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公开(公告)号:US20150270405A1
公开(公告)日:2015-09-24
申请号:US14734080
申请日:2015-06-09
Applicant: Semiconductor Energy Laboratory Co., Ltd.
Inventor: Masahiro TAKAHASHI , Takuya HIROHASHI , Masashi TSUBUKU , Noritaka ISHIHARA , Masashi OOTA
IPC: H01L29/786 , H01L29/04
CPC classification number: H01L27/1225 , C23C14/086 , G01N23/207 , G02F1/1368 , H01L21/0237 , H01L21/02422 , H01L21/02554 , H01L21/02565 , H01L21/02631 , H01L22/12 , H01L29/04 , H01L29/24 , H01L29/66969 , H01L29/7869 , H01L29/78693 , H01L2924/0002 , H01L2924/00
Abstract: A metal oxide film including a crystal part and having highly stable physical properties is provided. The size of the crystal part is less than or equal to 10 nm, which allows the observation of circumferentially arranged spots in a nanobeam electron diffraction pattern of the cross section of the metal oxide film when the measurement area is greater than or equal to 5 nmφ and less than or equal to 10 nmφ.
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公开(公告)号:US20150263331A1
公开(公告)日:2015-09-17
申请号:US14698896
申请日:2015-04-29
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Akiharu MIYANAGA , Junichi KOEZUKA , Masahiro TAKAHASHI
CPC classification number: H01M4/045 , C01B25/45 , H01M4/136 , H01M4/5825 , H01M10/054 , H01M2004/028
Abstract: A highly effective positive electrode is obtained by using a material such as Na which is an inexpensive abundant resource. A positive electrode active material of sodium transition metal phosphate of olivine structure in which the sodium transition metal phosphate of olivine structure includes, a phosphorus atom that is located at the center of a tetrahedron having an oxygen atom in each vertex, a transition metal atom that is located at the center of a first octahedron having an oxygen atom in each vertex; and a sodium atom that is located at the center of a second octahedron having an oxygen atom in each vertex, and adjacent sodium atoms are arranged one-dimensionally in a direction.
Abstract translation: 通过使用廉价的丰富资源的Na等材料,可以获得高效的正极。 橄榄石结构的过渡金属磷酸钠的正极活性物质,其中橄榄石结构的过渡金属磷酸钠包括位于每个顶点中具有氧原子的四面体的中心的磷原子,过渡金属原子, 位于每个顶点中具有氧原子的第一八面体的中心; 位于每个顶点中具有氧原子的第二八面体的中心的钠原子,并且相邻的钠原子在<010>方向上一维排列。
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73.
公开(公告)号:US20140367682A1
公开(公告)日:2014-12-18
申请号:US14474609
申请日:2014-09-02
Applicant: Semiconductor Energy Laboratory Co., Ltd.
Inventor: Shunpei YAMAZAKI , Akiharu MIYANAGA , Masahiro TAKAHASHI , Hideyuki KISHIDA , Junichiro SAKATA
IPC: H01L29/786 , H01L29/423 , H01L29/51
CPC classification number: H01L29/7869 , H01L27/1225 , H01L29/42364 , H01L29/42384 , H01L29/518 , H01L29/66969 , H01L29/78606 , H01L29/78696
Abstract: An object is to provide a semiconductor device including an oxide semiconductor with stable electric characteristics can be provided. An insulating layer having many defects typified by dangling bonds is formed over an oxide semiconductor layer with an oxygen-excess mixed region or an oxygen-excess oxide insulating layer interposed therebetween, whereby impurities in the oxide semiconductor layer, such as hydrogen or moisture (a hydrogen atom or a compound including a hydrogen atom such as H2O), are moved through the oxygen-excess mixed region or oxygen-excess oxide insulating layer and diffused into the insulating layer. Thus, the impurity concentration of the oxide semiconductor layer is reduced.
Abstract translation: 本发明的目的是提供一种包括具有稳定电特性的氧化物半导体的半导体器件。 在氧化物半导体层上形成具有以悬挂键为代表的许多缺陷的绝缘层,其间具有氧过剩混合区域或氧过剩氧化物绝缘层,由此氧化物半导体层中的诸如氢或水分的杂质( 氢原子或包含氢原子如H 2 O的化合物)通过氧过剩混合区域或氧 - 过量氧化物绝缘层移动并扩散到绝缘层中。 因此,氧化物半导体层的杂质浓度降低。
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公开(公告)号:US20140284596A1
公开(公告)日:2014-09-25
申请号:US14208661
申请日:2014-03-13
Applicant: Semiconductor Energy Laboratory Co., Ltd.
Inventor: Shunpei YAMAZAKI , Masahiro TAKAHASHI , Noboru KIMIZUKA
CPC classification number: C01G15/00 , C01G15/006 , C01P2002/60 , C01P2002/70 , C01P2002/74 , C01P2002/77 , C01P2004/04 , C01P2004/54 , C01P2006/10 , C01P2006/40 , H01L29/04 , H01L29/22 , H01L29/24 , H01L29/26 , H01L29/7869
Abstract: To provide an oxide semiconductor with a novel structure. Such an oxide semiconductor is composed of an aggregation of a plurality of InGaZnO4 crystals each of which is larger than or equal to 1 nm and smaller than or equal to 3 nm, and in the oxide semiconductor, the plurality of InGaZnO4 crystals have no orientation. Alternatively, such an oxide semiconductor is such that a diffraction pattern like a halo pattern is observed by electron diffraction measurement performed by using an electron beam with a probe diameter larger than or equal to 300 nm, and that a diffraction pattern having a plurality of spots arranged circularly is observed by electron diffraction measurement performed by using an electron beam with a probe diameter larger than or equal to 1 nm and smaller than or equal to 30 nm
Abstract translation: 提供具有新颖结构的氧化物半导体。 这种氧化物半导体由多个InGaZnO 4晶体的聚集构成,每个InGaZnO 4晶体大于或等于1nm且小于或等于3nm,并且在氧化物半导体中,多个InGaZnO 4晶体没有取向。 或者,这样的氧化物半导体使得通过使用探针直径大于或等于300nm的电子束进行的电子衍射测量观察到类似晕圈图案的衍射图案,并且具有多个点的衍射图案 通过使用探针直径大于或等于1nm且小于或等于30nm的电子束进行的电子衍射测量观察圆形排列
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公开(公告)号:US20240186486A1
公开(公告)日:2024-06-06
申请号:US18442450
申请日:2024-02-15
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Masahiro TAKAHASHI , Teruaki OCHIAI , Yohei MOMMA , Ayae TSURUTA
CPC classification number: H01M4/364 , H01M4/505 , H01M4/525 , H01M2004/028
Abstract: A positive electrode active material particle with little deterioration is provided. A power storage device with little deterioration is provided. A highly safe power storage device is provided. The positive electrode active material particle includes a first crystal grain, a second crystal grain, and a crystal grain boundary positioned between the crystal grain and the second crystal grain; the first crystal grain and the second crystal grain include lithium, a transition metal, and oxygen; the crystal grain boundary includes magnesium and oxygen; and the positive electrode active material particle includes a region where the ratio of the atomic concentration of magnesium in the crystal grain boundary to the atomic concentration of the transition metal in first crystal grain and the second crystal grain is greater than or equal to 0.010 and less than or equal to 0.50.
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公开(公告)号:US20240164124A1
公开(公告)日:2024-05-16
申请号:US18372263
申请日:2023-09-25
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Satoko SHITAGAKI , Satoshi SEO , Nobuharu OHSAWA , Hideko INOUE , Masahiro TAKAHASHI , Kunihiko SUZUKI
IPC: H10K50/11 , C09K11/02 , C09K11/06 , H05B33/14 , H10K50/15 , H10K50/16 , H10K50/17 , H10K50/818 , H10K50/828 , H10K85/60
CPC classification number: H10K50/11 , C09K11/025 , C09K11/06 , H05B33/14 , H10K50/15 , H10K50/16 , H10K50/17 , H10K50/171 , H10K50/818 , H10K50/828 , H10K85/6572 , H10K85/6576 , H10K85/342
Abstract: Provided is a light-emitting element with high external quantum efficiency, or a light-emitting element with a long lifetime. The light-emitting element includes, between a pair of electrodes, a light-emitting layer including a guest material and a host material, in which an emission spectrum of the host material overlaps with an absorption spectrum of the guest material, and phosphorescence is emitted by conversion of an excitation energy of the host material into an excitation energy of the guest material. By using the overlap between the emission spectrum of the host material and the absorption spectrum of the guest material, the energy smoothly transfers from the host material to the guest material, so that the energy transfer efficiency of the light-emitting element is high. Accordingly, a light-emitting element with high external quantum efficiency can be achieved.
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77.
公开(公告)号:US20230343924A1
公开(公告)日:2023-10-26
申请号:US18203148
申请日:2023-05-30
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Teruaki OCHIAI , Takahiro KAWAKAMI , Mayumi MIKAMI , Yohei MOMMA , Masahiro TAKAHASHI , Ayae TSURUTA
IPC: H01M4/1315 , H01M4/134 , H01M4/36 , H01M4/525 , H01M4/1391 , H01M4/62 , H01M4/13915 , H01M4/131 , H01M4/86
CPC classification number: H01M4/131 , H01M4/1315 , H01M4/134 , H01M4/1391 , H01M4/13915 , H01M4/366 , H01M4/525 , H01M4/625 , H01M4/8657 , H01M2004/021
Abstract: A positive electrode active material which can improve cycle characteristics of a secondary battery is provided. Two kinds of regions are provided in a superficial portion of a positive electrode active material such as lithium cobaltate which has a layered rock-salt crystal structure. The inner region is a non-stoichiometric compound containing a transition metal such as titanium, and the outer region is a compound of representative elements such as magnesium oxide. The two kinds of regions each have a rock-salt crystal structure. The inner layered rock-salt crystal structure and the two kinds of regions in the superficial portion are topotaxy; thus, a change of the crystal structure of the positive electrode active material generated by charging and discharging can be effectively suppressed. In addition, since the outer coating layer in contact with an electrolyte solution is the compound of representative elements which is chemically stable, the secondary battery having excellent cycle characteristics can be obtained.
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78.
公开(公告)号:US20230299265A1
公开(公告)日:2023-09-21
申请号:US18202480
申请日:2023-05-26
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Teruaki OCHIAI , Takahiro KAWAKAMI , Mayumi MIKAMI , Yohei MOMMA , Masahiro TAKAHASHI , Ayae TSURUTA
IPC: H01M4/131 , H01M4/1315 , H01M4/1391 , H01M4/62 , H01M4/13915 , H01M4/134 , H01M4/36 , H01M4/525 , H01M4/86
CPC classification number: H01M4/131 , H01M4/1315 , H01M4/1391 , H01M4/625 , H01M4/13915 , H01M4/134 , H01M4/366 , H01M4/525 , H01M4/8657 , H01M2004/021
Abstract: A positive electrode active material which can improve cycle characteristics of a secondary battery is provided. Two kinds of regions are provided in a superficial portion of a positive electrode active material such as lithium cobaltate which has a layered rock-salt crystal structure. The inner region is a non-stoichiometric compound containing a transition metal such as titanium, and the outer region is a compound of representative elements such as magnesium oxide. The two kinds of regions each have a rock-salt crystal structure. The inner layered rock-salt crystal structure and the two kinds of regions in the superficial portion are topotaxy; thus, a change of the crystal structure of the positive electrode active material generated by charging and discharging can be effectively suppressed. In addition, since the outer coating layer in contact with an electrolyte solution is the compound of representative elements which is chemically stable, the secondary battery having excellent cycle characteristics can be obtained.
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公开(公告)号:US20230298906A1
公开(公告)日:2023-09-21
申请号:US18021317
申请日:2021-08-12
Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Inventor: Shunpei YAMAZAKI , Yoshihiro KOMATSU , Shunichi ITO , Shinobu KAWAGUCHI , Masahiro TAKAHASHI
IPC: H01L21/477
CPC classification number: H01L21/477
Abstract: A semiconductor device with small variation in characteristics and high reliability is provided. In a method for manufacturing the semiconductor device, an oxide is formed, a first insulator is formed over the oxide, a conductor is formed over the first insulator, a second insulator is formed over the conductor, and heat treatment is performed so that hydrogen in the oxide and the first insulator is moved into and absorbed by the second insulator. The second insulator is formed by a sputtering method.
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公开(公告)号:US20220271167A1
公开(公告)日:2022-08-25
申请号:US17626654
申请日:2020-07-08
Applicant: Semiconductor Energy Laboratory co., Ltd.
Inventor: Shunpei YAMAZAKI , Erika TAKAHASHI , Shinya SASAGAWA , Naoki OKUNO , Masahiro TAKAHASHI , Kazuki TANEMARA
IPC: H01L29/786 , H01L27/108 , H01L21/02 , H01L29/66
Abstract: A semiconductor device with high reliability is provided. The semiconductor device includes a first oxide; a first conductor, a second conductor, and a first insulator over the first oxide; and a third conductor over the first insulator. The first conductor includes a first crystal. The second conductor includes a crystal having the same crystal structure as the first crystal. The first crystal has (111) orientation with respect to a surface of the first oxide. The first oxide includes a second crystal. The second crystal has c-axis alignment with respect to a surface where the first oxide is formed. The lattice mismatch degree of the first crystal with respect to the second crystal is lower than or equal to 8 percent.
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