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公开(公告)号：USH183H
公开(公告)日：1987-01-06
申请号：US766723
申请日：1985-08-19
摘要： Poly (p-xylylidenes) having a high degree of polymerization in the form of films, foams or highly molecularly oriented films and fibers are chemically modified from insulators to conducting materials by exposure to either p- or n-type dopants. Poly (p-xylylidene) films are cast from aqueous solutions of a poly (p-xylene-.alpha.-dimethylsulfonium salt) polyelectrolyte. Processing of the films at elevated temperatures can yield both fibers and foams. Exposure of the poly (p-xylylidene) films, fibers or foams to p-type dopants result in an up to fifteen order of magnitude increase in conductivity, while n-type coping yields a nine order of magnitude increase. Doping of molecularly oriented films and fibers yields a highly anisotropic conductor with a greatly improved conductivity in the orientation direction.
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公开(公告)号：US5328750A
公开(公告)日：1994-07-12
申请号：US812245
申请日：1991-12-19
CPC分类号： C23C18/1879 , C23C18/1612 , C23C18/1641 , C23C18/1882 , C23C18/2033 , C23C18/204 , C23C18/405 , H05K3/185 , Y10S428/901 , Y10S428/913 , Y10T428/24802 , Y10T428/24851 , Y10T428/24868 , Y10T428/24917 , Y10T428/24942 , Y10T428/31 , Y10T428/31935
摘要： Flexible printed circuits comprising copper circuitry electrolessly deposited on an activated ink coating prepared by heating a wet ink comprising a polymer, e.g. polyvinyl chloride or a butadiene polymer, and a Group 1B or 8 compound, e.g. palladium dichloride, which is adapted to drying at room temperature to a catalytically inert ink. Selective areas of the ink activated by application of heat or light, e.g. a laser, are catalytic to electroless deposition of copper.
摘要翻译： 柔性印刷电路，包括无电沉积在活性油墨涂层上的铜电路，其通过加热包含聚合物的湿油墨制备。 聚氯乙烯或丁二烯聚合物，以及1B或8族化合物，例如。 二氯化钯，其适于在室温下干燥至催化惰性油墨。 通过施加热或光而激活的油墨的选择区域，例如， 激光，对铜的无电沉积是催化剂。
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公开(公告)号：US4910072A
公开(公告)日：1990-03-20
申请号：US320914
申请日：1989-03-07
CPC分类号： C23C18/1879 , C23C18/1612 , C23C18/1641 , C23C18/1882 , C23C18/2033 , C23C18/204 , C23C18/405 , H05K3/185 , Y10S428/901 , Y10S428/913 , Y10T428/24802 , Y10T428/24851 , Y10T428/24868 , Y10T428/24917 , Y10T428/24942 , Y10T428/31 , Y10T428/31935
摘要： Catalytically inert films comprising complexes of polymer with a compound of a Group 1B or Group 8 metal at unusually low proportions of metal can be selectively activated, e.g. to provide a catalytic surface. Such films can be advantageously activatable to electroless deposition, e.g. of oxidation resistant layers of copper.
摘要翻译： 催化惰性薄膜包含聚合物与异常低比例金属的第1B族或第8族金属化合物的复合物，可选择性地活化，例如， 以提供催化表面。 这样的膜可以有利地可激活以进行无电沉积，例如。 的抗氧化层铜。
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公开(公告)号：US5437916A
公开(公告)日：1995-08-01
申请号：US272895
申请日：1994-07-08
CPC分类号： C23C18/1879 , C23C18/1612 , C23C18/1641 , C23C18/1882 , C23C18/2033 , C23C18/204 , C23C18/405 , H05K3/185 , Y10S428/901 , Y10S428/913 , Y10T428/24802 , Y10T428/24851 , Y10T428/24868 , Y10T428/24917 , Y10T428/24942 , Y10T428/31 , Y10T428/31935
摘要： Flexible printed circuits comprising cobalt circuitry electrolessly deposited on an activated ink coating prepared by heating a wet ink comprising a polymer, e.g. a vinyl polymer such as polyvinyl chloride or polyvinyl alcohol or an unsaturated polymer such as polybutadiene, and a Group 1B or 8 compound, e.g. palladium dichloride, which is adapted to drying at room temperature to a catalytically inert ink. Selective areas of the ink activated by application of heat or light are catalytic to electroless deposition of cobalt.
摘要翻译： 柔性印刷电路，包括无电沉积在通过加热包含聚合物的湿油墨制备的活化油墨涂层上的钴回路， 乙烯基聚合物如聚氯乙烯或聚乙烯醇或不饱和聚合物如聚丁二烯，以及1B或8族化合物，例如聚乙烯醇。 二氯化钯，其适于在室温下干燥至催化惰性油墨。 通过应用热或光活化的油墨的选择性区域催化钴的无电沉积。
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公开(公告)号：US5075037A
公开(公告)日：1991-12-24
申请号：US468509
申请日：1990-01-22
CPC分类号： C23C18/1879 , C23C18/1608 , C23C18/1612 , C23C18/1641 , C23C18/1865 , C23C18/1868 , C23C18/1882 , C23C18/2033 , C23C18/204 , C23C18/206 , C23C18/2066 , C23C18/28 , C23C18/30 , C23C18/405 , H05K3/185
摘要： Catalytically inert films comprising complexes of polymer with a compound of a Group 1B or Group 8 metal at unusually low proportions of metal can be selectively activated, e.g. to provide a catalytic surface. Such films can be advantageously activatable to electroless deposition, e.g. of oxidation resistant layers of copper.
摘要翻译： 催化惰性薄膜包含聚合物与异常低比例金属的第1B族或第8族金属化合物的复合物，可选择性地活化，例如， 以提供催化表面。 这样的膜可以有利地可激活以进行无电沉积，例如。 的抗氧化层铜。
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公开(公告)号：US4900618A
公开(公告)日：1990-02-13
申请号：US64898
申请日：1987-06-19
IPC分类号： C08F14/02 , C08F6/00 , C08K3/00 , C08L101/00 , C08L101/12 , C23C18/16 , C23C18/28 , C23C18/30 , H05K3/18
CPC分类号： C23C18/1879 , C23C18/1653 , C23C18/1865 , C23C18/1882 , C23C18/2033 , C23C18/2066 , C23C18/38 , H05K3/185 , Y10T428/12 , Y10T428/12424 , Y10T428/249978 , Y10T428/256 , Y10T428/264 , Y10T428/2927 , Y10T428/2944 , Y10T428/2958 , Y10T428/298 , Y10T428/31504 , Y10T428/31678
摘要： Oxidation-resistant, electrolessly deposited metal coatings, e.g. of copper, can be provided on a variety of substrates such as fibers and films. Precursor substrates have nascent or actual clusters of catalytic metal with dimensions less than 100 nanometers, e.g. about 10 nanometers. Disclosed methods can produce electrically conductive, copper-coated PET or acrylic multifilament with a resistance of less than 20 ohms/meter.
摘要翻译： 耐氧化，无电沉积金属涂层，例如 的铜可以设置在各种基材如纤维和薄膜上。 前体基材具有尺寸小于100纳米的催化金属的新生或实际簇，例如。 约10纳米。 公开的方法可以产生电阻小于20欧姆/米的导电铜涂层PET或丙烯酸复丝。
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