公开(公告)号：US10995400B2

公开(公告)日：2021-05-04

申请号：US13271828

申请日：2011-10-12

Applicant: Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Jason Barber

Inventor： Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Jason Barber

IPC: C23C14/00 ,  C23C14/35 ,  C23C14/34 ,  C23C14/06 ,  C23C14/08 ,  C03C17/34 ,  C03C17/245 ,  C03C17/27 ,  C23C14/58 ,  A01N59/16

Abstract: Techniques are provided for making a coated article including an antibacterial and/or antifungal coating. In certain example embodiments, the method includes providing a first sputtering target including Zr; providing a second sputtering target including Zn; and co-sputtering from at least the first and second sputtering targets in the presence of nitrogen to form a layer including ZnxZryNz on a glass substrate. These layers may be heat-treated or thermally tempered to form a single layer including ZnxZryOz. In other examples, two discrete layers of Zn and Zr may be formed. The coating may be heated or tempered to form a single layer including ZnxZryOz. Coated articles made using these methods may have antibacterial and/or antifungal properties.

公开(公告)号：US08354178B2

公开(公告)日：2013-01-15

申请号：US12923775

申请日：2010-10-07

Applicant: Nestor P. Murphy ,  Maximo Frati ,  Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Jens-Peter Muller ,  Herbert Lage

Inventor： Nestor P. Murphy ,  Maximo Frati ,  Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Jens-Peter Muller ,  Herbert Lage

IPC: B32B15/04

CPC classification number: C03C17/3441 ,  C03B27/012 ,  C03C17/3423 ,  C03C23/007 ,  C03C2217/78 ,  C03C2217/91 ,  C03C2218/322 ,  C03C2218/328 ,  C03C2218/355

Abstract: There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include an oxide of zinc. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.

Abstract translation: 提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。 例如，本发明的某些实施方案涉及一种制备涂覆制品的方法，包括对涂覆有至少一层或类金刚石碳（DLC）的玻璃基板和其上覆盖的保护膜进行热处理的步骤。 在某些示例性实施方案中，保护膜可以是或包括锌的氧化物。 继续和/或在热处理（例如热回火等）期间，可以去除保护膜。 本发明的其它实施方案涉及预HT涂覆制品或后HT涂覆制品。

公开(公告)号：US07833574B2

公开(公告)日：2010-11-16

申请号：US11699080

申请日：2007-01-29

Applicant: Nestor P. Murphy ,  Maximo Frati ,  Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Jens-Peter Muller ,  Herbert Lage

Inventor： Nestor P. Murphy ,  Maximo Frati ,  Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Jens-Peter Muller ,  Herbert Lage

IPC: C23C16/26 ,  C23C16/40

CPC classification number: C03C17/3441 ,  C03B27/012 ,  C03C17/3423 ,  C03C23/007 ,  C03C2217/78 ,  C03C2217/91 ,  C03C2218/322 ,  C03C2218/328 ,  C03C2218/355

Abstract: A method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include an oxide of zinc. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.

Abstract translation: 制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。 例如，本发明的某些实施方案涉及一种制备涂覆制品的方法，包括对涂覆有至少一层或类金刚石碳（DLC）的玻璃基板和其上覆盖的保护膜进行热处理的步骤。 在某些示例性实施方案中，保护膜可以是或包括锌的氧化物。 继续和/或在热处理（例如热回火等）期间，可以去除保护膜。 本发明的其它实施方案涉及预HT涂覆制品或后HT涂覆制品。

公开(公告)号：US20130142994A1

公开(公告)日：2013-06-06

申请号：US13312347

申请日：2011-12-06

Applicant: Jiangping WANG ,  Rudolph H. PETRMICHL ,  Tiong P. ONG

Inventor： Jiangping WANG ,  Rudolph H. PETRMICHL ,  Tiong P. ONG

IPC: B32B33/00 ,  B05D5/00 ,  C23C16/44 ,  B05D3/10 ,  B05D3/06 ,  C23C16/48 ,  B05D3/00 ,  C03C17/00

CPC classification number: B05D5/02 ,  B05D3/06 ,  B05D3/10 ,  B05D3/12 ,  C03C15/00 ,  C03C17/09 ,  C03C17/10 ,  C03C17/22 ,  C03C17/225 ,  C03C17/2456 ,  C03C17/256 ,  C03C2204/08 ,  C03C2217/212 ,  C03C2217/213 ,  C03C2217/258 ,  C03C2217/28 ,  C03C2217/281 ,  C03C2217/75 ,  C03C2217/76 ,  C03C2217/77 ,  Y10T428/24355

Abstract: Certain example embodiments of this invention relate to coated articles including anti-fingerprint and/or smudge-reducing coatings, and/or methods of making the same. Oil from fingerprints and the like may easily transfer to the surface of an article. However, it has been found that in certain example embodiments, a reduced-smudge and reduced-glare effect on a glass substrate may be achieved by micro-engineering a glass surface's properties, such as surface morphology and/or roughness. In certain example embodiments, a thin film coating may be introduced to the glass surface in order to alter the contact angle of the article, or for other optical, electrical, mechanical, chemical and/or environmental purposes and/or durability. It has further advantageously been found that by altering the contact angle of the surface, the anti-smudge and anti-glare effects of the substrate may be further improved.

Abstract translation: 本发明的某些示例性实施方案涉及包括抗指纹和/或防污涂层的涂层制品，和/或其制备方法。 来自指纹等的油可能容易地转移到物品的表面。 然而，已经发现，在某些示例性实施例中，可以通过微观化玻璃表面的表面性质（例如表面形态和/或粗糙度）来实现对玻璃基板的降低和减少的眩光效果。 在某些示例性实施例中，可以将薄膜涂层引入玻璃表面，以便改变制品的接触角，或用于其它光学，电学，机械，化学和/或环境目的和/或耐用性。 进一步有利地发现，通过改变表面的接触角，可以进一步提高基材的防污和防眩光效果。

公开(公告)号：US20120137734A1

公开(公告)日：2012-06-07

申请号：US13369337

申请日：2012-02-09

Applicant: Rudolph Hugo PETRMICHL ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

Inventor： Rudolph Hugo PETRMICHL ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

IPC: C03C17/22 ,  C03B27/012

CPC classification number: C03C17/3435 ,  C03C17/3423 ,  C03C17/3441 ,  C03C23/007 ,  C03C2217/78 ,  C03C2217/91 ,  C03C2218/322 ,  C03C2218/328 ,  C03C2218/355

Abstract: There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.

Abstract translation: 提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。 例如，本发明的某些实施方案涉及一种制备涂覆制品的方法，包括对涂覆有至少一层或类金刚石碳（DLC）的玻璃基板和其上覆盖的保护膜进行热处理的步骤。 在某些示例性实施方案中，保护膜可以由（a）氧阻挡层或阻挡层或（b）释放层构成或包括两者。 继续和/或在热处理（例如热回火等）期间，可以去除保护膜。 本发明的其它实施方案涉及预HT涂覆制品或后HT涂覆制品。

公开(公告)号：US08071166B2

公开(公告)日：2011-12-06

申请号：US12230551

申请日：2008-08-29

Applicant: Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

Inventor： Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

IPC: C23C16/26 ,  B05D5/00 ,  B05D3/02 ,  B32B33/00

CPC classification number: C03C17/3441 ,  C03C17/22 ,  C03C2217/282 ,  C03C2217/78 ,  C03C2217/91 ,  C03C2218/328 ,  C03C2218/33 ,  C03C2218/355 ,  Y10T428/30

Abstract: There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.

Abstract translation: 提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。 例如，本发明的某些实施方案涉及一种制备涂覆制品的方法，包括对涂覆有至少一层或类金刚石碳（DLC）的玻璃基板和其上覆盖的保护膜进行热处理的步骤。 在某些示例性实施方案中，保护膜可以由（a）氧阻挡层或阻挡层或（b）释放层构成或包括两者。 继续和/或在热处理（例如热回火等）期间，可以去除保护膜。 本发明的其它实施方案涉及预HT涂覆制品或后HT涂覆制品。

公开(公告)号：US20110027471A1

公开(公告)日：2011-02-03

申请号：US12923778

申请日：2010-10-07

Applicant: Nestor P. Murphy ,  Maximo Frati ,  Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Jens-Peter Muller ,  Herbert Lage

Inventor： Nestor P. Murphy ,  Maximo Frati ,  Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Jens-Peter Muller ,  Herbert Lage

IPC: B05D3/02 ,  C23C14/34

CPC classification number: C03C17/3441 ,  C03B27/012 ,  C03C17/3423 ,  C03C23/007 ,  C03C2217/78 ,  C03C2217/91 ,  C03C2218/322 ,  C03C2218/328 ,  C03C2218/355

Abstract: There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include an oxide of zinc. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.

Abstract translation: 提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。 例如，本发明的某些实施方案涉及一种制备涂覆制品的方法，包括对涂覆有至少一层或类金刚石碳（DLC）的玻璃基板和其上覆盖的保护膜进行热处理的步骤。 在某些示例性实施方案中，保护膜可以是或包括锌的氧化物。 继续和/或在热处理（例如热回火等）期间，可以去除保护膜。 本发明的其它实施方案涉及预HT涂覆制品或后HT涂覆制品。

公开(公告)号：US07645487B2

公开(公告)日：2010-01-12

申请号：US11489729

申请日：2006-07-20

Applicant: Rudolph Hugo Petrmichl ,  Douglas Klimesh ,  Jiangping Wang

Inventor： Rudolph Hugo Petrmichl ,  Douglas Klimesh ,  Jiangping Wang

IPC: B32B17/06 ,  B05D3/00

CPC classification number: C03C17/3417 ,  C03C17/245 ,  C03C17/27 ,  C03C17/3435 ,  C03C17/3441 ,  C03C17/3488 ,  C03C2217/216 ,  C03C2217/22 ,  C03C2217/23 ,  C03C2218/154 ,  C03C2218/322 ,  C03C2218/355 ,  C23C14/0635 ,  C23C14/0641 ,  C23C14/067 ,  C23C14/0676 ,  C23C14/08 ,  C23C14/5806 ,  C23C14/5853 ,  Y10T428/31678

Abstract: In certain example embodiments, a coated article includes a Zn-doped zirconium based layer before heat treatment (HT). The coated article is heat treated sufficiently to cause the Zn-doped zirconium based layer to transform into a Zn-doped zirconium oxide based layer that is scratch resistant and/or chemically durable. The doping of the layer with Zn has been found to improve scratch resistance and/or corrosion resistance.

Abstract translation: 在某些示例性实施方案中，涂覆制品在热处理（HT）之前包括掺Zn的锆基层。 涂覆的制品被充分热处理以使Zn掺杂的锆基层转变成耐划伤和/或化学耐久的掺Zn的氧化锆基层。 已经发现用Zn掺杂层改善耐刮擦性和/或耐腐蚀性。

公开(公告)号：US20080182032A1

公开(公告)日：2008-07-31

申请号：US11806674

申请日：2007-06-01

Applicant: Alexey Krasnov ,  Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

Inventor： Alexey Krasnov ,  Rudolph Hugo Petrmichl ,  Jiangping Wang ,  Nestor P. Murphy ,  Maximo Frati ,  Jose Nunez-Regueiro

IPC: C23C14/00 ,  B05D3/02

CPC classification number: C03C17/3441 ,  C03C23/007 ,  C03C2217/78 ,  C03C2218/322 ,  C03C2218/328 ,  C03C2218/355

Abstract: There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. The method may include heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) or other type of carbon, with a protective film thereon. In certain example embodiments, the protective film may be of or include a layer of or including SnOx prior to HT. Optionally, a release layer of a material such as zinc oxide may be provided between the SnOx and the DLC. Following and/or during heat treatment the SnOx transforms into SnOy (y>x) so that stress is created due to the SnOx to SnOy transition. Then, during quenching, stress relief may occur which causes the layer to buckle, creating cracks which may act as liquid channels that permit the sacrificial film to be easily removed via washing or the like.

Abstract translation: 提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。 该方法可以包括用至少一层或类金刚石碳（DLC）或其他类型的碳涂覆的玻璃基板与其上的保护膜进行热处理。 在某些示例性实施方案中，保护膜可以是或包含HT之前的或包括SnO x的层。 任选地，可以在SnO x和DLC之间提供诸如氧化锌的材料的剥离层。 在热处理之后和/或在热处理期间，SnO x x x转换成SnO y（y> x），使得由于SnO x x（x） 到SnO y y转换。 然后，在淬火期间，可能发生应力消除，这导致该层弯曲，产生可能作为允许通过洗涤等容易地除去牺牲膜的液体通道的裂纹。

公开(公告)号：US20120015195A1

公开(公告)日：2012-01-19

申请号：US13174282

申请日：2011-06-30

Applicant: Jiangping WANG ,  Jens-Peter Muller ,  Rudolph Hugo Petrmichl ,  Jean-Marc Lemmer

Inventor： Jiangping WANG ,  Jens-Peter Muller ,  Rudolph Hugo Petrmichl ,  Jean-Marc Lemmer

IPC: B32B17/06 ,  C03C17/34 ,  C03C15/00

CPC classification number: C03C17/22 ,  C03C15/00 ,  C03C17/27 ,  C03C17/3441 ,  C03C2217/22 ,  C03C2217/282 ,  C03C2217/77 ,  C03C2217/78 ,  C03C2217/91 ,  C03C2218/15 ,  C03C2218/31 ,  C03C2218/322 ,  C03C2218/328 ,  C03C2218/33 ,  C03C2218/355 ,  C03C2218/36

Abstract: There is provided a method of making a heat treated (HT) coated article to be used in shower door applications, window applications, or any other suitable applications where transparent coated articles are desired. For example, certain embodiments of this invention relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least a layer of or including diamond-like carbon (DLC) and an overlying protective film thereon. In certain example embodiments, the protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer. Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.

Abstract translation: 提供了一种制造用于淋浴门应用，窗户应用或需要透明涂层制品的任何其它合适应用的热处理（HT）涂覆制品的方法。 例如，本发明的某些实施方案涉及一种制备涂覆制品的方法，包括对涂覆有至少一层或类金刚石碳（DLC）的玻璃基板和其上覆盖的保护膜进行热处理的步骤。 在某些示例性实施方案中，保护膜可以由（a）氧阻挡层或阻挡层或（b）释放层构成或包括两者。 继续和/或在热处理（例如热回火等）期间，可以去除保护膜。 本发明的其它实施方案涉及预HT涂覆制品或后HT涂覆制品。