摘要:
An antiinflammatory steroid exhibiting a tendency to crystal growth in suspension in aerosol propellants is contacted with a halogenated hydrocarbon to form a crystalline solvate, which, after removal of some or all of the propellant from the crystals, is reduced to a particle size permitting inhalation into the human bronchial system when dispersed as an aerosol, the micronised crystalline solvate not thereafter exhibiting crystal growth in the aerosol propellant. The solvate is a new composition of matter which has been characterized by I.R. spectra and the aerosol formulation prepared therefrom has valuable therapeutic properties, particularly in the treatment of asthma.
摘要:
Paraphenylene diacetate is the predominant product when phenylacetate, acetic acid and acetic anhydride are reacted in the presence of palladium and a gas mixture containing an inert gas and no more than 13 vol.% oxygen.
摘要:
A process has been developed for controlling the catalytic co-oligmoerization of 1,3-dienes with Schiff's bases which comprises condensing a 1,3-diene of the formula ##STR1## wherein R.sup.4 and R.sup.5, independently of one another, represent hydrogen or an alkyl group having 1 to 4 carbon atoms with a Schiff base of the formula ##STR2## wherein each of R.sup.1, R.sup.2 and R.sup.3 represents hydrogen alkyl, cycloalkyl, aralkyl, aryl or dimethylamino groups which, in addition, optionally contain functional groups of the group consisting of ethers esters, C.dbd.N double bonds and which can be closed to form a ring, in the presence of a nickel (O)-containing catalyst, and optionally in the presence of an X--H compound with a molar ratio of Ni: X H of from 1:0 to 1:10.
摘要:
Process for preparing a supported Ziegler catalyst precursor by heating together, at a temperature in the range 150.degree.-1000.degree. C, an inorganic support having surface hydroxyl groups and a magnesium compound selected from the oxide, hydroxides, salts and alkoxides and incorporating a transition metal compound therein.
摘要:
A diamond synthesis run containing synthetic diamonds, graphite and catalyst from a high pressure temperature diamond process is treated with bromine to remove substantially all of the graphite. After bromination, the run is subjected to electrolysis to remove the catalyst metals leaving the diamond product for recovery. Some of the diamonds may have a layer of graphite which is exfoliated by further treatment with liquid bromine.
摘要:
A process for preparing a cobalt-based Fischer-Tropsch synthesis catalyst includes introducing a soluble modifying component precursor of the formula Mc(OR)x, where Mc is a modifying component selected from the group comprising Si, Ti, Cu, Zn, Zr, Mn, Ba, Ni, Na, K, Ca, Sn, Cr, Fe, Li, Tl, Sr, Ga, Sb, V, Hf, Th, Ce, Ge, U, Nb, Ta, W or La, R is an alkyl or acyl group, and x is an integer having a value of from 1 to 5, onto and/or into a cobalt-based Fischer-Tropsch synthesis catalyst precursor, which comprises a porous pre-shaped catalyst support supporting cobalt in an oxidized form. The resultant modified cobalt-based Fischer-Tropsch synthesis catalyst precursor is reduced to obtain a cobalt-based Fischer-Tropsch synthesis catalyst.
摘要:
The present invention relates to novel agropolymers, which comprise a carbohydrate and/or silica matrix substantially devoid of proteins, tannins and polyphenols and which comprise metal binding reactive sites. A method of producing the agropolymers is also disclosed wherein the agropolymers are derived from plant materials such as seed coats, seed covers, husks, or hulls of various agricultural crops. The agricultural crops typically used to produce the agropolymers include Oryza sativa, Panicum miliaceum, Setaria italica, Cajanus cajan, Vigna mungo, Vigna radiata, Triticum sp., Ricinus communis, Helianthus annus, Gossypium sp., and Arachis sp. The agropolymers of the present invention are capable of purifying aqueous solutions polluted or contaminated with metals and/or ions. Thus, the present invention also discloses a method whereby agropolymers are used in the purification of contaminated water and other aqueous solutions. The agropolymers disclosed herein are useful in several industrial applications including purifying polluted drinking water or ground water.
摘要:
A particulate pre-reduction cobalt supported Fischer-Tropsch synthesis catalyst precursor which comprises a catalyst support impregnated with cobalt, is treated with a pure hydrogen reducing gas, at a first specific feed gas space velocity, SV1, and at a first heating rate, HR1, to obtain a partially reduced precursor. The support contains reducible cobalt oxide in a calcined state and having a formula-unit in which each mole of cobalt atoms is associated with more than 4/3 moles of oxygen atoms and displaying a reducible cobalt oxide specific surface area at least equal to that of Co3O4 spinel. The partially reduced precursor is then treated with a pure hydrogen reducing gas, at a second specific feed gas space velocity, SV2, and at a second heating rate, HR2, to obtain an activated supported Fischer-Tropsch catalyst, with SV2≦SV1 and/or HR2≧HR1; however, when SV2=SV1, HR2≠HR1 and when HR2=HR1, SV2≠SV1.
摘要翻译:以纯氢还原气体,以第一特定进料气体空间速度SV1处理包含浸渍有钴的催化剂载体的颗粒状预还原钴 - 费 - 托合成催化剂前体,并且以第一加热速率HR1 ,以获得部分还原的前体。 载体含有煅烧状态的可还原的氧化钴,具有式 - 单元,其中每摩尔的钴原子与多于4/3摩尔的氧原子缔合,并且显示可还原的氧化钴比表面积至少等于 Co 3 N 4 O 4尖晶石。 然后将部分还原的前体用纯氢还原气体以第二特定进料气体空间速度SV2处理,并以第二加热速率HR2处理,得到活化的支持的费 - 托催化剂,其中SV2 <= SV1和 /或HR2> = HR1; 然而,当SV2 = SV1,HR2 SV1。
摘要:
The invention includes methods for isolating crystalline Form I of 5-azacytidine substantially free of other forms, wherein 5-azacytidine is represented by the formula: The invention also includes pharmaceutical compositions comprising Form I of 5-azacytidine.
摘要:
A photocatalytic/thermocatalytic coating includes an inner layer of metal/titanium dioxide or metal oxide/titanium dioxide that is applied on a honeycomb and an outer layer of titanium dioxide or metal oxide doped titanium dioxide applied on the inner layer. The inner layer of can be gold/titanium dioxide, platinum/titanium dioxide, or manganese oxide/titanium dioxide. The outer layer of titanium dioxide or metal oxide doped titanium dioxide oxides volatile organic compounds to carbon dioxide, water, and other substances. As the outer layer is thin and porous, the contaminants in the air can diffuse through the outer layer and adsorb onto the inner layer. When photons of the ultraviolet light are absorbed by the coating, reactive hydroxyl radicals are formed that oxidize the contaminant to produce water, carbon dioxide, and other substances.