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公开(公告)号：US5557024A
公开(公告)日：1996-09-17
申请号：US452919
申请日：1995-05-30
申请人： Jane C. Cheng , Anthony D. Fung , Donald J. Klocke , Stephen L. Lawton , Daria N. Lissy , Wieslaw J. Roth , C. Morris Smith , Dennis E. Walsh
发明人： Jane C. Cheng , Anthony D. Fung , Donald J. Klocke , Stephen L. Lawton , Daria N. Lissy , Wieslaw J. Roth , C. Morris Smith , Dennis E. Walsh
IPC分类号： B01J20/18 , B01J29/03 , B01J29/06 , B01J29/40 , B01J29/70 , C01B33/38 , C01B35/00 , C01B39/00 , C01B39/02 , C01B39/48 , C07C2/66 , C07C15/02 , C10G35/06 , C10G35/095
CPC分类号： B01J29/70 , B01J37/0009 , C01B33/38 , B01J2229/42
摘要： Relatively short chain alkyl aromatic compounds are prepared by alkylating an alkylatable aromatic compound with a relatively short chain alkylating agent under sufficient reaction conditions in the presence of a catalyst comprising zeolite MCM-56. The liquid phase syntheses of ethylbenzene and cumene are particular examples of such MCM-56 catalyzed reactions.
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公开(公告)号：US5453554A
公开(公告)日：1995-09-26
申请号：US249609
申请日：1994-05-26
申请人： Jane C. Cheng , Anthony S. Fung , Donald J. Klocke , Stephen L. Lawton , Daria N. Lissy , Wieslaw J. Roth , C. Morris Smith , Dennis E. Walsh
发明人： Jane C. Cheng , Anthony S. Fung , Donald J. Klocke , Stephen L. Lawton , Daria N. Lissy , Wieslaw J. Roth , C. Morris Smith , Dennis E. Walsh
IPC分类号： B01J20/18 , B01J29/03 , B01J29/06 , B01J29/40 , B01J29/70 , C01B33/38 , C01B35/00 , C01B39/00 , C01B39/02 , C01B39/48 , C07C2/66 , C07C15/02 , C10G35/06 , C10G35/095
CPC分类号： B01J29/70 , B01J37/0009 , C01B33/38 , B01J2229/42
摘要： Relatively short chain alkyl aromatic compounds are prepared by alkylating an alkylatable aromatic compound with a relatively short chain alkylating agent under sufficient reaction conditions in the presence of a catalyst comprising zeolite MCM-56. The liquid phase syntheses of ethylbenzene and cumene are particular examples of such MCM-56 catalyzed reactions.
摘要翻译： 通过在含有沸石MCM-56的催化剂的存在下，在足够的反应条件下，用相对短链的烷基化剂烷基化可烷基化芳族化合物来制备相对短链烷基芳族化合物。 乙苯和枯烯的液相合成是这种MCM-56催化反应的具体实例。
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3.发明授权Highly selective N-olefin isomerization process using microcrystalline ZSM-22 失效使用微晶ZSM-22的高选择性N-烯烃异构化方法
公开(公告)号：US5237121A
公开(公告)日：1993-08-17
申请号：US925442
申请日：1992-08-11
IPC分类号： C07C5/27
CPC分类号： C07C5/2775
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-22 having a crystal size whose largest dimension is no greater than 0.5 micron. The process is carried out under isomerization conditions to produce iso-olefins of corresponding carbon number, e.g., isobutene. High overall iso-olefin yields thus can be obtained, even at relatively low temperatures.
摘要翻译： 公开了一种用于在高水平进料转化率下将含线性烯烃的有机原料高度选择性骨架异构化成异烯烃的方法，其中线性烯烃例如正丁烯与包含ZSM-22的催化剂接触，ZSM-22的晶体尺寸 最大尺寸不大于0.5微米。 该方法在异构化条件下进行以产生相应碳数的异烯烃，例如异丁烯。 即使在相对较低的温度下也能获得高的全部异烯烃收率。
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公开(公告)号：US5516959A
公开(公告)日：1996-05-14
申请号：US357841
申请日：1994-12-09
CPC分类号： B01J29/7042 , B01J29/65 , B01J29/7046 , C07C5/2775 , B01J2229/26 , B01J2229/42
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-35 under skeletal isomerization conditions which can include temperatures of 100 to 750.degree. C. The process uses a catalyst composition comprising ZSM-35, e.g., microcrystalline ZSM-35 having a crystal size whose largest dimension is no greater than 0.5 micron and whose ratio of its second largest dimension to said largest dimension ranges from 0.5 to 1. The process exhibits enhanced catalyst cycle life where the ZSM-35 is composited with a silica-containing matrix to provide a catalyst composite having a total pore volume greater than 0.6 cc/g or 300.sup.+ angstroms pore volume of greater than 0.1 cc/g.
摘要翻译： 公开了一种用于在高水平进料转化率下将含线性烯烃的有机原料高度选择性骨架异构化为异烯烃的方法，其中线性烯烃例如正丁烯在骨架异构化条件下与包含ZSM-35的催化剂接触， 可以包括100至750℃的温度。该方法使用包含ZSM-35的催化剂组合物，例如具有最大尺寸不大于0.5微米的晶体尺寸的微晶ZSM-35，其第二大尺寸与所述 最大尺寸范围为0.5至1.该方法表现出增强的催化剂循环寿命，其中ZSM-35与含二氧化硅的基质复合以提供总孔体积大于0.6cc / g或300多埃孔体积的催化剂复合材料 大于0.1cc / g。
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5.发明授权Highly selective n-olefin isomerization process using low zeolite content ZSM-35 catalyst 失效使用低沸石含量的ZSM-35催化剂的高选择性正烯烃异构化方法
公开(公告)号：US5523511A
公开(公告)日：1996-06-04
申请号：US228779
申请日：1994-04-18
CPC分类号： B01J29/65 , B01J29/7042 , B01J29/7046 , C07C5/2775 , B01J2229/26 , B01J2229/42
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-35 under skeletal isomerization conditions which can include temperatures of 100.degree. to 750.degree. C. and linear olefin space velocities of less than 30 WHSV. The process uses a catalyst composition comprising 5 to 40 wt % ZSM-35, and 60 to 95 wt % inorganic oxide matrix, e.g., silica.
摘要翻译： 公开了一种用于在高水平进料转化率下将含线性烯烃的有机原料高度选择性骨架异构化为异烯烃的方法，其中线性烯烃例如正丁烯在骨架异构化条件下与包含ZSM-35的催化剂接触， 可以包括100℃至750℃的温度和低于30WHSV的线性烯烃空速。 该方法使用包含5至40重量％的ZSM-35和60至95重量％的无机氧化物基质如二氧化硅的催化剂组合物。
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公开(公告)号：US5449851A
公开(公告)日：1995-09-12
申请号：US49586
申请日：1993-04-19
CPC分类号： B01J29/65 , C07C5/2775 , B01J2229/26 , B01J2229/42 , B01J29/7042 , B01J29/7046
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-35 under isomerization conditions to produce iso-olefins of corresponding carbon number, e.g., isobutene. High iso-olefin selectivities thus can be obtained, even at relatively low temperatures and high linear olefin partial pressures.
摘要翻译： 公开了一种用于线性烯烃的有机原料的高度选择性骨架异构化的方法，其中线性烯烃例如正丁烯在异构化条件下与包含ZSM-35的催化剂接触以产生相应碳数的异烯烃，例如， 异丁烯 因此，即使在较低的温度和高的线性烯烃分压下，也可以获得高的异烯烃选择性。
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7.发明授权Highly selective n-olefin isomerization process using microcrystalline ZSM-22 失效使用微晶ZSM-22的高选择性n-烯烃异构化方法
公开(公告)号：US5157194A
公开(公告)日：1992-10-20
申请号：US811355
申请日：1991-12-20
CPC分类号： C07C5/2775
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-22 having a crystal size whose largest dimension is no greater than 0.5 micron. The process is carried out under isomerization conditions to produce iso-olefins of corresponding carbon number, e.g., isobutene. High overall iso-olefin yields thus can be obtained, even at relatively low temperatures.
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8.发明授权Method for preparing a zeolite catalyst bound with a refractory oxide of low acidity 失效制备与低酸度的难熔氧化物结合的沸石催化剂的方法
公开(公告)号：US5053374A
公开(公告)日：1991-10-01
申请号：US431002
申请日：1989-11-02
申请人： Robert P. L. Absil , Philip J. Angevine , Joseph A. Herbst , Donald J. Klocke , John P. McWilliams , Scott Han , David S. Shihabi
发明人： Robert P. L. Absil , Philip J. Angevine , Joseph A. Herbst , Donald J. Klocke , John P. McWilliams , Scott Han , David S. Shihabi
CPC分类号： B01J37/0009 , B01J29/084 , B01J29/7007
摘要： Low acidity refractory oxide-bound zeolite catalysts, for example, silica-bound ultrastable Y zeolite, possessing physical properties, e.g., crush strength, similar to those of their alumina-bound counterparts are described. Since low acidity refractory oxide-bound catalysts are inherently less active than alumina-bound zeolite catalysts, the former are particularly useful in hydrocarbon conversion processes in which reduced coke make increases catalyst cycle length. Due to their stability in acid environments, the low acidity refractory oxide-bound zeolite extrudate herein can be acid treated without unduly compromising its structural integrity.
摘要翻译： 描述了具有类似于其氧化铝结合的对应物的物理性能，例如粉碎强度的低酸度难熔氧化物结合的沸石催化剂，例如二氧化硅结合的超稳定Y沸石。 由于低酸度难熔氧化物结合的催化剂固有地比氧化铝结合的沸石催化剂具有更低的活性，因此前者在烃转化方法中特别有用，其中减少的焦炭使催化剂循环长度增加。 由于其在酸性环境中的稳定性，本文中低酸度难熔氧化物结合的沸石挤出物可以进行酸处理，而不会不利地损害其结构完整性。
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9.发明授权Low nitrogen iron-containing Fischer-Tropsch catalyst for conversion of synthesis gas and process for preparing the catalyst 失效用于转化合成气的低含氮铁的费 - 托催化剂和用于制备催化剂的方法
公开(公告)号：US4617288A
公开(公告)日：1986-10-14
申请号：US687695
申请日：1984-12-31
IPC分类号： B01J23/745 , B01J23/75 , B01J23/80 , B01J23/881 , B01J23/89 , C07C1/04 , B01J23/72 , B01J23/85
CPC分类号： B01J23/745 , B01J23/75 , B01J23/80 , B01J23/881 , B01J23/8906 , C07C1/0445 , C07C2521/02 , C07C2523/04 , C07C2523/06 , C07C2523/26 , C07C2523/28 , C07C2523/44 , C07C2523/72 , C07C2523/745 , C07C2523/75
摘要： Synthesis gas (a mixture of hydrogen gas and carbon monoxide) is converted to hydrocarbons by flowing the gas first over iron-containing Fischer-Tropsch catalyst and then over a zeolite. The Fischer-Tropsch catalyst contains relatively little nitrogen as a result of its preparation by continuous precipitation at a pH ranging from about 6.6 to 6.9 and a temperature ranging from about 80.degree. to about 100.degree. C.
摘要翻译： 将气体首先流过含铁费 - 托催化剂，然后通过沸石，将合成气（氢气和一氧化碳的混合物）转化成烃。 由于其在约6.6至6.9的pH和约80至约100℃的温度下连续沉淀制备，费 - 托催化剂含有相对较少的氮。
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公开(公告)号：US5538711A
公开(公告)日：1996-07-23
申请号：US376256
申请日：1995-01-23
申请人： Sean C. Emerson , Donald J. Klocke
发明人： Sean C. Emerson , Donald J. Klocke
摘要： A method for synthesizing an ultra-large pore crystalline material which can be used as a sorbent or catalyst component for the conversion of organic and inorganic compounds is improved through the addition of an antifoaming agent. The addition of antifoaming agents reduces foaming without interfering with material synthesis. Elimination of foam allows for easier charging of autoclaves and processing of synthesis mixtures.
摘要翻译： 通过添加消泡剂，可以提高合成可用作有机和无机化合物转化的吸附剂或催化剂组分的超大孔结晶材料的方法。 消泡剂的添加可减少发泡而不干扰材料合成。 消除泡沫可以更容易地对高压釜进行充电并加工合成混合物。
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