Process for production of formaldehyde from dimethyl ether
    56.
    发明申请
    Process for production of formaldehyde from dimethyl ether 审中-公开
    从二甲醚生产甲醛的方法

    公开(公告)号:US20030166972A1

    公开(公告)日:2003-09-04

    申请号:US10081047

    申请日:2002-02-20

    IPC分类号: C07C045/38

    摘要: Dimethyl ether is converted to formaldehyde using a supported catalyst comprising molybdenum and/or vanadium oxides. The surface density of the oxide(s) ranges from greater than that for the isolated monomeric oxides upwards, so long as there is a substantial absence of bulk crystalline molybdenum and/or vanadium oxide(s). Conversion and selectivity to formaldehyde are improved as compared to data reported for known catalysts. Also disclosed is a catalyst comprising molybdenum and/or vanadium oxides supported on a layer of stannic oxide that is disposed on the surface of a particulate alumina or zirconia support.

    摘要翻译: 使用包含钼和/或氧化钒的负载催化剂将二甲醚转化成甲醛。 氧化物的表面密度比对于分离的单体氧化物的表面密度高,只要基本上不存在块状结晶的钼和/或氧化钒。 与已知催化剂报道的数据相比,甲醛的转化率和选择性得到改善。 还公开了一种催化剂,其包含负载在氧化亚锡层上的钼和/或氧化钒,其设置在颗粒氧化铝或氧化锆载体的表面上。