摘要:
The invention provides a lubricating composition containing an oil of lubricating viscosity and a block copolymer of a poly(olefin) block, such as poly(isobutylene) (PIB) and a polyvinyl aromatic) block, such as poly(styrene), wherein the copolymer is optionally functionalized or grafted. The invention further provides a method of using the block copolymer to control deposits in a lubricating oil composition.
摘要:
Provided is a method for stabilizing a dispersion of a carbon nanomaterial in a lubricating oil basestock. The method includes providing a lubricating oil basestock; dispersing a carbon nanomaterial in the lubricating oil basestock; and adding at least one block copolymer thereto. The at least one block copolymer has two or more blocks includes at least one alkenylbenzene block and at least one linear alpha olefin block. The at least one block copolymer is present in an amount sufficient to stabilize the dispersion of the carbon nanomaterial in the lubricating oil basestock. Also provided is a lubricating engine oil having a composition including: a lubricating oil base stock; a carbon nanomaterial dispersed in the lubricating oil basestock; and at least one block copolymer.
摘要:
A lubricant composition comprising an oil of lubricating viscosity; (A) 0.05 to 1.5 percent by weight of a copolymer comprising 70 to 79 percent by weight of units derived from ethylene (“E”), having a Mw of 50,000 to 100,000, Mw/ Mn less than 3, density (“D”) of 860 to 896 kg/m3, and a melting point (“Tm”) of 15° C. to 60° C., wherein E and Tm fulfill the expression 3.44E−206≧Tm; and (B) 0.05 to 1.5 percent by weight of a block copolymer comprising a first block which comprises a vinyl aromatic comonomer and a second block which comprises a diene comonomer, the diene monomer-containing block being hydrogenated; wherein the weight ratio (A):(B) is 20:80 to 60:40; exhibits good low temperature performance and durability.
摘要:
Provided is an improved lithium complex grease. The grease composition has a higher thickener yield, yet good mechanical properties. The grease composition comprises a lubricating oil, a lithium complex thickener and a copolymer, which in one embodiment may comprise styrene and butadiene.
摘要:
The present invention includes star polymers which can be used as viscosity index improvers in oil compositions formulated for high performance engines. The star polymers have tetrablock copolymer arms of hydrogenated polyisoprene-polybutadiene-polyisoprene with a block of polystyrene and which provide excellent low temperature performance in lubricating oils, exhibit good thickening efficiency, and are finishable as polymer crumb.
摘要:
A process for the preparation of a polymer concentrate which is a relatively concentrated solution in a base stock oil, e.g., a mineral oil or synthetic hydrocarbon oil, of a highly branched polymer having segments of a polymer of p-tert-butylstyrene (t-BS), comprising the free radical solution polymerization in the base stock oil of t-BS and optionally, one or more additional polymerizable monoethylenically unsaturated (monofunctional) monomers together with a small amount of a multiethylenically unsaturated (multifunctional) cross-linking agent, e.g., divinylbenzene (DVB). Optionally, the polymer solution obtained from the polymerization may be diluted with an additional amount of the base stock oil employed in the polymerization to obtain a polymer concentrate having a lower polymer concentration and viscosity than the polymerization solution. The polymer concentrate may then be mixed with an additional a amount of base stock oil which may be the same or different from the base stock oil present in the polymer concentrate to obtain a functional fluid, e.g., a lubricating oil, having improved viscometric properties.
摘要:
A process for preparing a grafted star polymer which comprises contacting a nitrogen-containing polymerizable organic polar compound with a star polymer (as hereinbefore defined) in the presence of a free radical polymerization initiator and characterized in that the reaction is carried out in a mineral oil solvent and, as coupling inhibitor, either a chain transfer agent, a pi-electron donor, or a comonomer, together with the modified, hydrogenated star polymers thus produced, and their use as luboil additives.
摘要:
The high-temperature lubricant for the hot-working of metals which comprises (a) 10 to 90 percent by weight of graphite, (b) 2 to 45 percent by weight of an alkylene homopolymer or copolymer, and (c) 0.5 to 8 percent by weight of a dispersing agent. The lubricant is solid at room temperature. The high-temperature lubricant is applied in the form of an aqueous solution which includes 5 to 80 percent by weight of the solid high-temperature lubricant. The process of production and use of the high-temperature lubricant.The high-temperature lubricant for the hot-working of metals which comprises (a) 35 to 90 percent by weight of graphite, (b) 2 to 60 percent by weight of an alkylene homopolymer or copolymer, (c) 0.2 to 8 percent by weight of an auxiliary suspension agent, and (d) 2 to 40 percent by weight of a film stabilizer. The lubricant is applied in the form of an aqueous solution which includes 5 to 80 percent by weight of solid lubricant. The lubricant is used at temperatures of around 900.degree. C. or higher.
摘要:
Block copolymers are prepared by (1) anionic polymerization of an alkyl-substituted styrene, the alkyl group having at least 4 carbon atoms, or a hydrogenated block or random butadiene-styrene copolymer in the presence of an organometal catalyst of the alkali metal series and (2) addition to the reaction product resulting from this polymerization an alkylene oxide in sufficient amount to produce from 1% to about 50% by weight of a second block copolymerized with the first as an AB or BAB copolymer. These copolymers have molecular weights in the range of from about 1,000 to about 300,000 and perform as multifunctional additives in industrial organic compositions, providing such utility as detergency and viscosity index improvement. Copolymers capped with diisocyanate have excellent thermal and oxidative stability.
摘要:
SHEAR-STABLE, HIGH VISCOSITY INDEX LUBRICATING OIL FORMULATIONS ARE FORMED BY THE ADDITION OF A SMALL AMOUNT OF A HYDROGENATED RANDOM BUTADIENE-STYRENE COPOLYMER HAVING A BUTADIENE CONTENT OF 30 TO 44 WEIGHT PERCENT.