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51.发明授权Shape-selective conversion of organic feedstock using clathrate group tectosilicates 失效有机原料的形态选择性转化使用包合物组织硅酸盐
公开(公告)号：US4773987A
公开(公告)日：1988-09-27
申请号：US36825
申请日：1987-04-10
摘要： This invention relates to an efficient process for shape-selective conversion of organic feedstock with a catalyst comprising a Clathrate Group tectosilicate such as ZSM-39 and a highly siliceous, shape selective zeolite such as ZSM-5. In one embodiment, a stabilized, dewaxed lube stock is prepared by catalytically dewaxing a hydrocrackate.
摘要翻译： 本发明涉及一种用含有诸如ZSM-39的包合物组合硅酸盐催化剂和高度硅质的形状选择性沸石如ZSM-5的催化剂对有机原料进行形态选择性转化的有效方法。 在一个实施方案中，通过催化脱蜡加氢裂化剂制备稳定的脱蜡润滑剂原料。
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公开(公告)号：US4740649A
公开(公告)日：1988-04-26
申请号：US1134
申请日：1987-01-07
申请人： Pochen Chu , William E. Garwood
发明人： Pochen Chu , William E. Garwood
CPC分类号： C07C2/12 , B01J29/40 , C10G11/05 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/80 , C07C2529/40
摘要： Feedstock comprising aromatic compounds is converted by isomerization, alkylation, disproportionation or transalkylation to product comprising aromatic compounds which differs from the feedstock over catalyst having been prepared by reacting a high-silica zeolite with an acidic inorganic oxide in the presence of water.
摘要翻译： 包含芳族化合物的原料通过异构化，烷基化，歧化或烷基转移转化为含有芳族化合物的产物，其与原料相比，催化剂不同于通过在水存在下使高硅沸石与酸性无机氧化物反应而制备。
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公开(公告)号：US4665253A
公开(公告)日：1987-05-12
申请号：US792346
申请日：1985-10-29
申请人： Pochen Chu , William E. Garwood
发明人： Pochen Chu , William E. Garwood
CPC分类号： C07C2/12 , B01J29/40 , C10G11/05 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/80 , C07C2529/40
摘要： Feedstock comprising aromatic compounds is converted by isomerization, alkylation, disproportionation or transalkylation to product comprising aromatic compounds which differs from the feedstock over catalyst having been prepared by reacting a high-silica zeolite with an acidic inorganic oxide in the presence of water.
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54.发明授权
公开(公告)号：US4618737A
公开(公告)日：1986-10-21
申请号：US808705
申请日：1985-12-13
CPC分类号： C07C2/26 , C07C11/02 , C07C2/12 , C10G50/02 , C07C2529/06 , C07C2529/40 , C07C2531/02
摘要： High viscosity lubricants are formed by oligomerizing olefins in two stages. The first stage converts a lower olefin feed to distillate range hydrocarbons in the presence of an aluminosilicate zeolite such as ZSM-5. The distillate effluent from the first stage is further polymerized to lubricant range hydrocarbons at elevated temperatures in the presence of a ditertiary alkylperoxide catalyst.
摘要翻译： 高粘度润滑剂通过两个阶段的烯烃低聚而形成。 第一阶段在铝硅酸盐沸石如ZSM-5存在下将低级烯烃进料转化为馏出物范围的烃。 在二级烷基过氧化物催化剂的存在下，来自第一阶段的馏出物流出物在高温下进一步聚合成润滑剂烃。
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55.发明授权Viscosity index improvement in dewaxed lube basestock by partial desulfurization in hydrotreat bed 失效加氢处理床部分脱硫脱蜡润滑油基础油的粘度指数提高
公开(公告)号：US4564440A
公开(公告)日：1986-01-14
申请号：US512510
申请日：1983-07-11
CPC分类号： C10G67/0409 , C10G2400/10
摘要： Partial desulfurization in the range of about 30-90% during hydrotreating of a dewaxed lube oil basestock provides an increase in viscosity index of up to five numbers with less than about 5 wt. % yield loss, a consequence of the desulfurized compounds staying in the lube boiling range.
摘要翻译： 在脱蜡润滑油基础油的加氢处理期间，约30-90％范围内的部分脱硫使粘度指数提高至多5个数量，少于约5wt。 产率损失百分比，这是脱硫化合物在润滑油沸腾范围内的结果。
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公开(公告)号：US4524232A
公开(公告)日：1985-06-18
申请号：US568015
申请日：1984-01-04
IPC分类号： C10G57/02 , B01J29/00 , B01J29/40 , C10G50/02 , C10G69/12 , C10M105/04 , C10N20/02 , C07C2/02
CPC分类号： C10G69/126 , C10G50/02
摘要： A combination process for producing high viscosity index lubes from light olefins is provided wherein light olefins are first passed over a small pore zeolite and the liquid product therefrom is then processed over an intermediate pore zeolite to provide a lubricating oil with a higher viscosity, high Viscosity Index and low pour point in greater yield than obtained with either of the catalysts alone.
摘要翻译： 提供了用于从轻质烯烃生产高粘度指数的润滑剂的组合方法，其中轻质烯烃首先通过小孔沸石，然后将其中的液体产物在中间孔沸石上加工以提供具有较高粘度，高粘度的润滑油 指数和低倾点比单独使用任一种催化剂获得的产率更高。
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57.发明授权Process for the production of high viscosity index lubricating oils from olefins 失效从烯烃生产高粘度指数润滑油的方法
公开(公告)号：US4517399A
公开(公告)日：1985-05-14
申请号：US639529
申请日：1984-08-09
CPC分类号： B01J29/40 , C10G50/02 , B01J2229/26 , B01J2229/42 , B01J29/65 , B01J29/70
摘要： An improved process for the production of high viscosity lubricating oils obtained by reacting olefins over ZSM-5 type zeolites at elevated temperatures and pressures in order to obtain a liquid product and thereafter recovering a lube oil fraction from said liquid product is disclosed. The improvement resides in the use of large crystal ZSM-5 which has been found to enhance the viscosity index of lubes produced from olefins.
摘要翻译： 公开了一种用于生产高粘度润滑油的改进方法，所述高粘度润滑油通过使ZSM-5型沸石在高温和高压下反应以获得液体产物，然后从所述液体产物中回收润滑油馏分而使烯烃反应获得。 改进在于使用已经发现可以提高由烯烃生产的润滑油的粘度指数的大型晶体ZSM-5。
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公开(公告)号：US4283271A
公开(公告)日：1981-08-11
申请号：US158980
申请日：1980-06-12
申请人： William E. Garwood , Murray R. Silk
发明人： William E. Garwood , Murray R. Silk
CPC分类号： C10G65/12 , C10G2400/10
摘要： Hydrocracked, low pour lubricating oils of good stability are manufactured by passing a suitable hydrocarbon feed sequentially through a hydrocracking zone, a catalytic dewaxing zone, and a hydrotreating zone, all at high pressure and in that order, and with separation of hydrocrackate from recycle hydrogen prior to dewaxing. Only clean makeup hydrogen is fed to the dewaxer, passed through the hydrotreater, and then on to the hydrocracker, thereby providing an exceptionally efficient process.
摘要翻译： 通过使合适的烃进料依次通过加氢裂化区，催化脱蜡区和加氢处理区，全部以高压和依次顺序，并将氢化裂解物从再循环氢气中分离出来制备具有良好稳定性的加氢裂化低倾点润滑油 脱蜡之前。 只有干净的补充氢气才能进入脱蜡机，通过加氢处理器，然后再加到加氢裂化器上，从而提供了非常有效的工艺。
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59.发明授权
公开(公告)号：US4172843A
公开(公告)日：1979-10-30
申请号：US926987
申请日：1978-07-21
CPC分类号： B01J29/46 , B01J29/40 , C07C1/044 , B01J2229/26 , B01J2229/42 , C07C2529/072
摘要： An improved method is disclosed for converting synthesis gas to hydrocarbon mixtures wherein the syngas is contacted with a special catalyst comprising a crystalline zeolite having a silica-to-alumina ratio of greater than 200 (including zeolites containing essentially no alumina) and an (R.sub.2 O+ M.sub.2 /.sub.n O): SiO.sub.2 ratio of less than 1.1:1 where M is a metal other than a metal of Group IIIA, n is the valence of said metal, and R is an alkyl ammonium radical, said organosilicate being characterized by a specified x-ray diffraction pattern. In a specific embodiment of this invention, synthesis gas is contacted with a catalyst comprising an intimate mixture of said crystalline zeolite catalyst and iron-containing, Fischer-Tropsch catalyst to produce a liquid hydrocarbon product having a boiling range of less than 400.degree. F. at a 90 percent overhead and being a predominantly olefinic product, wherein the structure of the olefins is substantially branched chain with internally-positioned double bonds.
摘要翻译： 公开了一种用于将合成气转化为烃混合物的改进方法，其中合成气与包含二氧化硅与氧化铝之比大于200的结晶沸石（包括基本上不含氧化铝的沸石）和（R2O + M2 / nO）：SiO 2比小于1.1:1，其中M是除IIIA族金属以外的金属，n是所述金属的化合价，R是烷基铵基团，所述有机硅酸盐的特征在于指定的x- 射线衍射图。 在本发明的具体实施方案中，使合成气与包含所述结晶沸石催化剂和含铁的费 - 托催化剂的紧密混合物的催化剂接触，以产生沸点低于400°F的液体烃产物。 在90％的开销下，并且主要是烯烃产物，其中烯烃的结构基本上是支链的，内部定位的双键。
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公开(公告)号：US4126644A
公开(公告)日：1978-11-21
申请号：US732235
申请日：1976-10-14
IPC分类号： C10G35/095 , C10G59/06 , C10L1/06 , C07C3/62 , C07C1/02
CPC分类号： C10G59/06 , C10G35/095 , C10L1/06 , Y10S208/95
摘要： The product of Fischer-Tropsch synthesis is separated to recover a C.sub.5 -400.degree. F liquid fraction which is thereafter upgraded to a higher octane gasoline fraction and a low-pour, high diesel index fuel oil by a "dense phase" process using HZSM-5 and related zeolites as catalysts.
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