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    Solutions and Catalysts Comprising Group VI Metal, Group VIII Metal, Phosphorus and An Additive
    1.
    发明申请
    Solutions and Catalysts Comprising Group VI Metal, Group VIII Metal, Phosphorus and An Additive 有权
    包括VI族金属，VIII族金属，磷和添加剂的溶液和催化剂

    公开(公告)号：US20120145600A1

    公开(公告)日：2012-06-14

    申请号：US13391336

    申请日：2010-08-24

    Applicant: Sona Eijsbouts-Spickova ,  Marcel Adriaan Jansen

    Inventor： Sona Eijsbouts-Spickova ,  Marcel Adriaan Jansen

    IPC: C10G45/04 ,  B01J31/02 ,  B01J31/06 ,  B01J27/19 ,  B01J27/188 ,  B01J37/02 ,  B01J37/08 ,  C10G45/00 ,  B01J31/04

    CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J23/88 ,  B01J23/888 ,  B01J27/1853 ,  B01J37/0203 ,  B01J37/0213 ,  B01J37/0236 ,  B01J37/08 ,  C10G45/00 ,  C10G45/08 ,  C10G49/04

    Abstract: This invention provides a process for forming a solution composition, which process comprises forming a primary solution by bringing together, in an aqueous medium, i) at least one phosphorus compound, ii) at least one Group VI metal compound, iii) at least one Group VIII metal compound, and iv) an additive which is a) tetraethylene glycol, b) polyethylene glycol having an average molecular weight in the range of about 200 to about 400, c) a mixture of tetraethylene glycol and polyethylene glycol having an average molecular weight in the range of about 200 to about 400, or d) a mixture of (1) tetraethylene glycol and/or polyethylene glycol having an average molecular weight in the range of about 200 to about 400 and (2) one or more of monoethylene glycol, diethylene glycol, and triethylene glycol. The molar ratio of additive to the total moles of Group VI metal and Group VIII metal is above 0.30:1, and the atomic ratio of phosphorus to Group VI metal is at least about 0.33:1. Optionally, the primary solution is heated at a temperature above about 40° C. to form a heated solution. The heated solution is optionally cooled to form a cooled solution. Also provided are compositions formed by such processes, processes for forming catalyst compositions from these compositions, and catalyst compositions formed by these processes.

    Abstract translation: 本发明提供一种形成溶液组合物的方法，该方法包括通过在水性介质中混合形成初级溶液，i）至少一种磷化合物，ii）至少一种VI族金属化合物，iii）至少一种 VIII族金属化合物，和iv）a）四乙二醇，b）平均分子量在约200至约400范围内的聚乙二醇的添加剂，c）四甘醇和聚乙二醇的混合物，其平均分子量 重量在约200至约400的范围内，或d）平均分子量在约200至约400范围内的（1）四甘醇和/或聚乙二醇的混合物，和（2）一种或多种单乙烯 乙二醇，二甘醇和三甘醇。 VI族金属和VIII族金属的添加剂与总摩尔数的摩尔比大于0.30:1，磷与Ⅵ族金属的原子比为至少约0.33:1。 任选地，将主溶液在高于约40℃的温度下加热以形成加热溶液。 加热的溶液任选地冷却以形成冷却的溶液。 还提供了通过这些方法形成的组合物，由这些组合物形成催化剂组合物的方法，以及由这些方法形成的催化剂组合物。

    Solutions and catalysts comprising group VI metal, group VIII metal, phosphorus and an additive
    2.
    发明授权
    Solutions and catalysts comprising group VI metal, group VIII metal, phosphorus and an additive 有权
    包含VI族金属，VIII族金属，磷和添加剂的溶液和催化剂

    公开(公告)号：US09254478B2

    公开(公告)日：2016-02-09

    申请号：US13391336

    申请日：2010-08-24

    Applicant: Sona Eijsbouts-Spickova ,  Marcel Adriaan Jansen

    Inventor： Sona Eijsbouts-Spickova ,  Marcel Adriaan Jansen

    IPC: B01J31/06 ,  B01J27/185 ,  B01J27/19 ,  B01J23/888 ,  B01J21/04 ,  B01J23/88 ,  B01J37/02 ,  B01J37/08 ,  C10G49/04 ,  B01J27/186

    CPC classification number: B01J27/19 ,  B01J21/04 ,  B01J23/88 ,  B01J23/888 ,  B01J27/1853 ,  B01J37/0203 ,  B01J37/0213 ,  B01J37/0236 ,  B01J37/08 ,  C10G45/00 ,  C10G45/08 ,  C10G49/04

    Abstract: This invention provides a process for forming a solution composition, which process comprises forming a primary solution by bringing together, in an aqueous medium, i) at least one phosphorus compound, ii) at least one Group VI metal compound, iii) at least one Group VIII metal compound, and iv) an additive which is a) tetraethylene glycol, b) polyethylene glycol having an average molecular weight in the range of about 200 to about 400, c) a mixture of tetraethylene glycol and polyethylene glycol having an average molecular weight in the range of about 200 to about 400, or d) a mixture of (1) tetraethylene glycol and/or polyethylene glycol having an average molecular weight in the range of about 200 to about 400 and (2) one or more of monoethylene glycol, diethylene glycol, and triethylene glycol. The molar ratio of additive to the total moles of Group VI metal and Group VIII metal is above 0.30:1, and the atomic ratio of phosphorus to Group VI metal is at least about 0.33:1. Optionally, the primary solution is heated at a temperature above about 40° C. to form a heated solution. The heated solution is optionally cooled to form a cooled solution. Also provided are compositions formed by such processes, processes for forming catalyst compositions from these compositions, and catalyst compositions formed by these processes.

    Abstract translation: 本发明提供一种形成溶液组合物的方法，该方法包括通过在水性介质中混合形成初级溶液，i）至少一种磷化合物，ii）至少一种VI族金属化合物，iii）至少一种 VIII族金属化合物，和iv）a）四乙二醇，b）平均分子量在约200至约400范围内的聚乙二醇的添加剂，c）四甘醇和聚乙二醇的混合物，其平均分子量 重量在约200至约400的范围内，或d）平均分子量在约200至约400范围内的（1）四甘醇和/或聚乙二醇的混合物，和（2）一种或多种单乙烯 乙二醇，二甘醇和三甘醇。 VI族金属和VIII族金属的添加剂与总摩尔数的摩尔比大于0.30:1，磷与Ⅵ族金属的原子比为至少约0.33:1。 任选地，将主溶液在高于约40℃的温度下加热以形成加热溶液。 加热的溶液任选地冷却以形成冷却的溶液。 还提供了通过这些方法形成的组合物，由这些组合物形成催化剂组合物的方法，以及由这些方法形成的催化剂组合物。

    Process for sulfiding a hydrotreating catalyst comprising an organic compound comprising n and carbonyl
    8.
    发明授权
    Process for sulfiding a hydrotreating catalyst comprising an organic compound comprising n and carbonyl 有权
    硫化含有n和羰基的有机化合物的加氢处理催化剂的方法

    公开(公告)号：US06540908B1

    公开(公告)日：2003-04-01

    申请号：US09540402

    申请日：2000-03-31

    Applicant: Sonja Eijsbouts ,  Marcel Adriaan Jansen

    Inventor： Sonja Eijsbouts ,  Marcel Adriaan Jansen

    IPC: C10G4504

    CPC classification number: B01J31/1616 ,  B01J31/0215 ,  B01J31/0254 ,  B01J31/04 ,  B01J31/1805 ,  B01J31/2226 ,  B01J37/0203 ,  B01J37/20 ,  B01J2531/64 ,  B01J2531/847 ,  C10G45/08 ,  Y10S502/509 ,  Y10S502/51 ,  Y10S502/511

    Abstract: The invention pertains to a process for preparing a sulfided hydrotreating catalyst in which a hydrotreating catalyst is subjected to a sulfidation step, wherein the hydrotreating catalyst comprises a carrier comprising at least 50 wt % of alumina, the catalyst comprising at least one hydrogenation metal component and an organic compound comprising at least one covalently bonded nitrogen atom and at least one carbonyl moiety, the molar ratio between the organic compound and the total hydrogenation metal content being at least 0.01:1. The invention further pertains to the use of said hydrotreating catalyst in hydrotreating a hydrocarbon feed, in particular to achieve hydrodenitrogenation, (deep) hydrodesulfurization, or hydrodearomatization.

    Abstract translation: 本发明涉及一种制备硫化加氢处理催化剂的方法，其中加氢处理催化剂经受硫化步骤，其中加氢处理催化剂包含载体，该载体包含至少50wt％的氧化铝，该催化剂包含至少一种氢化金属组分和 包含至少一个共价键合的氮原子和至少一个羰基部分的有机化合物，有机化合物与总加氢金属含量之间的摩尔比为至少0.01:1。 本发明还涉及所述加氢处理催化剂在加氢处理烃进料中的用途，特别是实现加氢脱氮，（深）加氢脱硫或加氢脱芳构化。

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