Abstract:
Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient and selective dehydrogenative silylation, hydrosilylation, and crosslinking catalysts.
Abstract:
The present invention relates to processes for the synthesis of saturated and unsaturated silahydrocarbons using iron-containing or cobalt-containing catalysts. The processes of the invention can produce tetraalkylsilanes, phenyltrialkylsilanes, substituted phenyltrialkylsilanes and their mixtures, which are useful as lubricants and hydraulic fluids, as well as alkyl alkenylsilanes, phenyl alkenylsilanes and substituted phenyl alkenylsilanes and their mixtures, which are useful in the synthesis of saturated silahydrocarbons and other organofunctional silanes.
Abstract:
The present invention relates to a process for preparing silylated polyurethane polymers which have increased stability under ambient condition or storage toward atmospheric moisture, in the presence of at least one of titanium-containing catalyst or zirconium-containing catalyst and to silylated polyurethane polymer compositions comprising these catalysts.
Abstract:
The present invention relates to stable, zero or low VOC epoxy-containing polysiloxane oligomer compositions that provide for a high degree of chemical resistance to compositions containing organic resins, while at the same time, maintaining or improving the flexibility of these organic resin-containing compositions, to processes for preparing epoxy-containing polysiloxane oligomer compositions, and to uses in coatings, sealants, adhesives, and composites containing the same.
Abstract:
A silicon-containing copolymer which includes zwitterionic linking groups with the general structures —N+(Y−)(Z)— or —N(Z*)— and repeating groups which can be divalent silicone moieties, divalent hydrocarbons or divalent polyethers. The copolymer can be used in personal care products, fertilizers and other agricultural products, pesticides, antifouling agents, and various waterborne coating formulations.
Abstract:
Moisture-curable compositions are provided which comprises a moisture-curable silylated resin, a flexibilizer and at least one curing catalyst. The cured compositions possess enhanced elongation and tear properties, and are highly suitable for applications such as adhesives, sealants, coatings, gaskets, industrial rubber goods, and the like.
Abstract:
The present invention is directed to a primer composition, comprising: (a) metal oxide nanoparticles surface-modified with an organofunctional silane moiety having a specific functionality, (b) an organic polymer; and (c) one or more solvents; wherein the composition comprises less than 4 wt % of water, based on the total weight of said primer composition. The composition produces films having excellent optical and adhesion characteristics, and excellent weatherability and thermal stability.
Abstract:
There is provided herein a functionalized ionic silicone composition comprising a silicone of the formula (I): M1aM2bM3cD1dD2eD3fT1gT2hT3iQj (I) which contains a monovalent radical bearing ion-pairs and having the formula (II): -A-Ix−Mny+; where A is a spacing group having at least 2 spacing atoms selected from a divalent hydrocarbon or hydrocarbonoxy group, where I is an ionic group such as sulfonate —SO3−, carboxylate —COO−, phosphonate —PO32− group and phosphate —OPO32−, where M is hydrogen or a cation independently selected from alkali metals, alkali earth metals, transition metals, metals, quaternary ammonium and phosphonium groups; or, zwitterions having the formula (III): —R′—NR″2+—R′″—I (III) where I is defined as above, and where the subscript a, b, c, d, e, f, g, h, i, j are zero or positive subject to the following limitations: 2≦a+b+c+d+e+f+g+h+i+j≦6000, b+e+h>0 and c+f+i>0.
Abstract translation:本文提供了包含式(I)的硅氧烷:M1aM2bM3cD1dD2eD3fT1gT2hT3iQj(I)的官能化离子硅氧烷组合物,其含有带有离子对的一价基团并具有式(II):-A-Ix-Mny +; 其中A是具有选自二价烃或烃氧基的至少2个间隔原子的间隔基团,其中I是离子基团,例如磺酸酯-SO 3 - ,羧酸酯-COO-,膦酸酯-PO 32 - 基团和磷酸酯-OPO 32 - 其中M是氢或独立地选自碱金属,碱土金属,过渡金属,金属,季铵和鏻基的阳离子; 或者具有式(III)的两性离子:-R'-NR“2 + -R'” - I(III)其中I如上定义,并且其中下标a,b,c,d,e,f, 受限于以下限制:2≦̸ a + b + c + d + e + f + g + h + i + j≦̸ 6000,b + e + h> 0和c + f + i> 0。
Abstract:
A transport puck vertically aligns a caulking cartridge, nozzle-down. The puck includes (i) a substantially solid lower plug portion, having a lead face and a bottom face and an center passageway that is at least partially inverted frustum-shaped that forms a side contact face that tapers from a wider lead face opening to a narrower bottom face opening; and or to a tubular sleeve from the side contact face to the bottom face opening; (ii) an upper sleeve, shaped to receive the caulking cartridge in a desired vertical alignment to the lower plug portion; and (iii) at least one funnel-shaped bore into the bottom face with an inserted connector comprising a head and stem, the head spaced within the bore to define a spacing that has been determined to identify bottom face wear;
Abstract:
Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient and selective dehydrogenative silylation and crosslinking catalysts.