公开(公告)号：US20160035855A1

公开(公告)日：2016-02-04

申请号：US13111699

申请日：2011-05-19

Applicant: Tobin J. Marks ,  Young-geun Ha ,  Antonio Facchetti

Inventor： Tobin J. Marks ,  Young-geun Ha ,  Antonio Facchetti

IPC: H01L29/51 ,  H01L51/05 ,  H01L29/786

CPC classification number: H01L51/0533 ,  H01L21/441 ,  H01L29/24 ,  H01L29/4908 ,  H01L29/513 ,  H01L29/517 ,  H01L29/66969 ,  H01L51/0053 ,  H01L51/0055 ,  H01L51/0529 ,  H01L51/0537 ,  H01L51/0545 ,  H01L2251/301

Abstract: Disclosed are organic-inorganic hybrid self-assembled multilayers that can be used as electrically insulating (or dielectric) materials. These multilayers generally include an inorganic primer layer and one or more bilayers deposited thereon. Each bilayer includes a chromophore or “π-polarizable” layer and an inorganic capping layer composed of zirconia. Because of the regularity of the bilayer structure and the aligned orientation of the chromophore resulting from the self-assembly process, the present multilayers have applications in electronic devices such as thin film transistors, as well as in nonlinear optics and nonvolatile memories.

Abstract translation: 公开了可用作电绝缘（或电介质）材料的有机 - 无机混合自组装多层膜。 这些多层通常包括无机底漆层和沉积在其上的一个或多个双层。 每个双层包括发色团或“＆pgr可极化”层和由氧化锆组成的无机覆盖层。 由于双层结构的规则性和由自组装过程产生的发色团的排列取向，所以本发明的多层膜可用于诸如薄膜晶体管的电子器件，以及非线性光学和非易失性存储器中。

公开(公告)号：US08859714B1

公开(公告)日：2014-10-14

申请号：US12827146

申请日：2010-06-30

Applicant: Tobin J. Marks ,  Antonio Facchetti

Inventor： Tobin J. Marks ,  Antonio Facchetti

IPC: C08G69/08

CPC classification number: C08G61/126 ,  C08G73/06 ,  C08G2261/3223 ,  C08G2261/3229 ,  C08G2261/3246 ,  C08G2261/3327 ,  C08G2261/344 ,  C08G2261/51 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95

Abstract: Disclosed are new organic semiconductor materials prepared from polymers based on N-alkyl-2,2′-bithiophene-3,3′-dicarboximide (BTI) repeating units. Such polymers can exhibit desirable electronic properties and can possess processing advantages including solution-processability and/or good stability at ambient conditions.

Abstract translation: 公开了由基于N-烷基-2,2'-二噻吩-3,3'-二甲酰亚胺（BTI）重复单元的聚合物制备的新的有机半导体材料。 这样的聚合物可以表现出所需的电子性质，并且可以具有包括溶液加工性和/或在环境条件下的良好稳定性的加工优点。

公开(公告)号：US20140288313A1

公开(公告)日：2014-09-25

申请号：US14298523

申请日：2014-06-06

Applicant: Tobin J. Marks ,  Antonio Facchetti ,  Pierre-Luc Boudreault ,  Hiroyuki Miyauchi

Inventor： Tobin J. Marks ,  Antonio Facchetti ,  Pierre-Luc Boudreault ,  Hiroyuki Miyauchi

IPC: H01L51/00

CPC classification number: H01L51/0074 ,  B82Y10/00 ,  C07D495/04 ,  C07D519/00 ,  H01L51/0036 ,  H01L51/0047 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0541 ,  H01L51/0545 ,  H01L51/0558 ,  H01L51/4253 ,  Y02E10/549

Abstract: Disclosed are molecular and polymeric compounds having desirable properties as semiconducting materials. Such compounds can exhibit desirable electronic properties and possess processing advantages including solution-processability and/or good stability. Organic transistor and photovoltaic devices incorporating the present compounds as the active layer exhibit good device performance.

Abstract translation: 公开了具有期望性质的分子和聚合物作为半导体材料。 这样的化合物可以表现出所需的电子性质，并具有加工性和/或稳定性好的加工优点。 结合本发明化合物作为活性层的有机晶体管和光伏器件表现出良好的器件性能。

公开(公告)号：US08754188B2

公开(公告)日：2014-06-17

申请号：US13429005

申请日：2012-03-23

Applicant: Tobin J. Marks ,  Antonio Facchetti ,  Pierre-Luc Boudreault ,  Hiroyuki Miyauchi

Inventor： Tobin J. Marks ,  Antonio Facchetti ,  Pierre-Luc Boudreault ,  Hiroyuki Miyauchi

IPC: C08G75/00

CPC classification number: H01L51/0074 ,  B82Y10/00 ,  C07D495/04 ,  C07D519/00 ,  H01L51/0036 ,  H01L51/0047 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0541 ,  H01L51/0545 ,  H01L51/0558 ,  H01L51/4253 ,  Y02E10/549

Abstract: Disclosed are molecular and polymeric compounds having desirable properties as semiconducting materials. Such compounds can exhibit desirable electronic properties and possess processing advantages including solution-processability and/or good stability. Organic transistor and photovoltaic devices incorporating the present compounds as the active layer exhibit good device performance.

Abstract translation: 公开了具有期望性质的分子和聚合物作为半导体材料。 这样的化合物可以表现出所需的电子性质，并具有加工性和/或稳定性好的加工优点。 结合本发明化合物作为活性层的有机晶体管和光伏器件表现出良好的器件性能。

公开(公告)号：US08644648B2

公开(公告)日：2014-02-04

申请号：US12582518

申请日：2009-10-20

Applicant: Seng-Tiong Ho ,  Fei Yi ,  Tobin J. Marks

Inventor： Seng-Tiong Ho ,  Fei Yi ,  Tobin J. Marks

IPC: G02F1/035

CPC classification number: G02F1/065 ,  G02F1/0018 ,  G02F1/2255 ,  G02F2201/122 ,  G02F2202/02

Abstract: Electro-optic (EO) modulator and related device structures which can be used in conjunction with high EO materials to lower switching voltage and improve related performance parameters.

Abstract translation: 电光（EO）调制器和相关的器件结构，可与高EO材料结合使用，以降低开关电压并改善相关性能参数。

公开(公告)号：US08609902B2

公开(公告)日：2013-12-17

申请号：US12856154

申请日：2010-08-13

Applicant: Tobin J. Marks ,  Charles J. Weiss ,  Stephen D. Wobser

Inventor： Tobin J. Marks ,  Charles J. Weiss ,  Stephen D. Wobser

IPC: C07C381/00

CPC classification number: C07B45/06 ,  C07C319/18 ,  C07C323/03 ,  C07C323/27 ,  C07C2601/14 ,  C07C2601/16 ,  C07D213/32 ,  C07C321/18 ,  C07C321/20 ,  C07C321/22 ,  C07C321/28

Abstract: An efficient and highly Markovnikov selective organoactinide-, organolanthanide-, and organozirconium-catalyzed addition of aryl, benzyl, and aliphatic thiols to terminal alkynes is described. The corresponding vinyl sulfides are produced with little or no side-products.

Abstract translation: 描述了一种有效和高度的马尔科夫尼科夫选择性有机酸苷，有机镧系元素和有机锆催化的芳基，苄基和脂族硫醇向末端炔烃的加成。 生产相应的乙烯基硫化物很少或没有副产物。

公开(公告)号：US08399761B2

公开(公告)日：2013-03-19

申请号：US12771376

申请日：2010-04-30

Applicant: Tobin J. Marks ,  Alexander W. Hains

Inventor： Tobin J. Marks ,  Alexander W. Hains

IPC: H01L31/00

CPC classification number: H01L51/0094 ,  B82Y10/00 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/4253 ,  Y02E10/549

Abstract: An organic photovoltaic device and method of forming same. In one embodiment, the organic photovoltaic device has an anode, a cathode, an active layer disposed between the anode and the cathode; and an interfacial layer disposed between the anode and the active layer, the interfacial layer comprising 5,5′-bis[(p-trichlorosilylpropylphenyl)phenylamino]-2,2′-bithiophene (PABTSi2).

Abstract translation: 一种有机光伏器件及其形成方法。 在一个实施例中，有机光伏器件具有阳极，阴极，设置在阳极和阴极之间的有源层; 以及设置在阳极和活性层之间的界面层，界面层包含5,5'-双[（对三氯甲硅烷基丙基苯基）苯基氨基] -2,2'-二噻吩（PABTSi 2）。

公开(公告)号：US08163347B2

公开(公告)日：2012-04-24

申请号：US11985930

申请日：2007-11-19

Applicant: Tobin J. Marks ,  Michael T. Lanagan ,  Neng Guo ,  Sara A DiBenedetto

Inventor： Tobin J. Marks ,  Michael T. Lanagan ,  Neng Guo ,  Sara A DiBenedetto

IPC: B05D3/10

CPC classification number: C08J5/005 ,  B82Y30/00 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/06 ,  C08J2323/02 ,  H01G4/1227 ,  C08F4/025 ,  C08F4/65916 ,  C08F2500/15

Abstract: Disclosed are metal oxide-polymer composites having a substrate comprising a metal oxide component, an aluminum oxide component, and a metallocene olefin polymerization catalyst component coupled to the substrate. The compositions can be used as thin films in an insulator device. Also disclosed is a method of preparing such compositions.

Abstract translation: 公开了具有底物的金属氧化物 - 聚合物复合材料，所述基材包含金属氧化物组分，氧化铝组分和与基底结合的茂金属烯烃聚合催化剂组分。 该组合物可用作绝缘体装置中的薄膜。 还公开了制备这种组合物的方法。

公开(公告)号：US08110432B1

公开(公告)日：2012-02-07

申请号：US11891720

申请日：2007-08-13

Applicant: Tobin J. Marks ,  Antonio Facchetti

Inventor： Tobin J. Marks ,  Antonio Facchetti

IPC: H01L21/00

CPC classification number: H01L51/102 ,  H01L2251/105 ,  H01L2251/556

Abstract: Thin film transistor substrates with conductor components in conjunction therewith, and related methods of fabrication.

Abstract translation: 具有导体部件的薄膜晶体管衬底及其制造方法。

公开(公告)号：US07976954B1

公开(公告)日：2011-07-12

申请号：US12693816

申请日：2010-01-26

Applicant: Tobin J. Marks ,  Milko E. van der Boom ,  Seong-Sik Chang ,  Seng-Tiong Ho

Inventor： Tobin J. Marks ,  Milko E. van der Boom ,  Seong-Sik Chang ,  Seng-Tiong Ho

IPC: B32B15/04

CPC classification number: G02F1/065 ,  G02F1/3612 ,  G02F1/3614 ,  G02F1/37

Abstract: The preparation of robust, thin film materials with large second-order optical nonlinearities through the covalent self-assembly of chromophoric compositions and innovative use of silyl chemistry.