass container may include a glass body having an interior surface, an exterior surface and a wall thickness extending from the exterior surface to the interior surface. At least the interior surface of the glass body is delamination resistant. The glass container may further include a heat-tolerant coating positioned on at least a portion of the exterior surface of the glass body. The heat-tolerant coating may be thermally stable at temperatures greater than or equal to 260° C. for 30 minutes.

公开(公告)号：US12240782B2

公开(公告)日：2025-03-04

申请号：US17994522

申请日：2022-11-28

Applicant: CORNING INCORPORATED

Inventor： Kaveh Adib ,  Xiaoju Guo ,  Sean Thomas Ralph Locker ,  Lina Ma ,  Nicole Taylor Wiles

IPC: C03C3/095 ,  C03C3/097 ,  C03C4/02 ,  C03C21/00 ,  H05K5/03

Abstract: A glass composition includes SiO2, Al2O3, B2O3, alkali metal oxides, alkaline earth oxides, TiO2, CeO2, Fe2O3, and is provides a yellow-colored glass article.

公开(公告)号：US20240191099A1

公开(公告)日：2024-06-13

申请号：US18528916

申请日：2023-12-05

Applicant: CORNING INCORPORATED

Inventor： Kaveh Adib ,  Robert Alan Bellman ,  Philip Simon Brown ,  Theresa Chang ,  Christine Marie Mahoney Fahey ,  Dean Joseph Mastropietro ,  James Joseph Price ,  Shu Yuan

IPC: C09D183/04 ,  C03C17/245 ,  C03C17/25 ,  C03C17/34 ,  C09D5/00 ,  C09D5/16 ,  C23C14/10 ,  C23C14/22 ,  C23C14/58 ,  C23C18/12

CPC classification number: C09D183/04 ,  C03C17/245 ,  C03C17/25 ,  C03C17/3417 ,  C03C17/3435 ,  C09D5/006 ,  C09D5/1693 ,  C23C14/10 ,  C23C14/221 ,  C23C14/5846 ,  C23C18/1208 ,  C23C18/1295 ,  C03C2217/732 ,  C03C2217/78 ,  C03C2218/11 ,  C03C2218/151 ,  C03C2218/32

Abstract: Coated articles are described herein that include a surface-modifying layer that is fluorine-free. In aspects, the surface-modifying layer comprises a partial silica-like network having a ratio of Si—O—Si bonds to Si atoms in the anti-fingerprint coating from about 2 to about 3. Additionally or alternatively, the surface-modifying layer further comprises an alkyl silane at the exterior surface and bonded to a Si—O group in the silica-like network. Methods include evaporating a functionalized polyhedral oligomeric silsesquioxane onto a first major surface. Methods include impinging an ion beam on the first major surface. Alternatively, methods include disposing and heating a solution comprising a polysilazane or a polyhedral oligomeric silsesquioxane on a first major surface. In aspects, methods include reacting material at the first major surface with a alkyl silane.

公开(公告)号：US11999135B2

公开(公告)日：2024-06-04

申请号：US16639664

申请日：2018-08-20

Applicant: CORNING INCORPORATED

Inventor： Kaveh Adib ,  Indrani Bhattacharyya ,  Pei-Chen Chiang ,  Hong-goo Choi ,  Dae youn Kim ,  Jen-Chieh Lin ,  Prantik Mazumder ,  Pei-Lien Tseng

IPC: B32B17/10

CPC classification number: B32B17/1055 ,  B32B17/10036 ,  B32B2307/728

Abstract: Described herein are articles and methods of making articles, for example glass articles, comprising a thin sheet and a carrier, wherein the thin sheet and carrier are bonded together using a modification (coating) layer, for example a cationic polymer coating layer, and associated deposition methods, the carrier, or both, to control van der Waals, hydrogen and covalent bonding between the thin sheet and the carrier. The modification layer bonds the thin sheet and carrier together with sufficient bond strength to prevent delamination of the thin sheet and the carrier during high temperature (≤600° C.) processing while also preventing formation of a permanent bond between the sheets during such processing.

公开(公告)号：US11905203B2

公开(公告)日：2024-02-20

申请号：US18101668

申请日：2023-01-26

Applicant: CORNING INCORPORATED

Inventor： Kaveh Adib ,  Guangli Hu ,  William Joseph Hurley ,  Dana Ianson ,  Lin Lin ,  Santona Pal ,  James Joseph Price

IPC: B32B15/04 ,  B32B17/06 ,  C03C17/245 ,  C03C3/091 ,  C03C3/097 ,  C03C17/22

CPC classification number: C03C17/245 ,  C03C3/091 ,  C03C3/097 ,  C03C17/225 ,  C03C2217/281 ,  C03C2217/29 ,  C03C2217/78 ,  C03C2217/91 ,  C03C2218/155

Abstract: An article is described herein that includes: a substrate having a glass, glass-ceramic or a ceramic composition and comprising a primary surface; and a protective film disposed on the primary surface. The protective film comprises a thickness of greater than 1.5 microns and a maximum hardness of greater than 15 GPa at a depth of 500 nanometers, as measured on the film disposed on the substrate. Further, the protective film comprises a metal oxynitride that is graded such that an oxygen concentration in the film varies by 1.3 or more atomic %. In addition, the substrate comprises an elastic modulus less than an elastic modulus of the film.

公开(公告)号：US20230132277A1

公开(公告)日：2023-04-27

申请号：US18087234

申请日：2022-12-22

Applicant: CORNING INCORPORATED

Inventor： Kaveh Adib ,  Dana Craig Bookbinder ,  Theresa Chang ,  Paul Stephen Danielson ,  Steven Edward DeMartino ,  Melinda Ann Drake ,  Andrei Gennadyevich Fadeev ,  James Patrick Hamilton ,  Robert Michael Morena ,  Santona Pal ,  John Stephen Peanasky ,  Chandan Kumar Saha ,  Robert Anthony Schaut ,  Susan Lee Schiefelbein ,  Christopher Lee Timmons

IPC: C03C3/087 ,  B65D1/40 ,  A61J1/14 ,  C08G73/10 ,  C03C17/34 ,  C03C17/00 ,  C03C17/42 ,  C03C21/00 ,  C09D179/08 ,  C03B23/047 ,  C08K5/544 ,  B65D23/08 ,  C03C17/30 ,  C03C17/32 ,  B32B17/06 ,  B65D25/14

Abstract: Disclosed herein are delamination resistant glass pharmaceutical containers which may include a glass body having a Class HGA1 hydrolytic resistance when tested according to the ISO 720:1985 testing standard. The glass body may have an interior surface and an exterior surface. The interior surface of the glass body does not comprise a boron-rich layer when the glass body is in an as-formed condition. A heat-tolerant coating may be bonded to at least a portion of the exterior surface of the glass body. The heat-tolerant coating may have a coefficient of friction of less than about 0.7 and is thermally stable at a temperature of at least 250° C. for 30 minutes.

公开(公告)号：US20220234947A1

公开(公告)日：2022-07-28

申请号：US17610048

申请日：2020-05-13

Applicant: Corning Incorporated

Inventor： Kaveh Adib ,  Theresa Chang ,  Sean Patrick Coleman ,  Jiangwei Fei ,  Ying Wei ,  Christine Coulter Wolcott ,  Shu Yuan ,  Binwei Zhang ,  Chunhe Zhang

IPC: C03C17/30 ,  C09D183/06

Abstract: Various embodiments provide an article including a substrate and a coating thereon including a functionalized fluorine containing compound crosslinked with a multifunctional siloxane resin. A method of forming the article includes applying a multifunctional siloxane resin to a substrate, applying a functionalized fluorine containing compound to the substrate, and annealing the multifunctional siloxane resin and the functionalized fluorine containing compound.

公开(公告)号：US11123954B2

公开(公告)日：2021-09-21

申请号：US15921034

申请日：2018-03-14

Applicant: Corning Incorporated

Inventor： Kaveh Adib ,  Robert Alan Bellman ,  Dana Craig Bookbinder ,  Theresa Chang ,  Shiwen Liu ,  Robert George Manley ,  Prantik Mazumder

IPC: B32B7/06 ,  B32B37/26 ,  B32B17/06 ,  C03C17/22 ,  C03C23/00 ,  C03C27/06 ,  C03C27/10 ,  B32B7/02

Abstract: A method of controllably bonding a thin sheet having a thin sheet bonding surface with a carrier having a carrier bonding surface, by depositing a carbonaceous surface modification layer onto at least one of the thin sheet bonding surface and the carrier bonding surface, incorporating polar groups with the surface modification layer, and then bonding the thin sheet bonding surface to the carrier bonding surface via the surface modification layer. The surface modification layer may include a bulk carbonaceous layer having a first polar group concentration and a surface layer having a second polar group concentration, wherein the second polar group concentration is higher than the first polar group concentration. The surface modification layer deposition and the treatment thereof may be performed by plasma polymerization techniques.

公开(公告)号：US10822271B2

公开(公告)日：2020-11-03

申请号：US15974188

申请日：2018-05-08

Applicant: CORNING INCORPORATED ,  CORNING PRECISION MATERIALS CO., LTD.

Inventor： Kaveh Adib ,  Robert Alan Bellman ,  Yuhui Jin ,  Benedict Yorke Johnson ,  Timothy Edward Myers ,  Eric Louis Null ,  Jung-keun Oh ,  Charles Andrew Paulson ,  James Joseph Price ,  Florence Christine Monique Verrier ,  Jin-ah Yoo

IPC: C03C17/42 ,  C04B41/52 ,  C04B41/89 ,  H05K5/03 ,  H05K5/00 ,  C04B41/00 ,  C03C17/00

Abstract: An article that includes: a glass, glass-ceramic or ceramic substrate comprising a primary surface; at least one of an optical film and a scratch-resistant film disposed over the primary surface; and an easy-to-clean (ETC) coating comprising a fluorinated material that is disposed over an outer surface of the at least one of an optical film and a scratch-resistant film. The at least one of an optical film and a scratch-resistant film comprises an average hardness of 12 GPa or more. Further, the outer surface of the at least one of an optical film and a scratch-resistant film comprises a surface roughness (Rq) of less than 1.0 nm. Further, the at least one of an optical film and a scratch-resistant film comprises a total thickness of about 500 nm or more.