-
公开(公告)号:US12106971B2
公开(公告)日:2024-10-01
申请号:US17135216
申请日:2020-12-28
发明人: Xiangyu Guo , Kayla Diemoz , Nathan Stafford
IPC分类号: H01L21/311
CPC分类号: H01L21/31144 , H01L21/31116
摘要: Disclosed are methods for forming a high aspect ratio (HAR) structure during a HAR etch process in a substrate in a reaction chamber, the method comprising:
sequentially or simultaneously exposing the substrate to a vapor of an etchant including a hydrofluorocarbon or fluorocarbon compound and an additive compound, the substrate having a film disposed thereon and a pattered mask layer disposed on the film;
activating a plasma to produce an activated hydrofluorocarbon or fluorocarbon compound and an activated additive compound; and
allowing an etching reaction to proceed between the film uncovered by the patterned mask layer and the activated hydrofluorocarbon or fluorocarbon compound and the activated additive compound to selectively etch the film from the patterned mask layer, thereby forming the HAR patterned structure.-
公开(公告)号:US20240162042A1
公开(公告)日:2024-05-16
申请号:US17974246
申请日:2022-10-26
发明人: Xiangyu GUO , Nathan STAFFORD
IPC分类号: H01L21/3065
CPC分类号: H01L21/30655
摘要: A method for forming an aperture pattern in a substrate, the substrate including a film disposed thereon and a patterned mask layer disposed on the film, comprises 1) exposing the substrate to a vapor of a passivation molecule in a non-plasma condition for a period to form a surface protective layer on the patterned mask layer, 2) exposing the substrate to a plasma activated etch gas and plasma dry etching the substrate to form apertures over the patterned mask layer in the film with the plasma activated etch gas, and 3) repeating step 1) and 2) until a desired aperture pattern is formed in the film, wherein the surface protective layer is also formed on the sidewalls of the apertures formed in the film, wherein the passivation molecule has a boiling point equal to or larger than 20° C.
-
公开(公告)号:US11837474B2
公开(公告)日:2023-12-05
申请号:US17945631
申请日:2022-09-15
IPC分类号: H01L21/311 , H01L29/66 , H01L21/3105
CPC分类号: H01L21/31116 , H01L21/31058 , H01L29/6653
摘要: Cyclic etch methods comprise the steps of: i) exposing a SiN layer covering a structure on a substrate in a reaction chamber to a plasma of hydrofluorocarbon (HFC) to form a polymer layer deposited on the SiN layer that modifies the surface of the SiN layer, the HFC having a formula CxHyFz where x=2-5, y>z, the HFC being a saturated or unsaturated, linear or cyclic HFC; ii) exposing the polymer layer deposited on the SiN layer to a plasma of an inert gas, the plasma of the inert gas removing the polymer layer deposited on the SiN layer and the modified surface of the SiN layer on an etch front; and iii) repeating the steps of i) and ii) until the SiN layer on the etch front is selectively removed, thereby forming a substantially vertically straight SiN spacer comprising the SiN layer on the sidewall of the structure.
-
4.
公开(公告)号:US20230253200A1
公开(公告)日:2023-08-10
申请号:US17666686
申请日:2022-02-08
申请人: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude , American Air Liquide, Inc.
发明人: Daehyeon KIM , Junhyun SONG , Wontae NOH , Venkateswara R. PALLEM
CPC分类号: H01L21/02192 , C07F5/00 , H01L21/0228 , C23C16/409 , H01L21/02205
摘要: The disclosed lanthanide precursor compounds include a cyclopentadienyl ligand having at least one aliphatic group as a substituent and at least one bidentate ligand. These precursors are suitable for depositing lanthanide containing films.
-
5.
公开(公告)号:US20230095074A1
公开(公告)日:2023-03-30
申请号:US17977619
申请日:2022-10-31
申请人: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude , American Air Liquide, Inc.
发明人: Yumin LIU , Jean-Marc GIRARD , Peng ZHANG , Fan QIN , Gennadiy ITOV , Fabrizio MARCHEGIANI , Thomas J. LARRABEE , Venkateswara R. PALLEM
IPC分类号: C09D183/14
摘要: A method of forming a gap filling on a substrate, the substrate having gaps formed therein, comprises: producing a gap filling polycarbosilazane polymer or oligomer by a polymerization of a reaction mixture of carbosilanes with amines; forming a solution containing the gap filling polycarbosilazane polymer or oligomer; and contacting the solution with the substrate via a spin-on coating, spray coating, dip coating, or slit coating technique to fill the gaps in the substrate forming the silicon and carbon containing gap filling, wherein a concentration of the gap filling polycarbosilazane polymer or oligomer in the solution ranges from 1 to 60 wt %.
-
公开(公告)号:US20210102092A1
公开(公告)日:2021-04-08
申请号:US16971873
申请日:2019-02-21
申请人: American Air Liquide, Inc. , L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
发明人: Antonio SANCHEZ , Gennadiy ITOV , Manish KHANDELWAL , Cole RITTER , Peng ZHANG , Jean-Marc GIRARD , Zhiwen WAN , Glenn KUCHENBEISER , David ORBAN , Sean KERRIGAN , Reno PESARESI , Matthew Damien STEPHENS , Yang WANG , Guillaume HUSSON , Grigory NIKIFOROV
IPC分类号: C09D183/16 , C08G77/62 , C08J5/18 , C08F4/72
摘要: A Si-containing film forming composition comprising a catalyst and/or a polysilane and a N—H free, C-free, and Si-rich perhydropolysilazane having a molecular weight ranging from approximately 332 dalton to approximately 100,000 dalton and comprising N—H free repeating units having the formula [—N(SiH3)×(SiH2−)y], wherein x=0, 1, or 2 and y=0, 1, or 2 with x+y=2; and x=0, 1 or 2 and y=1, 2, or 3 with x+y=3. Also disclosed are synthesis methods and applications for using the same.
-
公开(公告)号:US10858271B2
公开(公告)日:2020-12-08
申请号:US16046702
申请日:2018-07-26
申请人: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés George Claude , American Air Liquide, Inc.
IPC分类号: C02F1/78 , C02F1/72 , A01N59/00 , A61L2/18 , B01F3/08 , B01F3/20 , B01F5/10 , B01F15/00 , C01B13/10 , C02F1/32 , B01D53/22 , A61L2/20
摘要: Disclosed are methods for continuous production of ozone strong water, the methods comprising the steps of injecting an acidification agent into a pressurized feed water to maintain a pH value of the pressurized feed water below 7, diffusing a two-phase mixture of O2-O3 gas and recirculated water into a body of acidic pressurized water to dissolve ozone into the acidic pressurized water. The disclosed methods include simultaneously maintaining a start-up mode in an upper portion of the dissolution column that favors high efficiency of ozone mass transfer into the acidic pressurized water and a steady state mode in a lower portion of the dissolution column that favors a high concentration of dissolved ozone in the acidic pressurized water coexistent in the body of the acidic pressurized water, wherein an ozone concentration gradient is formed along a height of the body of the acidic pressurized water.
-
公开(公告)号:US10822673B1
公开(公告)日:2020-11-03
申请号:US16716630
申请日:2019-12-17
发明人: Sylvester Zuttah
摘要: Method for removing arsenic mineral from a lead concentrate by reverse flotation with an ozone pre-treatment. The method comprises the steps of: receiving a slurry of the lead concentrate that has previously undergone flotation processes, bubbling ozone into the slurry of the lead concentrate to remove reagents used in previous flotation processes, adding a sulfide salt to the slurry to depress lead mineral, adding an alkali to increase the pH of the slurry, adding a collector and then a frother to the slurry for a reverse flotation processing and floating the arsenic mineral out of the lead mineral to obtain a now-purified lead concentrate.
-
9.
公开(公告)号:US10669160B2
公开(公告)日:2020-06-02
申请号:US15966799
申请日:2018-04-30
申请人: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude , American Air Liquide, Inc.
发明人: Yumin Liu , Feng Li , Zhiwen Wan , Claudia Fafard , Stefan Wiese , Guillaume Husson , Grigory Nikiforov , Bin Sui , Jean-Marc Girard
IPC分类号: C01G41/04
摘要: Synthesis of tungsten pentahalide compositions having low impurity profiles are disclosed. The specific impurity profile permits deposition of high purity tungsten-containing films using vapor deposition processes or other semiconductor manufacturing processes without introduction of performance-impacting contaminants.
-
10.
公开(公告)号:US10570513B2
公开(公告)日:2020-02-25
申请号:US15535631
申请日:2015-12-10
发明人: Glenn Kuchenbeiser , Claudia Fafard
摘要: Disclosed are organosilane precursors, methods of synthesizing the same, and methods of using the same to deposit silicon-containing films using vapor deposition processes. The disclosed organosilane precursors have the following formula: SiHx(RN—(CR)n—NR)y(NRR)z wherein R may each independently be H, a C1 to C6 alkyl group, or a C3-C20 aryl or heterocycle group, x+y+z=4 and n, x, y and z are integers, provided that x≠3 when y=1. Preferably, n=1 to 3, x=0 to 2, y=1 to 2, and z=1 to 3.
-
-
-
-
-
-
-
-
-