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1.发明申请Use of Methanol in the Production of Hydrogen and Fuel, Processes and Plants for the Production of Hydrogen and Fuel 审中-公开在生产氢气和燃料中使用甲醇，生产氢和燃料的方法和工艺公开(公告)号：US20100317905A1
公开(公告)日：2010-12-16
申请号：US12742213
申请日：2008-10-29
申请人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
发明人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
CPC分类号： C01B3/323 , C01B3/382 , C01B3/48 , C01B3/52 , C01B13/0248 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/0415 , C01B2203/043 , C01B2203/0465 , C01B2203/048 , C01B2203/049 , C01B2203/1223 , C01B2210/0046 , C02F1/00 , C02F3/00 , C02F2101/34 , C02F2103/023 , C02F2103/16 , C02F2103/28 , C02F2103/365 , C10G2/30 , C10G2/32 , C10G3/00 , C10G3/50 , C10G45/58 , C10G2300/1003 , C10G2300/1011 , C10J3/00 , C10J2300/0916 , C10J2300/0959 , C10J2300/16 , C10J2300/1659 , C10J2300/1678 , C10J2300/169 , C10K1/101 , C10K3/04 , C10L1/04 , C10L2200/0469 , C10L2290/42 , C10L2290/54 , D21C11/0007 , D21C11/06 , Y02E20/16 , Y02E20/18 , Y02E50/32 , Y02P20/145 , Y02P30/20
摘要： The invention relates to the use of biomethanol from the pulp industry in the production of biohydrogen. The preferred biomethanol comprises purified biomethanol derived from black liquor. The invention also relates to a process for the production of biohydrogen from crude biomethanol recovered from black liquor and to a process for producing hydrocarbon biofuel using such biohydrogen as a hydrogen source. The invention further relates to a biofuel production facility for producing fuel from biohydrogen and biohydrocarbon, and to biofuel so produced. The invention makes it possible to produce a biofuel, wherein 100% of the raw material stems from non-fossil sources.
摘要翻译： 本发明涉及来自纸浆工业的生物甲醇在生物氢生产中的应用。 优选的生物甲醇包含来自黑液的纯化生物甲醇。 本发明还涉及从从黑液中回收的粗生物甲醇生产生物氢的方法，以及使用这种生物氢作为氢源生产烃生物燃料的方法。 本发明还涉及用于从生物氢和生物烃生产燃料的生物燃料生产设备以及如此生产的生物燃料。 本发明使得可以生产生物燃料，其中100％的原料源自非化石源。
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2.发明申请公开(公告)号：US20110203277A1
公开(公告)日：2011-08-25
申请号：US13126789
申请日：2009-10-30
申请人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
发明人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
CPC分类号： C10K3/04 , C10G2/30 , C10J3/482 , C10J2300/0906 , C10J2300/0909 , C10J2300/0916 , C10J2300/092 , C10J2300/0946 , C10J2300/0959 , C10J2300/0976 , C10J2300/1659 , C10J2300/1675 , C10K1/004 , C10K1/024 , C10K1/08 , C10K1/165 , C10K3/023 , C10L1/06 , C10L1/08 , Y02E50/13 , Y02E50/32 , Y02P20/124 , Y02P20/145
摘要： The invention relates to producing liquid hydro carbonaceous product (1) from solid biomass (2). In the invention solid biomass (2) is gasified in a gasifier (6) to produce raw synthesis gas (3). The raw synthesis gas (3) is conditioned to purify the raw synthesis gas (3) to obtain purified synthesis gas (4), the conditioning comprising lowering the temperature of the raw synthesis gas (3) in a cooler (19) producing saturated steam (51). Then the purified gas (4) is subjected to a Fischer-Tropsch synthesis in a Fischer-Tropsch reactor (5) to produce liquid hydro carbonaceous product (1). In the invention the saturated steam (51) produced by the cooler (19) is further superheated in a superheating boiler (50) for producing superheated steam (52).
摘要翻译： 本发明涉及从固体生物质（2）生产液体含碳产物（1）。 在本发明中，固体生物质（2）在气化器（6）中气化以产生原始合成气（3）。 对原料合成气（3）进行调节以净化原料合成气（3）以获得纯化的合成气（4），该调理包括降低生产饱和蒸汽的冷却器（19）中的原料合成气（3）的温度 （51）。 然后，将经纯化的气体（4）在费 - 托反应器（5）中进行费 - 托合成以制备液体含碳产物（1）。 在本发明中，由冷却器（19）产生的饱和蒸汽（51）在用于制造过热蒸汽（52）的过热锅炉（50）中进一步过热。
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公开(公告)号：US20100305220A1
公开(公告)日：2010-12-02
申请号：US12669769
申请日：2008-07-18
申请人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
发明人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
CPC分类号： C01B3/48 , B01D53/526 , B01D53/8618 , B01D2252/2026 , B01D2252/204 , B01D2253/1124 , B01D2255/20792 , B01D2257/304 , B01D2257/504 , C01B3/38 , C01B3/52 , C01B2203/0233 , C01B2203/0283 , C01B2203/0415 , C01B2203/0475 , C01B2203/1235 , C10G2/32 , C10G2300/1011 , C10G2300/202 , C10G2300/4081 , C10G2300/44 , C10G2300/807 , C10J3/503 , C10J3/721 , C10J3/84 , C10J2300/0903 , C10J2300/0916 , C10J2300/0959 , C10J2300/0973 , C10J2300/1618 , C10J2300/1659 , C10J2300/1807 , C10J2300/1838 , C10J2300/1884 , C10K1/002 , C10K1/005 , C10K1/006 , C10K1/101 , C10K1/143 , C10K3/023 , C10K3/04 , Y02E50/32 , Y02P20/145 , Y02P20/152 , Y02P30/20
摘要： The invention relates to a method and apparatus for producing liquid hydro carbonaceous product (1) such as biofuel from solid biomass (2). The method comprises a gasifying step for gasifying solid biomass (2) in a gasifier (6) to produce raw synthesis gas (3), conditioning of the raw synthesis gas (3) to purify the raw synthesis gas (3) to obtain purified synthesis gas (4) having a molar ratio of hydrogen to carbon monoxide between 2.5 to 1 and 0.5 to 1, preferably to between 2.1 to 1 and 1.8 to 1, more preferably about 2 to 1, and subjecting purified synthesis gas (4) to a Fischer-Tropsch synthesis in a Fischer-Tropsch reactor (5) to produce liquid hydro carbonaceous product (1).
摘要翻译： 本发明涉及一种用于生产液体含碳物质（1）如固体生物质（2）的生物燃料的方法和装置。 该方法包括在气化器（6）中气化固体生物质（2）以产生原料合成气（3）的气化步骤，原料合成气（3）的调理以净化原料合成气（3）以获得纯化合成 将氢与一氧化碳的摩尔比在2.5至1和0.5至1之间，优选为2.1至1至1.8至1，更优选约2至1的气体（4）和将纯化的合成气（4） 费 - 托反应器（5）中的费 - 托合成，生产液态含碳产物（1）。
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4.发明授权公开(公告)号：US09434615B2
公开(公告)日：2016-09-06
申请号：US12669769
申请日：2008-07-18
申请人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
发明人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
IPC分类号： B01J8/18 , C07C27/00 , C01B3/48 , C01B3/38 , C01B3/52 , C10G2/00 , C10J3/50 , C10J3/72 , C10J3/84 , C10K1/00 , C10K1/10 , C10K1/14 , C10K3/04 , C10K3/02
CPC分类号： C01B3/48 , B01D53/526 , B01D53/8618 , B01D2252/2026 , B01D2252/204 , B01D2253/1124 , B01D2255/20792 , B01D2257/304 , B01D2257/504 , C01B3/38 , C01B3/52 , C01B2203/0233 , C01B2203/0283 , C01B2203/0415 , C01B2203/0475 , C01B2203/1235 , C10G2/32 , C10G2300/1011 , C10G2300/202 , C10G2300/4081 , C10G2300/44 , C10G2300/807 , C10J3/503 , C10J3/721 , C10J3/84 , C10J2300/0903 , C10J2300/0916 , C10J2300/0959 , C10J2300/0973 , C10J2300/1618 , C10J2300/1659 , C10J2300/1807 , C10J2300/1838 , C10J2300/1884 , C10K1/002 , C10K1/005 , C10K1/006 , C10K1/101 , C10K1/143 , C10K3/023 , C10K3/04 , Y02E50/32 , Y02P20/145 , Y02P20/152 , Y02P30/20
摘要： The invention relates to a method and apparatus for producing liquid hydro carbonaceous product (1) such as biofuel from solid biomass (2). The method comprises a gasifying step for gasifying solid biomass (2) in a gasifier (6) to produce raw synthesis gas (3), conditioning of the raw synthesis gas (3) to purify the raw synthesis gas (3) to obtain purified synthesis gas (4) having a molar ratio of hydrogen to carbon monoxide between 2.5 to 1 and 0.5 to 1, preferably to between 2.1 to 1 and 1.8 to 1, more preferably about 2 to 1, and subjecting purified synthesis gas (4) to a Fischer-Tropsch synthesis in a Fischer-Tropsch reactor (5) to produce liquid hydro carbonaceous product (1).
摘要翻译： 本发明涉及一种用于生产液体含碳物质（1）如固体生物质（2）的生物燃料的方法和装置。 该方法包括在气化器（6）中气化固体生物质（2）以产生原料合成气（3）的气化步骤，原料合成气（3）的调理以净化原料合成气（3）以获得纯化合成 将氢与一氧化碳的摩尔比在2.5至1和0.5至1之间，优选为2.1至1至1.8至1，更优选约2至1的气体（4）和将纯化的合成气（4） 费 - 托反应器（5）中的费 - 托合成，生产液态含碳产物（1）。
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公开(公告)号：US09133027B2
公开(公告)日：2015-09-15
申请号：US12669764
申请日：2008-07-18
申请人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
发明人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
IPC分类号： C01B3/24 , C01B3/52 , C01B3/38 , C01B3/48 , C10G2/00 , C10J3/00 , C10J3/50 , C10J3/52 , C10J3/84
CPC分类号： C01B3/52 , C01B3/38 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/0415 , C01B2203/0475 , C01B2203/1241 , C10G2/30 , C10G2/32 , C10G2300/1011 , C10J3/00 , C10J3/50 , C10J3/52 , C10J3/84 , C10J2200/15 , C10J2300/0916 , C10J2300/0969 , C10J2300/1659 , C10J2300/1693 , C10J2300/1807 , Y02E20/18 , Y02E50/32 , Y02P20/145 , Y02P30/20 , Y02W10/40
摘要： The invention relates to a method and apparatus for producing synthesis gas (7) from biomass (2). The method comprises a step for producing raw product gas (3), and a purifying step comprising several processing steps performed in gas processing means (10, 12, 13, 14) for converting the raw product gas (3) to synthesis gas (7). One processing step is a carbon dioxide removal step for separating carbon dioxide from the stream of raw product gas (3) in a gas processing means comprising a gas purificator (10). The method comprises a step for feeding a stream of the carbon dioxide (9) from the gas purificator (10) to at least one part of the apparatus, said at least one part of the apparatus being selected from: the biomass supply system (4), the gasifier (6) and at least one of the gas processing means (10, 12, 13, 14).
摘要翻译： 本发明涉及从生物质（2）生产合成气（7）的方法和装置。 该方法包括生产原料气体（3）的步骤，以及净化步骤，包括在用于将原料气体（3）转化为合成气（7）的气体处理装置（10,12,13,14）中进行的几个处理步骤 ）。 一个处理步骤是用于在包括气体净化器（10）的气体处理装置中从原料气体（3）流中分离二氧化碳的二氧化碳去除步骤。 该方法包括将来自气体净化器（10）的二氧化碳流（9）进料到设备的至少一部分的步骤，所述设备的至少一部分选自：生物质供应系统（4） ），气化器（6）和气体处理装置（10,12,13,14）中的至少一个。
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6.发明授权公开(公告)号：US09024095B2
公开(公告)日：2015-05-05
申请号：US13203832
申请日：2010-02-26
申请人： Pekka Knuuttila , Petri Kukkonen , Ulf Hotanen
发明人： Pekka Knuuttila , Petri Kukkonen , Ulf Hotanen
CPC分类号： C10G3/46 , C10G3/50 , C10G3/60 , C10G45/00 , C10G45/58 , C10G65/14 , C10G69/02 , C10G2300/1011 , C10G2300/1014 , C10G2300/1022 , C10G2300/1048 , C10G2300/201 , C10G2300/805 , C10G2400/04 , Y02P30/20
摘要： A method for preparing fuel components from crude tall oil. Feedstock containing tall oil including unsaturated fatty acids is introduced to a catalytic hydrodeoxygenation to convert unsaturated fatty acids, rosin acids and sterols to fuel components. Crude tall oil is purified in a purification by washing the crude tall oil with washing liquid and separating the purified crude tall oil from the washing liquid. The purified crude tall oil is introduced directly to the catalytic hydrodeoxygenation as a purified crude tall oil feedstock. An additional feedstock may be supplied to the catalytic hydrodeoxygenation.
摘要翻译： 一种由粗妥尔油制备燃料成分的方法。 将含有不饱和脂肪酸的妥尔油的原料引入催化加氢脱氧以将不饱和脂肪酸，松香酸和固醇转化成燃料组分。 通过用洗涤液洗涤粗妥尔油并将纯化的粗妥尔油与洗涤液分离，在纯化中纯化粗妥尔油。 纯化的粗妥尔油直接引入催化加氢脱氧作为纯化的原始妥尔油原料。 可以向催化加氢脱氧提供另外的原料。
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7.发明申请Waste Water Treatment From A Biomass-To-Liquid Process Comprising Synthesis Gas Production and Integrated Factory Facility 有权包括合成气生产和综合工厂设施的生物质 - 液体过程的废水处理公开(公告)号：US20100317749A1
公开(公告)日：2010-12-16
申请号：US12742229
申请日：2008-07-18
申请人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
发明人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
CPC分类号： C01B3/323 , C01B3/382 , C01B3/48 , C01B3/52 , C01B13/0248 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/0415 , C01B2203/043 , C01B2203/0465 , C01B2203/048 , C01B2203/049 , C01B2203/1223 , C01B2210/0046 , C02F1/00 , C02F3/00 , C02F2101/34 , C02F2103/023 , C02F2103/16 , C02F2103/28 , C02F2103/365 , C10G2/30 , C10G2/32 , C10G3/00 , C10G3/50 , C10G45/58 , C10G2300/1003 , C10G2300/1011 , C10J3/00 , C10J2300/0916 , C10J2300/0959 , C10J2300/16 , C10J2300/1659 , C10J2300/1678 , C10J2300/169 , C10K1/101 , C10K3/04 , C10L1/04 , C10L2200/0469 , C10L2290/42 , C10L2290/54 , D21C11/0007 , D21C11/06 , Y02E20/16 , Y02E20/18 , Y02E50/32 , Y02P20/145 , Y02P30/20
摘要： Treatment of waste water from a biomass-to-liquid process, said process comprising producing synthesis gas from biomass and conversion of said synthesis gas into liquid hydrocarbons by a Fisher-Tropsch process. The waste waters obtained are purified in common with waste waters from another industrial process to which said biomass-to- liquid process is integrated, such as in forestry, power and/or heat generation, waste incineration or a process in a metal-, petrochemical and/or oil refining industry. The biomass-to-liquid. process and said another industrial process may have a common feed water process unit, a common cooling water process unit and a common waste water treatment unit. The waste water treatment process may comprise a biological purification process and said Fischer-Tropsch process may utilize a cobalt catalyst. An integrated factory comprising a biomass-to-liquid plant and another industrial facility in which both plants are connected to a common waste water treatment facility is also described.
摘要翻译： 从生物质到液体方法处理废水，所述方法包括从生物质产生合成气并通过费 - 托法将所述合成气转化成液态烃。 所获得的废水与来自另一个工业过程的废水同样地被净化，所述生物质 - 液化过程被整合到其中，例如在林业，动力和/或发热，废物焚化或金属，石油化工 和/或炼油工业。 生物质到液体。 并且所述另一工业过程可以具有共同的给水处理单元，普通的冷却水处理单元和普通的废水处理单元。 废水处理方法可以包括生物净化方法，并且所述费 - 托法可以使用钴催化剂。 还描述了一个综合工厂，其中包括一个生物质液化设备和另一个工厂，其中两个工厂连接到一个普通的废水处理设施。
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8.发明授权Waste water treatment from a biomass-to-liquid process comprising synthesis gas production and integrated factory facility 有权从生物质到液体方法的废水处理，包括合成气生产和综合工厂设施公开(公告)号：US08591737B2
公开(公告)日：2013-11-26
申请号：US12742229
申请日：2008-07-18
申请人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
发明人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
CPC分类号： C01B3/323 , C01B3/382 , C01B3/48 , C01B3/52 , C01B13/0248 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/0415 , C01B2203/043 , C01B2203/0465 , C01B2203/048 , C01B2203/049 , C01B2203/1223 , C01B2210/0046 , C02F1/00 , C02F3/00 , C02F2101/34 , C02F2103/023 , C02F2103/16 , C02F2103/28 , C02F2103/365 , C10G2/30 , C10G2/32 , C10G3/00 , C10G3/50 , C10G45/58 , C10G2300/1003 , C10G2300/1011 , C10J3/00 , C10J2300/0916 , C10J2300/0959 , C10J2300/16 , C10J2300/1659 , C10J2300/1678 , C10J2300/169 , C10K1/101 , C10K3/04 , C10L1/04 , C10L2200/0469 , C10L2290/42 , C10L2290/54 , D21C11/0007 , D21C11/06 , Y02E20/16 , Y02E20/18 , Y02E50/32 , Y02P20/145 , Y02P30/20
摘要： Treatment of waste water from a biomass-to-liquid process, said process comprising producing synthesis gas from biomass and conversion of said synthesis gas into liquid hydrocarbons by a Fisher-Tropsch process. The waste waters obtained are purified in common with waste waters from another industrial process to which said biomass-to-liquid process is integrated, such as in forestry, power and/or heat generation, waste incineration or a process in a metal-, petrochemical and/or oil refining industry. The biomass-to-liquid. process and said another industrial process may have a common feed water process unit, a common cooling water process unit and a common waste water treatment unit. The waste water treatment process may comprise a biological purification process and said Fischer-Tropsch process may utilize a cobalt catalyst. An integrated factory comprising a biomass-to-liquid plant and another industrial facility in which both plants are connected to a common waste water treatment facility is also described.
摘要翻译： 从生物质到液体方法处理废水，所述方法包括从生物质产生合成气并通过费 - 托法将所述合成气转化成液态烃。 所获得的废水与来自另一个工业过程的废水同样地被纯化，其中所述生物质与液体过程被整合到其中，例如在林业，动力和/或发热，废物焚烧或金属，石油化工 和/或炼油工业。 生物质到液体。 并且所述另一工业过程可以具有共同的给水处理单元，普通的冷却水处理单元和普通的废水处理单元。 废水处理方法可以包括生物净化方法，并且所述费 - 托法可以使用钴催化剂。 还描述了一个综合工厂，其中包括一个生物质液化设备和另一个工厂，其中两个工厂连接到一个普通的废水处理设施。
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公开(公告)号：US20120088943A1
公开(公告)日：2012-04-12
申请号：US13203832
申请日：2010-02-26
申请人： Pekka Knuuttila , Petri Kukkonen , Ulf Hotanen
发明人： Pekka Knuuttila , Petri Kukkonen , Ulf Hotanen
CPC分类号： C10G3/46 , C10G3/50 , C10G3/60 , C10G45/00 , C10G45/58 , C10G65/14 , C10G69/02 , C10G2300/1011 , C10G2300/1014 , C10G2300/1022 , C10G2300/1048 , C10G2300/201 , C10G2300/805 , C10G2400/04 , Y02P30/20
摘要： A method for preparing fuel components from crude tall oil. Feedstock containing tall oil including unsaturated fatty acids is introduced to a catalytic hydrodeoxygenation to convert unsaturated fatty acids, rosin acids and sterols to fuel components. Crude tall oil is purified in a purification by washing the crude tall oil with washing liquid and separating the purified crude tall oil from the washing liquid. The purified crude tall oil is introduced directly to the catalytic hydrodeoxygenation as a purified crude tall oil feedstock. An additional feedstock may be supplied to the catalytic hydrodeoxygenation.
摘要翻译： 一种由粗妥尔油制备燃料成分的方法。 将含有不饱和脂肪酸的妥尔油的原料引入催化加氢脱氧以将不饱和脂肪酸，松香酸和固醇转化成燃料组分。 通过用洗涤液洗涤粗妥尔油并将纯化的粗妥尔油与洗涤液分离，在纯化中纯化粗妥尔油。 纯化的粗妥尔油直接引入催化加氢脱氧作为纯化的原始妥尔油原料。 可以向催化加氢脱氧提供另外的原料。
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公开(公告)号：US20100280137A1
公开(公告)日：2010-11-04
申请号：US12669764
申请日：2008-07-18
申请人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
发明人： Petri Kukkonen , Pekka Knuuttila , Pekka Jokela
CPC分类号： C01B3/52 , C01B3/38 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/0415 , C01B2203/0475 , C01B2203/1241 , C10G2/30 , C10G2/32 , C10G2300/1011 , C10J3/00 , C10J3/50 , C10J3/52 , C10J3/84 , C10J2200/15 , C10J2300/0916 , C10J2300/0969 , C10J2300/1659 , C10J2300/1693 , C10J2300/1807 , Y02E20/18 , Y02E50/32 , Y02P20/145 , Y02P30/20 , Y02W10/40
摘要： The invention relates to a method and apparatus for producing synthesis gas (7) from biomass (2). The method comprises a step for producing raw product gas (3), and a purifying step comprising several processing steps performed in gas processing means (10, 12, 13, 14) for converting the raw product gas (3) to synthesis gas (7). One processing step is a carbon dioxide removal step for separating carbon dioxide from the stream of raw product gas (3) in a gas processing means comprising a gas purificator (10). The method comprises a step for feeding a stream of the carbon dioxide (9) from the gas purificator (10) to at least one part of the apparatus, said at least one part of the apparatus being selected from: the biomass supply system (4), the gasifier (6) and at least one of the gas processing means (10, 12, 13, 14).
摘要翻译： 本发明涉及从生物质（2）生产合成气（7）的方法和装置。 该方法包括生产原料气体（3）的步骤，以及净化步骤，包括在用于将原料气体（3）转化为合成气（7）的气体处理装置（10,12,13,14）中进行的几个处理步骤 ）。 一个处理步骤是用于在包括气体净化器（10）的气体处理装置中从原料气体（3）流中分离二氧化碳的二氧化碳去除步骤。 该方法包括将来自气体净化器（10）的二氧化碳流（9）进料到设备的至少一部分的步骤，所述设备的至少一部分选自：生物质供应系统（4） ），气化器（6）和气体处理装置（10,12,13,14）中的至少一个。
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