公开(公告)号：US07497935B2

公开(公告)日：2009-03-03

申请号：US10928770

申请日：2004-08-27

申请人： Gregory J. McCollum ,  Geoffrey R. Webster, Jr. ,  Michael L. White

发明人： Gregory J. McCollum ,  Geoffrey R. Webster, Jr. ,  Michael L. White

IPC分类号： C25D13/06

CPC分类号： C09D5/4419 ,  C09D5/4492

摘要： The invention provides a curable electrodepositable coating composition that has improved durability in the presence of metal ions. The coating composition includes one or more ungelled, active hydrogen-containing ionic salt group-containing resins which are electrodepositable on an electrode, one or more curing agents, and one or more metal deactivators.

摘要翻译： 本发明提供一种在金属离子存在下具有改善的耐久性的可固化的可电沉积涂料组合物。 涂料组合物包括一种或多种非电凝的含氢离子盐基团的树脂，其可电沉积在电极上，一种或多种固化剂和一种或多种金属钝化剂。

公开(公告)号：US20090020038A1

公开(公告)日：2009-01-22

申请号：US11780796

申请日：2007-07-20

申请人： David Fenn ,  Gregory J. McCollum

发明人： David Fenn ,  Gregory J. McCollum

IPC分类号： C08G8/34

CPC分类号： C08G59/4215 ,  C09D5/4415 ,  C09D193/04

摘要： Cationic electrodepositable coatings comprising rosin, wherein the rosin forms part of the cationic resin backbone, are disclosed.

摘要翻译： 公开了包含松香的阳离子电沉积涂层，其中松香形成阳离子树脂主链的一部分。

公开(公告)号：US07459504B2

公开(公告)日：2008-12-02

申请号：US11101803

申请日：2005-04-08

申请人： Venkatachalam Eswarakrishnan ,  Gregory J. McCollum ,  Matthew Scott ,  Geoffrey R. Webster, Jr. ,  Judith A. Orzechowski ,  Kevin J. Dufford ,  David Robert Fenn ,  Alan J. Kaylo ,  Thomas C. Moriarity

发明人： Venkatachalam Eswarakrishnan ,  Gregory J. McCollum ,  Matthew Scott ,  Geoffrey R. Webster, Jr. ,  Judith A. Orzechowski ,  Kevin J. Dufford ,  David Robert Fenn ,  Alan J. Kaylo ,  Thomas C. Moriarity

IPC分类号： B32B15/08 ,  C08G59/40 ,  C08L33/14 ,  C08L63/02 ,  C08L63/10

CPC分类号： C09D5/4419 ,  C08G59/56 ,  Y10T428/31507 ,  Y10T428/31529

摘要： The present invention provides a film-forming composition. The composition includes a reaction product of: a) a polyamine containing a primary amino group and a secondary amino group; and b) an acyclic carbonate. Also provided is a method of preparing a film-forming composition and an article coated with such compositions.

摘要翻译： 本发明提供一种成膜组合物。 该组合物包括：a）含有伯氨基和仲氨基的多胺的反应产物; 和b）无环碳酸酯。 还提供了制备成膜组合物的方法和用这种组合物涂覆的制品。

公开(公告)号：US20080146716A1

公开(公告)日：2008-06-19

申请号：US11610651

申请日：2006-12-14

申请人： Michael A. Zalich ,  Gregory J. McCollum ,  Thomas G. Rukavina

发明人： Michael A. Zalich ,  Gregory J. McCollum ,  Thomas G. Rukavina

IPC分类号： C08L75/04 ,  C08K3/20

CPC分类号： C08G18/758 ,  C08G18/3206 ,  C08K3/36 ,  C08K7/00 ,  C08K9/06

摘要： Polymer composites comprising a thermoset polymeric phase and an inorganic particulate phase and a method for preparing the composites are disclosed.

摘要翻译： 公开了包含热固性聚合物相和无机颗粒相的聚合物复合材料和制备复合材料的方法。

公开(公告)号：US20080075871A1

公开(公告)日：2008-03-27

申请号：US11839165

申请日：2007-08-15

申请人： Ronald R. Ambrose ,  Anthony M. Chasser ,  Susan F. Donaldson ,  Gregory J. McCollum

发明人： Ronald R. Ambrose ,  Anthony M. Chasser ,  Susan F. Donaldson ,  Gregory J. McCollum

IPC分类号： B05D3/00 ,  C09D163/00 ,  C09D183/00

CPC分类号： B05D3/046 ,  C08G59/1433 ,  C09D163/00 ,  C09D183/10 ,  C09D183/14

摘要： Disclosed are low temperature, moisture curable coating compositions, related coated substrates, and methods for coating a substrate. The coating compositions include an ungelled, secondary amine-containing Michael addition reaction product of reactants including a compound comprising more than one site of ethylenic unsaturation, and an aminofunctional silane.

摘要翻译： 公开了低温，湿固化涂料组合物，相关的涂覆基材和涂布基材的方法。 涂料组合物包括含有包含多于一个烯属不饱和位点的化合物和氨基官能硅烷的反应物的未凝胶化，含仲胺的迈克尔加成反应产物。

公开(公告)号：US07172809B2

公开(公告)日：2007-02-06

申请号：US10642826

申请日：2003-08-19

申请人： Steven V. Barancyk ,  John W. Burgman ,  James B. O'Dywer ,  Laura A. Kiefer-Liptak ,  Michael Allen Mayo ,  Gregory J. McCollum ,  Shiryn Tyebjee

发明人： Steven V. Barancyk ,  John W. Burgman ,  James B. O'Dywer ,  Laura A. Kiefer-Liptak ,  Michael Allen Mayo ,  Gregory J. McCollum ,  Shiryn Tyebjee

IPC分类号： B32B5/16

CPC分类号： C09D201/06 ,  C08G18/4692 ,  C08G18/792 ,  C09D167/00 ,  C09D175/04 ,  Y10T428/25 ,  Y10T428/251 ,  Y10T428/254 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2998 ,  Y10T428/31511 ,  Y10T428/31551 ,  C08L2666/28 ,  C08L2666/16

摘要： Coating compositions formed from at least one hydroxyl functional non-vinyl material comprising at least one alcoholic hydroxyl group blocked with a hydrolyzable silyl group, and at least one curing agent are provided by the present invention. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carbamate functional material comprising at least one carbamate group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carboxyl functional material comprising at least one carboxyl group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one amide functional material comprising at least one amide blocked with a hydrolyzable silyl group, and at least one curing agent. Other embodiments of the present invention are directed to substrates coated with the aforementioned cured compositions. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings. Further embodiments of the present invention are directed to methods for improving scratch resistance of a substrate.

摘要翻译： 由至少一种包含至少一个用可水解甲硅烷基封端的醇羟基的羟基官能非乙烯基材料形成的涂料组合物和至少一种固化剂由本发明提供。 本发明的另一个实施方案涉及由包含至少一种氨基甲酸酯官能材料的组分形成的涂料组合物，所述氨基甲酸酯官能材料包含至少一个被可水解甲硅烷基封端的氨基甲酸酯基团和至少一种固化剂。 本发明的另一个实施方案涉及由包含至少一种包含至少一个被可水解甲硅烷基封端的羧基的羧基官能材料和至少一种固化剂的组分形成的涂料组合物。 本发明的另一个实施方案涉及由包含至少一种酰胺官能材料的组分形成的涂料组合物，所述酰胺官能材料包含至少一个用可水解甲硅烷基封端的酰胺和至少一种固化剂。 本发明的其它实施方案涉及用上述固化组合物涂覆的基材。 还提供了多组分复合涂层，其包括由着色涂料组合物沉积的固化底涂层和从表面涂层组合物沉积的固化顶涂层。 本发明的多组分复合涂层提供高耐刮擦的彩色 - 透明涂层。 本发明的其它实施方案涉及用于改善基材的耐刮擦性的方法。

公开(公告)号：US07132476B2

公开(公告)日：2006-11-07

申请号：US10887682

申请日：2004-07-09

申请人： Simion Coca ,  Edward R. Coleridge ,  Gregory J. McCollum ,  James B. O'Dwyer ,  James E. Poole ,  Victoria A. Trettel

发明人： Simion Coca ,  Edward R. Coleridge ,  Gregory J. McCollum ,  James B. O'Dwyer ,  James E. Poole ,  Victoria A. Trettel

IPC分类号： C08F8/00

CPC分类号： B05D7/57 ,  B05D1/007 ,  B05D3/0209 ,  B05D3/067 ,  B05D7/53 ,  C08F8/00 ,  C08F210/10 ,  C08F220/10 ,  C08F290/046 ,  C08G18/6229 ,  C08G18/792 ,  C08G18/798 ,  C08G18/8025 ,  C08G18/807 ,  C08G18/8074 ,  C08G2150/20 ,  C08L33/068 ,  C09D123/22 ,  C09D133/062 ,  C09D133/08 ,  Y10T428/31504 ,  Y10T428/31511 ,  C08F220/00 ,  C08F220/12 ,  C08F210/00 ,  C08L2666/28 ,  C08L2666/02 ,  C08F214/18 ,  C08F2500/03 ,  C08F2500/02 ,  C08F212/00 ,  C08F222/00 ,  C08F2500/26 ,  C08L2666/04

摘要： A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.

公开(公告)号：US06715196B2

公开(公告)日：2004-04-06

申请号：US10025406

申请日：2001-12-19

申请人： John Reising ,  Richard S. Tansey ,  Gregory J. McCollum ,  Ronald J. Isger

发明人： John Reising ,  Richard S. Tansey ,  Gregory J. McCollum ,  Ronald J. Isger

IPC分类号： B23P2500

CPC分类号： B05D7/576 ,  B05D5/068 ,  B05D7/577 ,  B05D2202/10 ,  B05D2701/40 ,  Y10T29/49885 ,  Y10T29/49982 ,  Y10T428/12569

摘要： A method of coating metallic substrates with weldable primer and at least one powder coating is provided by the present invention. The base powder coating contains flake pigments that align parallel to the surface when the powder coating is heated. Optionally, a clear top coating is applied over the base powder coating. Substrates coated by the method of coating are also provided. The method of coating allows substrates coated with weldable primer to be assembled into assemblies or finished parts by welding, and then to be coated with the powder basecoat and clear coat. The parts prepared have striking visual effects and performance comparable to conventional automotive parts but are prepared more efficiently and economically.

摘要翻译： 本发明提供了一种用可焊接底漆涂覆金属基材和至少一种粉末涂料的方法。 基础粉末涂料含有当粉末涂料被加热时平行于表面排列的片状颜料。 任选地，在基底粉末涂层上施加透明顶涂层。 还提供了通过涂覆方法涂覆的基材。 涂覆方法允许用可焊接底漆涂覆的基材通过焊接组装成组件或成品部件，然后涂覆粉末底漆和透明涂层。 制备的零件具有惊人的视觉效果和性能，与传统的汽车零件相当，但更有效和经济地制备。

公开(公告)号：US06635341B1

公开(公告)日：2003-10-21

申请号：US09629421

申请日：2000-07-31

申请人： Steven V. Barancyk ,  John W. Burgman ,  James B. O'Dywer ,  Laura A. Kiefer-Liptak ,  Michael Allen Mayo ,  Gregory J. McCollum ,  Shiryn Tyebjee

发明人： Steven V. Barancyk ,  John W. Burgman ,  James B. O'Dywer ,  Laura A. Kiefer-Liptak ,  Michael Allen Mayo ,  Gregory J. McCollum ,  Shiryn Tyebjee

IPC分类号： B32B516

CPC分类号： C09D201/06 ,  C08G18/4692 ,  C08G18/792 ,  C09D167/00 ,  C09D175/04 ,  Y10T428/25 ,  Y10T428/251 ,  Y10T428/254 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2998 ,  Y10T428/31511 ,  Y10T428/31551 ,  C08L2666/28 ,  C08L2666/16

摘要： Coating compositions formed from at least one hydroxyl functional non-vinyl material comprising at least one alcoholic hydroxyl group blocked with a hydrolyzable silyl group, and at least one curing agent are provided by the present invention. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carbamate functional material comprising at least one carbamate group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carboxyl functional material comprising at least one carboxyl group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition, formed from components comprising at least one amide functional material comprising at least one amide blocked with a hydrolyzable silyl group, and at least one curing agent. Other embodiments of the present invention are directed to substrates coated with the aforementioned cured compositions. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings. Further embodiments of the present invention are directed to methods for improving scratch resistance of a substrate.

摘要翻译： 由至少一种包含至少一个用可水解甲硅烷基封端的醇羟基的羟基官能非乙烯基材料形成的涂料组合物和至少一种固化剂由本发明提供。 本发明的另一个实施方案涉及由包含至少一种氨基甲酸酯官能材料的组分形成的涂料组合物，所述氨基甲酸酯官能材料包含至少一个被可水解甲硅烷基封端的氨基甲酸酯基团和至少一种固化剂。 本发明的另一个实施方案涉及由包含至少一种包含至少一个被可水解甲硅烷基封端的羧基的羧基官能材料和至少一种固化剂的组分形成的涂料组合物。 本发明的另一个实施方案涉及由包含至少一种酰胺官能材料的组分形成的涂料组合物，所述酰胺官能材料包含至少一个用可水解甲硅烷基封端的酰胺和至少一种固化剂。 本发明的其它实施方案涉及用上述固化组合物涂覆的基材。 还提供了多组分复合涂层，其包括由着色涂料组合物沉积的固化底涂层和从表面涂层组合物沉积的固化顶涂层。 本发明的多组分复合涂层提供高耐刮擦的彩色 - 透明涂层。 本发明的其它实施方案涉及用于改善基材的耐刮擦性的方法。

公开(公告)号：US06509407B2

公开(公告)日：2003-01-21

申请号：US10044574

申请日：2002-01-11

申请人： Gregory J. McCollum ,  Linda K. Anderson ,  Simion Coca

发明人： Gregory J. McCollum ,  Linda K. Anderson ,  Simion Coca

IPC分类号： C08F832

CPC分类号： C09D5/4488 ,  C08L57/12 ,  C08L2666/02

摘要： Disclosed are thermosetting compositions which are comprised of a resinous phase dispersed in an aqueous medium, the resinous phase comprising (a) an ungelled active hydrogen group-containing polymer which contains amine salt groups, the polymer having been prepared by atom transfer radical polymerization in the presence of an initiator having at least one radically transferable group, and (b) a curing agent having at least two functional groups which are reactive with the active hydrogen groups of (a). The active hydrogen group-containing polymers of the thermosetting compositions, which are prepared by atom transfer radical polymerization, have narrow molecular weight distributions and well-defined, specifically tailored polymer architecture which can provide enhanced crosslink density and dispersibility of the thermosetting compositions. Also disclosed is a method of electrocoating a conductive substrate using the thermosetting compositions of the invention, and a substrate coated by this method.