Water-blown rigid foams with improved mechanical properties at low temperatures
    1.
    发明授权
    Water-blown rigid foams with improved mechanical properties at low temperatures 有权
    水冷刚性泡沫在低温下具有改善的机械性能

    公开(公告)号:US08940803B2

    公开(公告)日:2015-01-27

    申请号:US13139138

    申请日:2009-12-03

    摘要: The present invention relates to a rigid polyurethane foam which can be obtained by mixing (a) isocyanates, (b) compounds having groups which are reactive toward isocyanates, (c) blowing agents comprising water, (d) catalysts and optionally (e) further additives to form a reaction mixture, applying the reaction mixture to a reinforcing material and curing the reaction mixture, where the isocyanates (a) have a viscosity of not more than 500 mPas at 25° C. and the compounds (b) having groups which are reactive toward isocyanates comprise a polyetherol (b1) having a functionality of 4 or more and a viscosity at 25° C. of 10 000 mPas or less, a polyetherol (b2) having a functionality of 3.5 or less and a viscosity at 25° C. of 600 mPas or less, a polyesterol (b3) having a viscosity at 25° C. of 2000 mPas or less, chain extenders (b4) comprising at least 30% secondary OH groups and optionally a crosslinker (b5). The present invention further relates to a process for producing such rigid polyurethane foams and the use of the rigid polyurethane foams for the insulation of liquefied natural gas tanks.

    摘要翻译: 本发明涉及一种硬质聚氨酯泡沫塑料,其可通过混合(a)异氰酸酯,(b)具有对异氰酸酯具有反应性的基团的化合物,(c)包含水的发泡剂,(d)催化剂和任选(e) 添加剂以形成反应混合物,将反应混合物施加到增强材料上并固化反应混合物,其中异氰酸酯(a)在25℃下的粘度不超过500mPas,并且化合物(b)具有 对异氰酸酯反应的物质包含官能度为4以上,25℃下的粘度为10000mPa·s以下的聚醚类(b1),官能度为3.5以下,25℃时的粘度的聚醚类(b2) 600mPa·s以下的聚酯醇(b3),其在25℃下的粘度为2000mPa·s以下,含有至少30%的仲羟基和任选的交联剂(b5)的增链剂(b4)。 本发明还涉及一种用于生产这种硬质聚氨酯泡沫体的方法,以及使用硬质聚氨酯泡沫塑料用于液化天然气罐的绝缘。

    CORE FOAMS OF POLYURETHANE FOR PRODUCTION OF WINGS AND BLADES FOR WIND POWER SYSTEMS IN PARTICULAR
    6.
    发明申请
    CORE FOAMS OF POLYURETHANE FOR PRODUCTION OF WINGS AND BLADES FOR WIND POWER SYSTEMS IN PARTICULAR 审中-公开
    用于生产特定风力发电系统的翅片和叶片的聚氨酯的核心技术

    公开(公告)号:US20120142801A1

    公开(公告)日:2012-06-07

    申请号:US13307543

    申请日:2011-11-30

    IPC分类号: C08J9/00 C08L75/04

    摘要: A reinforced polyurethane foam obtained by (1) mixing polyisocyanates (a) with compounds having isocyanate-reactive groups (b), a blowing agent containing water (c), and optionally a catalyst (d) and further additives (e) to form a reaction mixture, and (2) curing the reaction mixture, where the reaction mixture to be cured contains hollow microspheres and/or is applied to a porous reinforcing agent (f) capable of forming two-dimensional or three-dimensional networks in the polyurethane foam. The compounds having isocyanate-reactive groups (b) include polyetherols (b1), polyesterols (b2), chain extenders (b3) and optionally crosslinkers (b4) and aromatic polyether diols (b5), and the sum of (b2), (b3) and (b5) is at least 50% by weight of component (b). A process for producing such reinforced polyurethane foams and their use as reinforcing foams for load-bearing, stiff areal elements, in the interior of wings or blades, and also as insulation material for liquefied natural gas tanks.

    摘要翻译: 一种增强聚氨酯泡沫体,其通过(1)将多异氰酸酯(a)与具有异氰酸酯反应性基团的化合物(b),含水(c)的发泡剂和任选的催化剂(d)和另外的添加剂(e))混合而形成 反应混合物,和(2)固化反应混合物,其中待固化的反应混合物包含中空微球,和/或施加到能够在聚氨酯泡沫中形成二维或三维网络的多孔增强剂(f) 。 具有异氰酸酯反应性基团(b)的化合物包括聚醚醚(b1),聚酯醇(b2),扩链剂(b3)和任选的交联剂(b4)和芳族聚醚二醇(b5),和(b2),(b3) )和(b5)为组分(b)的至少50重量%。 用于生产这种增强的聚氨酯泡沫的方法以及它们作为用于承载,刚性面层元件的增强泡沫在翼或叶片的内部以及用作液化天然气罐的绝缘材料中的用途。