摘要:
The invention relates to a method for the specific production of a polymer material doped by a first metal element, which is gold, and at least one second metal element, said first metal element and said at least one second metal element being identical or different from each other.
摘要:
Even when a mixture resin of virgin resin and recovered resin material is used as a resin material for molding, a stable, high-quality foam-molded article with excellent impact resistance is produced at low cost. For this, the resin material that is used includes a mixture resin of recovered resin material obtained by pulverizing a resin material solidified after melting, and virgin resin without thermal history of melting, and a foaming agent added to the mixture resin. The resin material is a mixture of a polypropylene-based resin and a polyethylene-based elastomer.
摘要:
Microporous polyolefin and microporous polydicyclopentadiene (polyDCPD) based aerogels and methods for preparing and using the same are provided. The aerogels are produced by forming a polymer gel structure within a solvent from a olefin or dicyclopentadiene monomer via Ring Opening Metathesis Polymerization (ROMP) reactions, followed by supercritical drying to remove the solvent from the aerogel. Other aerogels are prepared by sequentially (1) mixing at least one dicyclopentadiene monomer, at least one solvent at least one catalyst and at least one inorganic and/or organic reinforcing material, (2) gelling the mixture, (3) aging, and (4) supercritical drying. Aerogels provided herein are inexpensive to prepare, possess desirable thermal, mechanical, acoustic, chemical, and physical properties and are hydrophobic. The aerogels provided herein are suitable for use in various applications, including but not limited to thermal and acoustic insulation, radiation shielding, and vibrational damping applications.
摘要:
The present invention relates to a process for producing a foamed material, wherein a composition in the form of emulsion with a matrix-forming component, a surfactant component and a near-critical or supercritical blowing agent component is submitted to a lowering of pressure. The blowing agent component further comprises a hydrophobic co-component, which is soluble in supercritical CO2 at a pressure of ≧150 bar, is insoluble in subcritical CO2 at a pressure of ≦40 bar and is insoluble in the matrix-forming component and furthermore is present in a proportion from ≧3 wt % to ≦35 wt % of the blowing agent component. It further relates to a composition in the form of emulsion to be used herein and a foamed material obtainable by the process according to the invention.
摘要:
Disclosed herein is a composition comprising a polymer; and a superheated fluid; where at least a portion of the polymer and the superheated fluid co-exist in a single phase. Disclosed herein is a method comprising exposing a polymer to a superheated fluid; swelling at least a portion of the polymer with the superheated fluid so that the polymer and the superheated fluid co-exist in a single phase; and changing pressure or temperature within the single phase to change a property in the polymer.
摘要:
Pellets, beads, particles, or other pieces of a thermoplastic elastomer having a maximum size in at least one dimension of 10 mm or less (collectively, “pellets”) are infused with a supercritical fluid in a pressurized container, then rapidly depressurized and heated either by immersion in a heated fluid or with infrared or microwave radiation to foam the pellets The pellets are prepared with at least two different densities. Pellets with different densities, thermoplastic elastomer compositions, or foam response rates are placed in different areas of a mold. The mold is filled with pellets, then the pellets are molded into a part. The part has areas of different density as a result of the placement of pellets of different density.
摘要:
A foam molding method, a foamed plastic formed by the method, and a foaming agent used in the foam molding method are provided. The foam molding method may include rotating a screw provided in a barrel, feeding a granular or powdered raw material and a foaming agent into the barrel, the foaming agent producing foam through a chemical reaction, melting the fed raw material and producing a gas from the foaming agent, and phase-changing the produced gas to a supercritical state and mixing the gas with the melted raw material.
摘要:
Microporous polyolefin and microporous polydicyclopentadiene (polyDCPD) based aerogels and methods for preparing and using the same are provided. The aerogels are produced by forming a polymer gel structure within a solvent from a olefin or dicyclopentadiene monomer 5 via Ring Opening Metathesis Polymerization (ROMP) reactions, followed by supercritical drying to remove the solvent from the aerogel. Other aerogels are prepared by sequentially (1) mixing at least one dicyclopentadiene monomer, at least one solvent at least one catalyst and at least one inorganic and/or organic reinforcing material, (2) gelling the mixture, (3) aging, and (4) supercritical drying. Aerogels provided herein are inexpensive to prepare, possess desirable 10 thermal, mechanical, acoustic, chemical, and physical properties and are hydrophobic. The aerogels provided herein are suitable for use in various applications, including but not limited to thermal and acoustic insulation, radiation shielding, and vibrational damping applications.
摘要:
Porous cross-linked polyimide-urea networks are provided. The networks comprise a subunit comprising two anhydride end-capped polyamic acid oligomers in direct connection via a urea linkage. The oligomers (a) each comprise a repeating unit of a dianhydride and a diamine and a terminal anhydride group and (b) are formulated with 2 to 15 of the repeating units. The subunit was formed by reaction of the diamine and a diisocyanate to form a diamine-urea linkage-diamine group, followed by reaction of the diamine-urea linkage-diamine group with the dianhydride and the diamine to form the subunit. The subunit has been cross-linked via a cross-linking agent, comprising three or more amine groups, at a balanced stoichiometry of the amine groups to the terminal anhydride groups. The subunit has been chemically imidized to yield the porous cross-linked polyimide-urea network. Also provided are wet gels, aerogels, and thin films comprising the networks, and methods of making the networks.