REMOVABLE ADHESIVE COMPOSITION, REMOVABLE ADHESIVE LAYER, ADHESIVE SHEET, AND SURFACE PROTECTIVE MATERIAL
    1.
    发明申请
    REMOVABLE ADHESIVE COMPOSITION, REMOVABLE ADHESIVE LAYER, ADHESIVE SHEET, AND SURFACE PROTECTIVE MATERIAL 有权
    可拆卸胶粘组合物,可拆卸粘合剂层,粘合片和表面保护材料

    公开(公告)号:US20090022925A1

    公开(公告)日:2009-01-22

    申请号:US11816900

    申请日:2006-02-06

    IPC分类号: B32B33/00 C08L33/02

    摘要: Provided is a re-peeling pressure-sensitive adhesive composition for a surface protecting material for an adherend having a photocatalytic layer, comprising: a (meth)acryl-based polymer including, as monomer units, 50 to 99.9% by weight of (A) at least one acrylate-based monomer represented by the general formula (1): CH2═CR1COOR2 wherein R1 represents a hydrogen atom or a methyl group, and R2 represents an alkyl group having 2 to 14 carbon atoms, 0.1 to 10% by weight of (B) a functional-group-containing vinyl-based monomer, and 0 to 49.9% by weight of (C) a vinyl-based monomer copolymerizable with the component (A) and/or the component (B); and (D) a surfactant having a molecular weight of 150 to 5000, the amount of the component (D) being from 0.01 to 30 parts by weight with respect to 100 parts by weight of the (meth)acryl-based polymer. The re-peeling pressure-sensitive adhesive composition is excellent in re-peeling property, contact-angle-recoverability, and weather resistance.

    摘要翻译: 本发明提供一种用于具有光催化层的被粘物的表面保护材料的再剥离用压敏粘合剂组合物,其包含:(甲基)丙烯酸类聚合物,其包含作为单体单元的(A)50-99.9重量% 至少一种由通式(1)表示的丙烯酸酯类单体:CH2-CR1COOR2,其中R1表示氢原子或甲基,R2表示碳原子数2〜14的烷基,0.1〜10重量% (B)含官能团的乙烯基类单体和0〜49.9重量%的(C)可与组分(A)和/或组分(B)共聚的乙烯基类单体; 和(D)分子量为150〜5000的表面活性剂,相对于(甲基)丙烯酸系聚合物100重量份,成分(D)的含量为0.01〜30重量份。 再剥离压敏粘合剂组合物的再剥离性,接触角恢复性和耐候性优异。

    PRESSURE-SENSITIVE ADHESIVE TAPE
    3.
    发明申请
    PRESSURE-SENSITIVE ADHESIVE TAPE 审中-公开
    压敏胶带

    公开(公告)号:US20110244227A1

    公开(公告)日:2011-10-06

    申请号:US13025379

    申请日:2011-02-11

    IPC分类号: B32B7/12 B29C47/06

    摘要: Provided is the following novel pressure-sensitive adhesive tape that expresses a sufficiently strong adhesion for an adherend. The adhesion of the novel pressure-sensitive adhesive tape in its production process is controlled so as to be moderately weak. Accordingly, a peeling failure and the occurrence of a wrinkle are sufficiently suppressed, and hence stable product supply is performed. The pressure-sensitive adhesive tape of the present invention includes at least three layers including: a base material layer (A); a first pressure-sensitive adhesive layer (B1); and a second pressure-sensitive adhesive layer (B2) in the stated order, in which: the base material layer (A) contains a thermoplastic resin; each of the first pressure-sensitive adhesive layer (B1) and the second pressure-sensitive adhesive layer (B2) contains a tackifier; a ratio R1/R2 of a content (R1) of the tackifier in the first pressure-sensitive adhesive layer (B1) to a content (R2) of the tackifier in the second pressure-sensitive adhesive layer (B2) is 0.90 to 1.10; and the content of the tackifier in the second pressure-sensitive adhesive layer (B2) is 5 wt % or more.

    摘要翻译: 提供了对于被粘物表现出足够强的粘附性的以下新型压敏粘合带。 新型压敏粘合带在其生产过程中的粘合力被控制为适度弱。 因此,能够充分抑制剥离破坏和褶皱的发生,从而进行稳定的产品供给。 本发明的压敏粘合带包括至少三层,包括:基材层(A); 第一压敏粘合剂层(B1); 和第二压敏粘合剂层(B2),其中:基材层(A)含有热塑性树脂; 第一压敏粘合剂层(B1)和第二压敏粘合剂层(B2)中的每一个含有增粘剂; 第一粘合剂层(B1)中的增粘剂的含量(R1)与第二粘合剂层(B2)中的增粘剂的含量(R2)的比率R1 / R2为0.90〜1.10; 并且第二压敏粘合剂层(B2)中的增粘剂的含量为5重量%以上。

    LAMINATED FILM AND PRESSURE-SENSITIVE ADHESIVE TAPE

    公开(公告)号:US20110033662A1

    公开(公告)日:2011-02-10

    申请号:US12836347

    申请日:2010-07-14

    IPC分类号: B32B3/10

    摘要: Provided are a laminated film and a pressure-sensitive adhesive tape each of which is adjusted so as to be capable of achieving compatibility between low haze property excellent in transparency and such large surface roughness that foreign matter such as a fish eye is hardly observed without fluctuations in mechanical properties of the entire laminated film or pressure-sensitive adhesive tape. Also provided is such a pressure-sensitive adhesive tape as described below capable of protecting the uneven surface of a member having unevenness on its surface. The pressure-sensitive adhesive tape brings together sufficient pressure-sensitive adhesiveness for, and sufficient releasability from, the member. In addition, even upon deformation of the member protected with the pressure-sensitive adhesive tape by, for example, lamination or continuous winding, the uneven shape does not deform and a base material layer in the pressure-sensitive adhesive tape is not damaged, and further, the pressure-sensitive adhesive tape is adjusted so as to be capable of achieving compatibility between low haze property excellent in transparency and such large surface roughness that foreign matter such as a fish eye is hardly observed without fluctuations in mechanical properties of the entire pressure-sensitive adhesive tape. Also provided is such a pressure-sensitive adhesive tape as described below. When a prism sheet having multiple triangle pole-shaped prisms fixed on its surface is used as the above-mentioned member having unevenness on its surface, the pressure-sensitive adhesive tape functions as a surface protective film capable of effectively protecting a lens surface, and brings together sufficient pressure-sensitive adhesiveness for, and sufficient releasability from, the prism sheet. In addition, when the prism sheet protected with the pressure-sensitive adhesive tape is brought into a state such as a laminated state or a continuously wound state, the emergence of irregularity (indentation) in the external appearance of the prism sheet to which the pressure-sensitive adhesive tape is attached can be suppressed. A laminated film of the present invention is a laminated film including a base material layer, a roughness-expressing layer, and a fine unevenness-erasing layer in the stated order, in which: the base material layer contains a thermoplastic resin; the roughness-expressing layer contains at least one kind of a resin component (A) selected from polyethylenes, ethylene-vinyl acetate copolymers, propylene-based polymers, and olefin-based thermoplastic elastomers; the fine unevenness-erasing layer contains a thermoplastic resin (B); an arithmetic average surface roughness Ra on the surface on the side of the fine unevenness-erasing layer is 1.0 μm to 3.0 μm; and the haze value of the laminated film is 30% or less.

    Method of inflation extrusion molding, extrusion molding apparatus therefor, and process for producing pressure-sensitive adhesive sheet
    5.
    发明申请
    Method of inflation extrusion molding, extrusion molding apparatus therefor, and process for producing pressure-sensitive adhesive sheet 失效
    膨胀挤出成型方法,挤压成型装置以及压敏粘合片的制造方法

    公开(公告)号:US20050056973A1

    公开(公告)日:2005-03-17

    申请号:US10942139

    申请日:2004-09-16

    摘要: The invention provides a method of inflation extrusion molding, comprising: introducing one or more resin materials extruded from one or more extruders into a die; subsequently extruding the resin material(s) from the die and inflating the extrudate into a cylindrical shape having a predetermined diameter by blown-film extrusion; and then passing the cylindrical inflated resin material through a space between stabilizers which face each other at a predetermined angle, to deform the cylindrical resin material into a flat tube shape having an elongated elliptic section, thereby producing a film or sheet having a predetermined width, wherein the deformation of the cylindrical inflated resin material into a flat tube shape having an elongated elliptic section is assisted by a guide device to thereby facilitate the deformation.

    摘要翻译: 本发明提供了一种膨胀挤压成型方法,包括:将从一个或多个挤出机挤出的一种或多种树脂材料引入模头; 随后从模具中挤出树脂材料,并通过吹膜挤出将挤出物膨胀成具有预定直径的圆柱形; 然后使圆筒状膨胀树脂材料通过预定角度彼此相对的稳定器之间的空间,使圆筒形树脂材料变形为具有细长椭圆形截面的扁平管状,从而制造具有预定宽度的薄膜或片材, 其中圆柱形膨胀树脂材料变形为具有细长椭圆形截面的扁平管状,由导向装置辅助,从而有助于变形。

    Apparatus and method for inflation extrusion molding of pressure-sensitive adhesive sheet
    6.
    发明授权
    Apparatus and method for inflation extrusion molding of pressure-sensitive adhesive sheet 有权
    用于压敏粘合片的吹塑挤出成型的装置和方法

    公开(公告)号:US08226398B2

    公开(公告)日:2012-07-24

    申请号:US13296591

    申请日:2011-11-15

    IPC分类号: A01J21/00

    摘要: The present invention provides an apparatus for inflation extrusion molding of pressure-sensitive adhesive sheet, including: one or a plurality of extruders; a die into which one or a plurality of resin materials are respectively introduced and which extrudes from an ejection opening the resin materials into an inflated cylindrical shape having a predetermined diameter in accordance with an inflation method; and two stabilizers facing each other at a predetermined angle so as to upwardly approach each other, and defining a space therebetween through which the cylindrically-shaped resin materials extruded from the die are passed to be deformed into a pressure-sensitive adhesive sheet in a flattened elliptical shape having a predetermined width, in which the stabilizers each have a plurality of air floating portions each of which blows air toward the resin materials; and the stabilizers rotate in one direction around the central axis of the cylindrically-shaped resin materials.

    摘要翻译: 本发明提供一种用于压敏粘合片的吹塑挤出成型的装置,包括:一个或多个挤出机; 分别引入一个或多个树脂材料的模具,并且根据膨胀方法将树脂材料从喷射口挤出成具有预定直径的膨胀圆筒形状的模具; 两个稳定器以预定的角度彼此面对,以便彼此向上接近,并且在其间限定了从模具挤出的圆柱形树脂材料通过的空间,以变形成压平粘合片 具有预定宽度的椭圆形状,其中稳定器具有多个空气浮动部分,每个空气浮动部分朝向树脂材料吹送空气; 并且稳定剂围绕圆柱形树脂材料的中心轴线在一个方向上旋转。

    Removable adhesive composition, removable adhesive layer, adhesive sheet, and surface protective material
    7.
    发明授权
    Removable adhesive composition, removable adhesive layer, adhesive sheet, and surface protective material 有权
    可拆卸的粘合剂组合物,可去除的粘合剂层,粘合片和表面保护材料

    公开(公告)号:US07968189B2

    公开(公告)日:2011-06-28

    申请号:US11816900

    申请日:2006-02-06

    IPC分类号: B32B27/30 B32B33/00 C08L33/02

    摘要: Provided is a re-peeling pressure-sensitive adhesive composition for a surface protecting material for an adherend having a photocatalytic layer, comprising: a (meth)acryl-based polymer including, as monomer units, 50 to 99.9% by weight of (A) at least one acrylate-based monomer represented by the general formula (1): CH2═CR1COOR2 wherein R1 represents a hydrogen atom or a methyl group, and R2 represents an alkyl group having 2 to 14 carbon atoms, 0.1 to 10% by weight of (B) a functional-group-containing vinyl-based monomer, and 0 to 49.9% by weight of (C) a vinyl-based monomer copolymerizable with the component (A) and/or the component (B); and (D) a surfactant having a molecular weight of 150 to 5000, the amount of the component (D) being from 0.01 to 30 parts by weight with respect to 100 parts by weight of the (meth)acryl-based polymer. The re-peeling pressure-sensitive adhesive composition is excellent in re-peeling property, contact-angle-recoverability, and weather resistance.

    摘要翻译: 本发明提供一种用于具有光催化层的被粘物的表面保护材料的再剥离用压敏粘合剂组合物,其包含:(甲基)丙烯酸类聚合物,其包含作为单体单元的(A)50-99.9重量% 至少一种由通式(1)表示的丙烯酸酯类单体:CH2 = CR1COOR2,其中R1表示氢原子或甲基,R2表示碳原子数2〜14的烷基,0.1〜10重量% (B)含官能团的乙烯基类单体和0〜49.9重量%的(C)可与组分(A)和/或组分(B)共聚的乙烯基类单体; 和(D)分子量为150〜5000的表面活性剂,相对于(甲基)丙烯酸系聚合物100重量份,成分(D)的含量为0.01〜30重量份。 再剥离压敏粘合剂组合物的再剥离性,接触角恢复性和耐候性优异。

    PRESSURE-SENSITIVE ADHESIVE TAPE
    8.
    发明申请

    公开(公告)号:US20110033699A1

    公开(公告)日:2011-02-10

    申请号:US12836337

    申请日:2010-07-14

    IPC分类号: C09J7/02

    摘要: Provided is such a pressure-sensitive adhesive tape as described below, which is capable of protecting the uneven surface of a member having unevenness on its surface. The pressure-sensitive adhesive tape brings together sufficient pressure-sensitive adhesiveness for, and sufficient releasability from, the member. In addition, even upon deformation of the member protected with the pressure-sensitive adhesive tape by, for example, lamination or continuous winding, the uneven shape does not deform and a base material layer in the pressure-sensitive adhesive tape is not damaged. Also provided is a pressure-sensitive adhesive tape useful as such a surface protective film for a prism sheet as described below, which is capable of effectively protecting, for example, a lens surface of a prism sheet having multiple triangle pole-shaped prisms fixed on its surface. The surface protective film brings together sufficient pressure-sensitive adhesiveness for, and sufficient releasability from, the prism sheet. In addition, when the prism sheet protected with the surface protective film is brought into a state such as a laminated state or a continuously wound state, the emergence of irregularity (indentation) in the external appearance of the prism sheet to which the surface protective film is attached can be suppressed. A pressure-sensitive adhesive tape of the present invention is a pressure-sensitive adhesive tape including a base material layer, a first pressure-sensitive adhesive layer, and a second pressure-sensitive adhesive layer in the stated order, in which: the base material layer contains a thermoplastic resin; the storage modulus of the first pressure-sensitive adhesive layer is higher than the storage modulus of the second pressure-sensitive adhesive layer; and a difference between the storage modulus of the first pressure-sensitive adhesive layer at a frequency of 10 Hz and 23° C., and the storage modulus of the second pressure-sensitive adhesive layer at a frequency of 10 Hz and 23° C. is 3×105 Pa or more.

    PRESSURE-SENSITIVE ADHESIVE TAPE
    10.
    发明申请
    PRESSURE-SENSITIVE ADHESIVE TAPE 审中-公开
    压敏胶带

    公开(公告)号:US20110287253A1

    公开(公告)日:2011-11-24

    申请号:US13072983

    申请日:2011-03-28

    IPC分类号: C09J7/02 B32B27/32

    摘要: Provided is the following novel pressure-sensitive adhesive tape. The pressure-sensitive adhesive tape has a moderately weak adhesion during a time period from a production process (during its production) to the time of the accomplishment of the product as a result of the completion of the production (immediately after the production). Accordingly, the occurrence of a peeling trace, the occurrence of a peeling sound, and the like resulting from strong adherence of a pressure-sensitive adhesive layer to a roll or the like at the time of the production can be sufficiently suppressed. As a result, stable product supply can be performed. On the other hand, the pressure-sensitive adhesive tape can express a sufficiently strong adhesion for an adherend after a lapse of a predetermined time from the production (e.g., at the time of its use). The pressure-sensitive adhesive tape includes at least three layers including: a base material layer (A); a first pressure-sensitive adhesive layer (B1); and a second pressure-sensitive adhesive layer (B2) in the stated order, in which: the base material layer (A) contains a thermoplastic resin; the first pressure-sensitive adhesive layer (B1) contains a tackifier at a content of 12 wt % or more; the second pressure-sensitive adhesive layer (B2) contains a tackifier at a content of 10 wt % or less; and the adhesive strength of the pressure-sensitive adhesive tape immediately after the production for a stainless plate measured in conformity with JIS Z 0237 (2000) is 0.7 N/20 mm or less.

    摘要翻译: 提供以下新型压敏粘合带。 在生产过程(生产期间)到生产完成(生产之后)完成产品的时间段期间,压敏粘合带具有适度弱的粘附性。 因此,能够充分地抑制在制造时粘合剂层对辊等的强粘附而产生的剥离痕迹,剥离声等的发生。 因此,可以实现稳定的产品供应。 另一方面,压敏粘合带在从生产(例如在使用时)经过预定时间之后,可以对被粘物表现出足够强的粘合性。 所述压敏粘合带包括至少三层,包括:基材层(A); 第一压敏粘合剂层(B1); 和第二压敏粘合剂层(B2),其中:基材层(A)含有热塑性树脂; 第一粘合剂层(B1)含有12重量%以上的增粘剂, 第二压敏粘合剂层(B2)含有10重量%以下的增粘剂, 并且根据JIS Z 0237(2000)测定的不锈钢板的制造之后的压敏粘合带的粘合强度为0.7N / 20mm以下。