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416 条记录 (耗时 0.051 秒)

    Comb-shaped copolymers of a macromolecular monomer of polyhaloether with terminal olefinic unsaturation and process
    65.
    发明授权
    Comb-shaped copolymers of a macromolecular monomer of polyhaloether with terminal olefinic unsaturation and process 失效
    聚卤醚的大分子单体与末端烯属不饱和键的过程的梳状共聚物

    公开(公告)号：US5225491A

    公开(公告)日：1993-07-06

    申请号：US960673

    申请日：1992-10-14

    申请人： Simon H. Yu

    发明人： Simon H. Yu

    IPC分类号： C08F290/06 ,  C08G63/08 ,  C08G63/664 ,  C08L55/00 ,  C08L101/00

    CPC分类号： C08G63/664 ,  C08F290/061 ,  C08G63/08 ,  C08L101/00 ,  C08L55/005

    摘要： This invention relates to a comb-shaped graft copolymer, to a process for making the comb, and to a polymer blend made with the comb. The comb is made by a free radical polymerization of an ethylenically unsaturated monomer with a macromolecular monomer ("macromer" for brevity) of a haloalkylene oxide ("HAO" for brevity) homopolymer, random or block copolymer. The comb copolymer and blends of the comb with a polymer(s) may be cured. A comb with a terminal acrylyl or methacrylyl group or "head" and pendant polyether chains, which always include some HAO repeating units, may be made in an emulsion or suspension polymerization process which provides a comb having adequately high molecular weight so that the comb may be used in blends. The preferred comb of epichlorohydrin has a (meth)acrylyl head at one end, through which it (the macromer) is polymerizable, and a terminal hydroxyl (OH) group, or an end-capping group derived from the OH group at the other end. Each "tine" (pendant chain) of the comb is an uninterrupted one (that is, having no branch) having at least two repeating units derived from a HAO, preferably epichlorohydrin ("ECH"), with the tine terminating with a OH group, or an end-capping group derived from the OH group.

    摘要翻译： 本发明涉及梳状接枝共聚物，制造梳子的方法，以及由梳子制成的聚合物共混物。 通过烯键式不饱和单体与大分子单体（简称为“大分子单体”）的卤代环氧烷（简称“HAO”）均聚物，无规或嵌段共聚物的自由基聚合制成梳子。 梳状共聚物和梳子与聚合物的共混物可以固化。 总是包含一些HAO重复单元的末端丙烯酰基或甲基丙烯酰基或“头”和侧挂聚醚链的梳子可以在乳液或悬浮聚合方法中制备，其提供具有足够高分子量的梳子，使得梳子可以 用于混合物。 表氯醇的优选梳在一端具有（甲基）丙烯酰头，其（大分子单体）可以通过其聚合，并且末端羟基（OH）基团或衍生自另一端的OH基团的封端基 。 梳子的每个“齿”（侧链）是具有至少两个衍生自HAO的重复单元（优选表氯醇（“ECH”））的不间断的（即没有分支），其中终止于OH基团 或衍生自OH基团的封端基团。

    Low birefringence polyarylate from polyarylene dicarboxylic acid and polyarylene diphenol
    66.
    发明授权
    Low birefringence polyarylate from polyarylene dicarboxylic acid and polyarylene diphenol 失效
    聚亚芳基二羧酸和聚亚芳基二酚的低双折射多芳基化合物

    公开(公告)号：US5043413A

    公开(公告)日：1991-08-27

    申请号：US513816

    申请日：1990-04-25

    申请人： Takumi Tanaka

    发明人： Takumi Tanaka

    IPC分类号： C08G63/185 ,  C08G63/19 ,  C08G63/193 ,  C08G63/664 ,  C08G63/682 ,  C08G63/688

    CPC分类号： C08G63/193 ,  C08G63/185

    摘要： An organic polyarylate containing a repeating unit represented by the formula; ##STR1## wherein X is at least one member selected from the group consisting of --O--, --S--, --SO.sub.2 --, --CO--, alkylene, alkenylene and following formulas; ##STR2## and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, and R.sub.7 respectively show a hydrogen atom, a halogen atom or a C.sub.1 -C.sub.10 alkyl group; said polyarylates having an inherent viscosity of at least 0.2 dl/g measured at 25.degree. C. in a solution of 1 g of the polarylate in 100 ml of a mixture of 50% by weight of phenol and 50% by weight of 1,1,2,2-tetrachloroethane.

    摘要翻译： 一种含有下式表示的重复单元的有机多芳基化合物： 其中X是选自-O - ， - S - ， - SO 2 - ， - CO-，亚烷基，亚烯基和下列通式中的至少一个： R1，R2，R3，R4，R5，R6和R7分别表示氢原子，卤素原子或C1-C10烷基; 所述多芳基化合物的特性粘度至少为0.2dl / g，在25℃下在1g的极性化合物的溶液中，在100ml的50重量％的苯酚和50重量％的1,1 ，2,2-四氯乙烷。

    Process for making macromolecular monomers of polylactones with terminal acryloyl unsaturation and block copolymers thereof
    67.
    发明授权
    Process for making macromolecular monomers of polylactones with terminal acryloyl unsaturation and block copolymers thereof 失效
    制备具有末端丙烯酰基不饱和基团的聚内酯的高分子单体及其嵌段共聚物的方法

    公开(公告)号：US4983689A

    公开(公告)日：1991-01-08

    申请号：US283422

    申请日：1988-12-12

    申请人： Simon H. Yu

    发明人： Simon H. Yu

    IPC分类号： C08G63/08 ,  C08G63/664

    CPC分类号： C08G63/664 ,  C08G63/08

    摘要： Preparation of a macromolecular monomer of a lactone having an alpha-beta monoolefinically unsaturated "head" is effected at low temperature with a strong oxonium salt, such as a trialkyloxonium (TAO) hexafluorophosphate catalyst, with essentially no formation of cyclic oligomers and an insignificant amount of diacrylate. Cationic ring-opening polymerization of lactone monomer in conjunction with an unsaturated alcohol (propagator) having an acryloyl or methacryloyl double bond, produces a polylactone macromer having an ethylenic double bond at one end and a hydroxyl group at the other. The polymerization proceeds by polyaddition of the lactone to the OH group which is the propagating species. The macromer so formed allows the preparation of a macromer of block copolymer of the polylactone with a polyether such as epichlorohydrin, using the same TAO catalyst. In such a macromer of block copolymer, the polylactone ester block is next to the double bond, followed by the polyether block. This macromer of block copolymer, in turn, may be copolymerized with commonly available olefinically unsaturated monomers. There is no known method for the preparation of such copolymers with a homomacromer of polylactone, or, a macromer of polylactone-b-polyether. The propagator is a primary or secondary acryloyl or methacryloyl alcohol.

    摘要翻译： 具有α-β单烯属不饱和“头”的内酯的高分子单体的制备在低温下用强氧鎓盐如三烷基氧鎓（TAO）六氟磷酸盐催化剂进行，基本上不形成环状低聚物，并且不显着的量 的二丙烯酸酯。 内酯单体与具有丙烯酰基或甲基丙烯酰基双键的不饱和醇（传播剂）的阳离子开环聚合产生一端具有烯属双键和另一端具有羟基的聚内酯大分子单体。 通过将内酯加成到作为增殖物质的OH基团进行聚合。 如此形成的大分子单体使用相同的TAO催化剂制备聚内酯与聚醚如表氯醇的嵌段共聚物的大分子单体。 在这种嵌段共聚物的大分子单体中，聚内酯酯嵌段紧邻双键，其次是聚醚嵌段。 嵌段共聚物的这种大单体又可以与常用的烯属不饱和单体共聚。 没有已知的用聚内酯的同型共聚物制备这种共聚物的方法，或聚内酯-b-聚醚的大分子单体。 传播者是初级或次级丙烯酰基或甲基丙烯酰醇。

    Copolyetheresters from caprolactone
    69.
    发明授权
    Copolyetheresters from caprolactone 失效
    来自己内酯的共聚醚酯

    公开(公告)号：US4569973A

    公开(公告)日：1986-02-11

    申请号：US643985

    申请日：1984-08-24

    申请人： John A. Tyrell ,  Victor Mark

    发明人： John A. Tyrell ,  Victor Mark

    IPC分类号： C08G63/664 ,  C08G63/76

    CPC分类号： C08G63/664

    摘要： Novel copolyetherester elastomer molding compositions are prepared from diols, diacids, poly(alkylene ether) glycol and caprolactone or polycaprolactone.

    摘要翻译： 新型共聚醚酯弹性体成型组合物由二醇，二酸，聚（亚烷基醚）二醇和己内酯或聚己内酯制备。

    Method of making lactone-epoxide copolymer polyols
    70.
    发明授权
    Method of making lactone-epoxide copolymer polyols 失效
    制备内酯 - 环氧化物共聚物多元醇的方法

    公开(公告)号：US4291155A

    公开(公告)日：1981-09-22

    申请号：US20343

    申请日：1979-03-14

    申请人： Jacques Brochet

    发明人： Jacques Brochet

    IPC分类号： C08G18/42 ,  C08G63/664 ,  C08G63/08 ,  C08G63/10

    CPC分类号： C08G63/664 ,  C08G18/4269

    摘要： The invention concerns a method for the manufacture of polyols, principally utilizable in the synthesis of polyurethanes, which are ester/ether copolymers with hydroxylated terminal groups obtained by the direct copolymerization of a lactone and a vicinal epoxide in the presence of a chain initiator possessing at least two labile hydrogen atoms per mole and of an alkaline catalyst.

    摘要翻译： 本发明涉及一种制备主要用于合成聚氨酯的多元醇的方法，所述多元醇是具有羟基化端基的酯/醚共聚物，其通过内酯和邻位环氧化物的直接共聚获得， 每摩尔至少两个不稳定的氢原子和碱性催化剂。