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    Process for preparing a free rise or slabstock flexible polyurethane foam
    1.
    发明授权
    Process for preparing a free rise or slabstock flexible polyurethane foam 有权
    制备自由上升或块状软质聚氨酯泡沫的方法

    公开(公告)号：US06774153B2

    公开(公告)日：2004-08-10

    申请号：US10191371

    申请日：2002-07-01

    申请人： Alain Parfondry ,  Jianming Yu

    发明人： Alain Parfondry ,  Jianming Yu

    IPC分类号： C08G1848

    CPC分类号： C08G18/409 ,  C08G18/7664 ,  Y10S521/904

    摘要： Process for making free rise or slabstock flexible polyurethane foams with high resilience using diphenylmethane diisocyanate and a polyol composition comprising: (a) a polyoxyethylene-polyoxypropylene-polyol, having an average nominal hydroxyl functionality of 2-8, an average equivalent weight of 1000-4000 and containing 10-25% by weight of oxyethylene groups; (b) 3 to 8 parts by weight of water as the sole blowing agent or optionally together with CO2 as the sole blowing agents; and (c) 2 to 20, preferably 2 to 10 parts by weight of a polyether polyol having an average nominal hydroxyl functionality of 2-6, an average equivalent weight of 200-600 and containing at least 60% by weight of oxyethylene groups; and optionally (d) up to 30 and preferably 2-25 parts by weight of particulate material which is dispersed in said polyol composition; the amounts of (b)(ii) to (b)(iv) being calculated per 100 parts by weight of (b)(i); and optionally (e) auxiliaries and additives.

    摘要翻译： 使用二苯基甲烷二异氰酸酯和多元醇组合物制备具有高回弹性的自由起泡或块状软质聚氨酯泡沫的方法，所述多元醇组合物包含：（a）平均标称羟基官能度为2-8的聚氧乙烯 - 聚氧丙烯多元醇，平均当量为1000- 4000，含有10-25重量％的氧化乙烯基团; （b）作为唯一发泡剂的3至8重量份的水或任选地与作为唯一发泡剂的CO 2一起; 和（c）2至20，优选2至10重量份的平均标称羟基官能度为2-6的聚醚多元醇，平均当量为200-600，并含有至少60重量％的氧化乙烯基团; 和任选地（d）最多30个，优选2-25重量份的分散在所述多元醇组合物中的颗粒材料; （b）（ii）至（b）（iv）的量按（b）（i）每100重量份计算; 和任选的（e）助剂和添加剂。

    Process for making high resilience foams
    2.
    发明授权
    Process for making high resilience foams 有权
    制造高弹性泡沫的工艺

    公开(公告)号：US06593387B2

    公开(公告)日：2003-07-15

    申请号：US10122454

    申请日：2002-04-12

    申请人： Alain Parfondry ,  Jianming Yu

    发明人： Alain Parfondry ,  Jianming Yu

    IPC分类号： C08G1810

    CPC分类号： C08G18/4837 ,  C08G18/10 ,  Y10S521/904 ,  C08G18/48

    摘要： The invention relates to a prepolymer process for preparing a high resilience flexible polyurethane foam by reacting a polyisocyanate composition comprising at least 80% by weight of 4,4′-MDI and having an NCO value below 20% with a polyol composition comprising b1) an EO-rich polyol; b2) a polyol with an EO content between 20-50% and a primary hydroxy content of at least 50%; and b3) a polyol with an EO content between 10-20% and a primary hydroxy content of at least 50%; according to the following proportions: b1:40-90 wt %, b2:5-60 wt %, b3:0-20 wt %. The invention also relates to reaction systems comprising the above components.

    摘要翻译： 本发明涉及通过使包含至少80重量％的4,4'-MDI和NCO值低于20％的多异氰酸酯组合物与多元醇组合物反应制备高弹性软质聚氨酯泡沫的预聚物方法，所述多元醇组合物包含：b1） 富含EO的多元醇; b2）EO含量为20-50％，伯羟基含量至少为50％的多元醇; 和b3）EO含量为10-20％且伯羟基含量为至少50％的多元醇; 根据以下比例：b1：40-90重量％，b2：5-60重量％，b3：0-20重量％。本发明还涉及包含上述组分的反应体系。

    Process for making high resilience foams
    3.
    发明授权
    Process for making high resilience foams 有权
    制造高弹性泡沫的工艺

    公开(公告)号：US06784217B2

    公开(公告)日：2004-08-31

    申请号：US10458901

    申请日：2003-06-11

    申请人： Alain Parfondry ,  Jianming Yu

    发明人： Alain Parfondry ,  Jianming Yu

    IPC分类号： C08G1810

    CPC分类号： C08G18/4837 ,  C08G18/10 ,  Y10S521/904 ,  C08G18/48

    摘要： A prepolymer process for preparing a high resilience flexible polyurethane foam by reacting a polyisocyanate composition comprising at least 80% by weight of 4,4′-MDI and having an NCO value below 20% with a polyol composition comprising b1) an EO-rich polyol; b2) a polyol with an EO content between 20-50% and a primary hydroxy content of at least 50%; and b3) a polyol with an EO content between 10-20% and a primary hydroxy content of at least 50%; according to the following proportions: b1: 40-90 wt %, b2: 5-60 wt %, b3: 0-20 wt %. The invention also relates to reaction systems comprising the above components.

    摘要翻译： 一种通过使包含至少80重量％的4,4'-MDI和NCO值低于20％的多异氰酸酯组合物与多元醇组合物反应制备高弹性软质聚氨酯泡沫的预聚物方法，所述多元醇组合物包含：富含EO的多元醇多元醇 ; b2）EO含量为20-50％，伯羟基含量至少为50％的多元醇; 和b3）EO含量为10-20％且伯羟基含量为至少50％的多元醇; 根据以下比例：b1：40-90重量％，b2：5-60重量％，b3：0-20重量％。 本发明还涉及包含上述组分的反应体系。

    Process for making cold-setting flexible foams, polyol composition and reaction system useful therefor, foams thus obtained
    4.
    发明授权
    Process for making cold-setting flexible foams, polyol composition and reaction system useful therefor, foams thus obtained 失效
    用于制备冷定型柔性泡沫的方法，可用于其的多元醇组合物和反应体系，由此获得的泡沫

    公开(公告)号：US06506813B1

    公开(公告)日：2003-01-14

    申请号：US10030385

    申请日：2002-01-10

    申请人： Alain Parfondry ,  Jianming Yu

    发明人： Alain Parfondry ,  Jianming Yu

    IPC分类号： C08G1848

    CPC分类号： C08G18/6688 ,  C08G18/10 ,  C08G18/482 ,  C08G2101/0008 ,  C08G2101/0083 ,  C08L71/02 ,  C08G18/48 ,  C08L71/00

    摘要： The invention relates to a polyol composition comprising b1) a polyol where the EO content is at least 50%; b2) a polyol having a primary hydroxyl content of at least 50%; b3) an amine-initiated polyoxypropylene polyol having an OH value greater than 400, according to the following proportions: b1: 20-70 wt %, b2: 5-50 wt %, b3: 5-50 wt %. The invention also relates to a process for preparing a cold-setting flexible polyurethane foam at NCO index of 70-120 by reacting a) a polyisocyanate; the polyols b1), b2) and b3); c) water; and d) additives and auxiliaries known per se. The invention finally relates to a reaction system comprising A) a polyisocyanate and B) an isocyanate-reactive component comprising the polyols b1), b2) and b3).

    摘要翻译： 本发明涉及多元醇组合物，其包含b1）多元醇，其中EO含量为至少50％; b2）伯羟基含量为至少50％的多元醇; b3）根据以下比例具有OH值大于400的胺引发的聚氧丙烯多元醇：b1：20-70重量％，b2：5-50重量％，b3：5-50重量％。 本发明还涉及一种通过使a）多异氰酸酯反应制备NCO指数为70-120的冷定型柔性聚氨酯泡沫的方法。 多元醇b1），b2）和b3）; c）水; 和d）本身已知的添加剂和助剂。 本发明最终涉及包含A）多异氰酸酯和B）包含多元醇b1），b2）和b3）的异氰酸酯反应性组分的反应体系。

    Process for making visco-elastic foams, polyols blend and reaction system useful therefor
    7.
    发明授权
    Process for making visco-elastic foams, polyols blend and reaction system useful therefor 有权
    制备粘弹性泡沫的方法，多元醇混合物和对其有用的反应体系

    公开(公告)号：US06617369B2

    公开(公告)日：2003-09-09

    申请号：US10122435

    申请日：2002-04-12

    申请人： Alain Parfondry ,  Jianming Yu

    发明人： Alain Parfondry ,  Jianming Yu

    IPC分类号： C08G1814

    CPC分类号： C08G18/4841 ,  C08G18/4804 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083 ,  Y10S521/904

    摘要： The invention relates to a one-shot or prepolymer process for preparing a visco-elastic polyurethane foam by reacting a polyisocyanate composition with a polyol composition comprising b1) an EO-rich polyol; b2) a polyol with an EO content between 20-50% and a primary hydroxy content of at least 50%; b3) a polyol with an EO content between 10-20% and a primary hydroxy content of at least 50%; and b4) a polyalkyleneglycol; according to the following proportions: b1: 30-85 wt %, b2: 5-65 wt %, b3: 5-40 wt %, b4: 0-50 wt %. The invention also relates to reaction systems comprising the above components and to the polyol composition.

    摘要翻译： 本发明涉及通过使多异氰酸酯组合物与多元醇组合物反应制备粘弹性聚氨酯泡沫体的单次或预聚物方法，所述多元醇组合物包含：b1）富含EO的多元醇; b2）EO含量为20-50％，伯羟基含量至少为50％的多元醇; b3）EO含量为10-20％且伯羟基含量为至少50％的多元醇; 和b4）聚亚烷基二醇; 根据以下比例：b1：30-85重量％，b2：5-65重量％，b3：5-40重量％，b4：0-50重量％。本发明还涉及包含上述组分和 涉及多元醇组合物。

    Process for making low density foams, polyol composition and reaction system useful therefor
    8.
    发明授权
    Process for making low density foams, polyol composition and reaction system useful therefor 有权
    制备低密度泡沫的方法，多元醇组合物和对其有用的反应体系

    公开(公告)号：US06590008B1

    公开(公告)日：2003-07-08

    申请号：US09979849

    申请日：2002-03-01

    申请人： Alain Parfondry ,  Jianming Yu

    发明人： Alain Parfondry ,  Jianming Yu

    IPC分类号： C08G1810

    CPC分类号： C08G18/4072 ,  C08G18/4816 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083

    摘要： The invention relates to a polyol composition comprising by weight 60-97% of b1) a polyoxyethylene-polyoxypropylene polyol, having a functionality of 2-6, with 10-25% tipped EO, 3-40% of b2) a polyoxyethylene-polyoxypropylene polyol, having a functionality of 2-6, with 20-50% total EO and 10-20% tipped EO; and 0-25% of b3) a polyol, having a functionality of 2-6, with at least 50% random EO. The invention also relates to a process for preparing a flexible polyurethane foam by reacting a) a polyisocyanate composition; b) a polyol composition of the invention; c) water; and d) additives and auxiliaries known per se. The invention finally relates to a reaction system comprising A) a polyisocyanate and B) an isocyanate-reactive component comprising the polyol of the invention.

    摘要翻译： 本发明涉及一种多元醇组合物，该组合物包含重量百分比为60-97％的b1）聚氧乙烯 - 聚氧丙烯多元醇，其官能度为2-6，具有10-25％的EO，3-40％的b2）聚氧乙烯 - 聚氧丙烯 多官能度为2-6，总EO为20-50％，末端EO为10-20％的多元醇; 和0-25％的b3）官能度为2-6的多元醇，具有至少50％的随机EO。 本发明还涉及通过使a）多异氰酸酯组合物与多异氰酸酯组合物反应来制备软质聚氨酯泡沫的方法; b）本发明的多元醇组合物; c）水; 和d）本身已知的添加剂和助剂。 本发明最终涉及包含A）多异氰酸酯和B）包含本发明多元醇的异氰酸酯反应性组分的反应体系。