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1.发明授权公开(公告)号：US08338626B2
公开(公告)日：2012-12-25
申请号：US13314618
申请日：2011-12-08
IPC分类号： C07D307/02 , C07D307/48
CPC分类号： C07D307/46 , C10L1/02 , Y02P20/127
摘要： Method for the manufacture of 5-alkoxymethylfurfural derivatives by reacting a fructose and/or glucose-containing starting material with an alcohol in the presence of a catalytic or sub-stoechiometric amount of heterogeneous acid catalyst. The catalysts may be employed in a continuous flow fixed bed or catalytic distillation reactor. The ethers can be applied as a fuel or fuel additive.
摘要翻译： 通过在催化剂或亚化学量的多相酸催化剂存在下使果糖和/或含葡萄糖的原料与醇反应制备5-烷氧基甲基糠醛衍生物的方法。 催化剂可用于连续流动固定床或催化蒸馏反应器中。 醚可以作为燃料或燃料添加剂使用。
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2.发明授权公开(公告)号：US08877950B2
公开(公告)日：2014-11-04
申请号：US12968378
申请日：2010-12-15
IPC分类号： C07D307/02 , C10L1/02 , C07D307/46
CPC分类号： C07D307/46 , C10L1/02 , Y02P20/127
摘要： Method for the manufacture of 5-hydroxymethylfurfural derivatives by reacting a fructose and/or glucose-containing starting material with an alcohol in the presence of a catalytic or sub-stoichiometric amount of solid (“heterogeneous”) acid catalyst. The catalysts may be employed in a continuous flow fixed bed or catalytic distillation reactor. The ethers can be applied as a fuel or fuel additive.
摘要翻译： 在催化剂或亚化学计量的固体（“异质”）酸催化剂存在下，通过使果糖和/或含葡萄糖的原料与醇反应制备5-羟甲基糠醛衍生物的方法。 催化剂可用于连续流动固定床或催化蒸馏反应器中。 醚可以作为燃料或燃料添加剂使用。
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公开(公告)号：US20100081833A1
公开(公告)日：2010-04-01
申请号：US12517112
申请日：2008-09-05
申请人： Gerardus Johannes Maria Gruter , Leo Ernest Manzer , Ano Sofia Vagueiro De Sousa Dias , Frits Dautzenberg , Jindra Purmova
发明人： Gerardus Johannes Maria Gruter , Leo Ernest Manzer , Ano Sofia Vagueiro De Sousa Dias , Frits Dautzenberg , Jindra Purmova
IPC分类号： C07D307/34
CPC分类号： C07D307/46 , C10L1/1857
摘要： Accordingly, the current invention provides a method for the manufacture of an ether or ester of 5-hydroxymethyl-furfural by reacting a hexose-containing starting material or HMF with an alcohol or an organic acid dissolved into an ionic liquid, using a metal chloride as catalyst.
摘要翻译： 因此，本发明提供了通过使含己糖的起始物质或HMF与溶解在离子液体中的醇或有机酸反应，使用金属氯化物作为反应产生5-羟甲基 - 糠醛的醚或酯的方法 催化剂。
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公开(公告)号：US20070227951A1
公开(公告)日：2007-10-04
申请号：US11598000
申请日：2004-05-31
IPC分类号： C10G27/10
CPC分类号： C10G21/06 , C10G21/16 , C10G21/20 , C10G21/27 , C10G25/00 , C10G25/02 , C10G25/05 , C10G27/04 , C10G45/02 , C10G53/04 , C10G53/08 , C10G53/14 , C10G67/04 , C10G67/06 , C10G67/12 , C10G67/14
摘要： A process for removing sulfur-containing compounds from fuel, said process comprising contacting the fuel in liquid phase with air to oxidise the sulfur containing compounds, said contacting being carried out in the presence of at least one transition metal oxide catalyst.
摘要翻译： 一种从燃料中除去含硫化合物的方法，所述方法包括使液相中的燃料与空气接触以氧化含硫化合物，所述接触在至少一种过渡金属氧化物催化剂的存在下进行。
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5.发明申请公开(公告)号：US20060128555A1
公开(公告)日：2006-06-15
申请号：US11350156
申请日：2006-02-08
申请人： Zhiping Shan , Peter Wilhelm , Bowden Maingay , Philip Angevine , Jacobus Jansen , Chuen Yeh , Thomas Maschmeyer , Frits Dautzenberg , Leonardo Marchese , Heloise Oliveira Pastore
发明人： Zhiping Shan , Peter Wilhelm , Bowden Maingay , Philip Angevine , Jacobus Jansen , Chuen Yeh , Thomas Maschmeyer , Frits Dautzenberg , Leonardo Marchese , Heloise Oliveira Pastore
IPC分类号： B01J29/06
CPC分类号： C10G11/04 , B01J21/06 , B01J21/12 , B01J23/26 , B01J23/38 , B01J23/44 , B01J23/50 , B01J23/52 , B01J29/005 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/084 , B01J29/166 , B01J29/18 , B01J29/40 , B01J29/60 , B01J29/65 , B01J29/70 , B01J29/7007 , B01J29/80 , B01J29/85 , B01J29/87 , B01J29/88 , B01J29/89 , B01J35/002 , B01J35/1023 , B01J35/1028 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/108 , B01J37/0018 , B01J37/033 , B01J37/10 , B01J2229/183 , B01J2229/186 , B01J2229/32 , B01J2229/36 , B01J2229/42 , B01J2229/62 , C01B13/366 , C01B33/126 , C01B37/005 , C01B37/02 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C07C2/66 , C07C45/46 , C07D215/227 , C07D301/06 , C07D301/10 , C10G2/332 , C10G11/05 , C10G27/04 , C10G29/205 , C10G45/00 , C10G45/04 , C10G45/12 , C10G45/60 , C10G45/62 , C10G45/64 , C10G45/68 , C10G47/00 , C10G47/14 , C10G47/16 , C10G49/02 , C10G49/08 , C10G50/00 , C10G2300/1096 , C10G2300/301 , C10G2300/4018 , C10G2400/04 , C10G2400/10 , C10G2400/30 , C07C15/073 , C07C49/84
摘要： A catalytic material includes microporous zeolites supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite Beta, zeolite Y (including “ultra stable Y”—USY), mordenite, Zeolite L, ZSM-5, ZSM-11, ZSM-12, ZSM-20, Theta-1, ZSM-23, ZSM-34, ZSM-35, ZSM-48, SSZ-32, PSH-3, MCM-22, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-4, ITQ-21, SAPO-5, SAPO-11, SAPO-37, Breck-6, ALPO4-5, etc. The mesoporous inorganic oxide can be e.g., silica or silicate. The catalytic material can be further modified by introducing some metals e.g. aluminum, titanium, molybdenum, nickel, cobalt, iron, tungsten, palladium and platinum. It can be used as catalysts for acylation, alkylation, dimerization, oligomerization, polymerization, hydrogenation, dehydrogenation, aromatization, isomerization, hydrotreating, catalytic cracking and hydrocracking reactions.
摘要翻译： 催化材料包括负载在介孔无机氧化物载体上的微孔沸石。 微孔沸石可以包括沸石β，沸石Y（包括“超稳定Y”-USY），丝光沸石，沸石L，ZSM-5，ZSM-11，ZSM-12，ZSM-20，Theta-1，ZSM-23， ZSM-34，ZSM-35，ZSM-48，SSZ-32，PSH-3，MCM-22，MCM-49，MCM-56，ITQ-1，ITQ-2，ITQ-4，ITQ-21，SAPO- 5，SAPO-11，SAPO-37，Breck-6，ALPO 4 -5等。介孔无机氧化物可以是例如二氧化硅或硅酸盐。 催化材料可以通过引入一些金属进一步改性，例如 铝，钛，钼，镍，钴，铁，钨，钯和铂。 可用作酰化，烷基化，二聚，低聚，聚合，氢化，脱氢，芳构化，异构化，加氢处理，催化裂化和加氢裂化反应的催化剂。
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6.发明授权Method for the synthesis of organic acid esters of 5-hydroxymethylfurfural and their use 有权5-羟甲基糠醛有机酸酯的合成方法及其应用公开(公告)号：US08242293B2
公开(公告)日：2012-08-14
申请号：US12282288
申请日：2007-03-12
IPC分类号： C07D307/02 , C10L1/24
CPC分类号： C10L1/02 , C07D307/46 , C07D307/50 , Y02P20/127
摘要： Method for the manufacture of organic acid esters of 5-hydroxymethylfurfural by reacting a fructose or glucose-containing starting material with an organic acid or its anhydride in the presence of a catalytic or sub-stoechiometric amount of solid acid catalyst. The catalysts are heterogeneous and may be employed in a continuous flow fixed bed reactor. The esters can be applied as a fuel or fuel additive.
摘要翻译： 通过使含果糖或含葡萄糖的原料与有机酸或其酸酐在催化剂或亚微量的固体酸催化剂存在下反应制备5-羟甲基糠醛有机酸酯的方法。 催化剂是非均相的，可用于连续流动的固定床反应器中。 酯可以作为燃料或燃料添加剂使用。
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7.发明申请Method For The Synthesis Of Organic Acid Esters Of 5-Hydroxymethylfurfural And Their Use 有权用于合成5-羟甲基糠醛的有机酸酯及其用途的方法公开(公告)号：US20090306415A1
公开(公告)日：2009-12-10
申请号：US12282288
申请日：2007-03-12
IPC分类号： C07D307/54
CPC分类号： C10L1/02 , C07D307/46 , C07D307/50 , Y02P20/127
摘要： Method for the manufacture of organic acid esters of 5-hydroxymethylfurfural by reacting a fructose or glucose-containing starting material with an organic acid or its anhydride in the presence of a catalytic or sub-stoechiometric amount of solid acid catalyst. The catalysts are heterogeneous and may be employed in a continuous flow fixed bed reactor. The esters can be applied as a fuel or fuel additive.
摘要翻译： 通过使含果糖或含葡萄糖的原料与有机酸或其酸酐在催化剂或亚微量的固体酸催化剂存在下反应制备5-羟甲基糠醛有机酸酯的方法。 催化剂是非均相的，可用于连续流动的固定床反应器中。 酯可以作为燃料或燃料添加剂使用。
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公开(公告)号：US08314260B2
公开(公告)日：2012-11-20
申请号：US12517112
申请日：2008-09-05
申请人： Gerardus Johannes Maria Gruter , Leo Ernest Manzer , Ana Sofia Vagueiro De Sousa Dias , Frits Dautzenberg , Jindra Purmova
发明人： Gerardus Johannes Maria Gruter , Leo Ernest Manzer , Ana Sofia Vagueiro De Sousa Dias , Frits Dautzenberg , Jindra Purmova
IPC分类号： C07D307/02
CPC分类号： C07D307/46 , C10L1/1857
摘要： Accordingly, the current invention provides a method for the manufacture of an ether or ester of 5-hydroxymethyl-furfural by reacting a hexose-containing starting material or HMF with an alcohol or an organic acid dissolved into an ionic liquid, using a metal chloride as catalyst.
摘要翻译： 因此，本发明提供了通过使含己糖的起始物质或HMF与溶解在离子液体中的醇或有机酸反应，使用金属氯化物作为反应产生5-羟甲基 - 糠醛的醚或酯的方法 催化剂。
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9.发明授权公开(公告)号：US08133289B2
公开(公告)日：2012-03-13
申请号：US12282264
申请日：2007-03-12
IPC分类号： C07D307/48 , C10L1/185 , C07D307/02
CPC分类号： C07D307/46 , C10L1/02 , Y02P20/127
摘要： Method for the manufacture of 5-alkoxymethylfurfural derivatives by reacting a fructose and/or glucose-containing starting material with an alcohol in the presence of a catalytic or sub-stoechiometric amount of solid (“heterogeneous”) acid catalyst. The catalysts may be employed in a continuous flow fixed bed or catalytic distillation reactor. The ethers can be applied as a fuel or fuel additive.
摘要翻译： 通过在催化剂或亚微量的固体（“异质”）酸催化剂存在下使果糖和/或含葡萄糖的原料与醇反应制备5-烷氧基甲基糠醛衍生物的方法。 催化剂可用于连续流动固定床或催化蒸馏反应器中。 醚可以作为燃料或燃料添加剂使用。
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公开(公告)号：US20060278568A1
公开(公告)日：2006-12-14
申请号：US11147963
申请日：2005-06-08
CPC分类号： C10G25/00 , C07C2/62 , C07C7/12 , C07C2527/03 , C07C9/16
摘要： A process for the removal of oxygenated sulfur compounds from a hydrocarbon stream, especially the effluent from a sulfuric acid alkylation reactor, in which the hydrocarbon stream is first subjected to deentrainment of any carryover liquid sulfuric acid and then passed over a sorbent which removes the oxygenated sulfur compounds.
摘要翻译： 一种从烃流中除去含氧硫化合物的方法，特别是来自硫酸烷基化反应器的流出物，其中烃流首先进行任何残留液体硫酸的去除，然后通过吸附剂，除去含氧的 硫化合物。
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