摘要:
A heat resistant resin bonded grindstone is prepared by heating under pressure a molded composition comprising 20 to 50 vol. % of a polyimide resin powder, 50 to 70 vol. % of a metal powder, and 10 to 30 vol. % of a diamond powder, so that the diamond powder can be dispersed in and supported by a binder phase comprising the polyimide resin powder and the metal powder, in which the polyimide resin powder has been produced from a diamine compound comprising p-phenylenediamine and a mixture of 85 to 97 mol. % of 3,3′,4,4′-biphenyltetracarboxylic acid or its dianhydride and 15 to 3 mol. % of 2,3,3′,4′-biphenyltetracarboxylic acid or its dianhydride.
摘要:
A polyimide/metal composite sheet is composed of a metal film and a polyimide film polyimide which is prepared by reaction of asymmetric biphenyltetracarboxylic acid dianhydride and 1,3-bis(4-aminophenoxy)benzene. The polyimide film is firmly bonded to and hardly peelable from the metal film. The polyimide film can contain a solid filler.
摘要:
A resin composition comprising;100 parts by weight of a mixture comprising (a) from 5 to 95% by weight of polyamide and (b) from 95 to 5% by weight of a thermoplastic polyester; and(c) from 0.5 part to 40 parts by weight of a grafted polyolefin modified product formed by graft polymerization of an addition polymer having a peroxy bond in its molecular chain to a modified polyolefin having a functional group in its molecular chain; and a molded product thereof.
摘要:
A crystalline terpolymer polyamide produced from: (a) an equimolar salt of hexamethylenediamine with adipic acid, (b) an equimolar salt of hexamethylenediamine with terephthalic acid, and (c) 12-aminododecanoic acid or .omega.-laurolactam; a polyamide resin composition comprising (A) the terpolymer polyamide and (B) a modified polyolefin; a polyamide resin composition comprising (A) the terpolymer polyamide, (B) the modified polyolefin, and (C) polyamide 12; a polyamide resin composition comprising (A) the terpolymer polyamide and (D) an inorganic filler and/or a flame retardant; and an automotive part comprising a molding one of these terpolymer polyamide and polyamide resin compositions.
摘要:
A process for production of polyimide molded bodies which comprises a step in which a polyimide resin powder obtained by polymerization and imidation of p-phenylenediamine with 3,3′,4,4′-biphenyltetracarboxylic acid, its ester or its dianhydride and 2,3,3′,4′-biphenyltetracarboxylic acid, its ester or its dianhydride is molded at a pressure of approximately 3,000-5,000 kgf/cm2, and a step in which it is calcined at about 460-550° C. under low pressure. The polyimide molded bodies obtained thereby have a density in the range of 1.28-1.34 g/cm3.
摘要:
A continuous polymerization method for laurolactam which has three stages. A prepolymerization process include steps of preliminarily heating laurolactam with 1 to 10% weight of water added, thereafter continuously feeding and passing the laurolactam from the upper part of the lower part of the longitudinal-type polymerization reaction zone, arranging a temperature decreasing gradient of 10.degree. C. or more than the upper part to the lower part directions at a polymerization temperature of 250.degree. and 300.degree. C. in the polymerization zone, and polymerizing the laurolactam under vapor pressure up to a conversion rate of 99.5% or more. A intermediate process has a step of releasing pressure from the prepolymerization product from the prepolymerization process for conversion into an intermediate product at atmospheric pressure. A post polymerization process includes the steps of continuously feeding the intermediate product at atmospheric pressure from the intermediate process in the direction from one end of the lower end to the other lower end of the traverse-type polymerization zone, polymerizing the intermediate product with agitation and air discharge in the presence of inert gas under reduced pressure or atmospheric pressure to a final relative viscosity of .eta..sub..tau. of 1.9 to 3.3.
摘要:
A connector comprising a housing comprising a resin composition comprising:(A) from 50 to 95 parts by weight of a semi-aromatic polyamide comprising (A1) an adipate of hexamethylenediamine and (A2) a terephthalate of hexamethylenediamine, where the weight ratio of the adipate of hexamethylenediamine (A1) to the terephthalate of hexamethylenediamine (A2) is from 80/20 to 50/50; and(B) from 5 to 50 parts by weight of a modified polyolefin comprising (B1) a polyolefin copolymer comprising (B11) propylene and (B12) ethylene where the molar ratio of propylene (B11) to ethylene (B12) is from 90/10 to 99/1, the polyolefin copolymer (B1) being graft-modified with (B2) from 0.05 to 5 parts by weight of an .alpha.,.beta.-unsaturated carboxylic acid, an anhydride thereof, or a derivative thereof per 100 parts by weight of the polyolefin copolymer (B1).
摘要:
A process for production of polyimide molded bodies which comprises a step in which a polyimide resin powder obtained by polymerization and imidation of p-phenylenediamine with 3,3,4,4′-biphenyltetracarboxylic acid, its ester or its dianhydride and 2,3,3′,4′-biphenyltetracarboxylic acid, its ester or its dianhydride is molded at a pressure of approximately 800-5,000 kgf/cm2, a step in which the pressurized body is subjected to calcination at about 450-550° C. under low pressure, a step in which the calcined molded body is vacuum encapsulated into a metal capsule, and a step in which the encapsulated molded body is isotropically subjected to hot compression at approximately 460-550° C. in an inert gas atmosphere such as argon. The polyimide molded bodies obtained thereby have a density in the range of 1.44-1.38 g/cm3.
摘要翻译:一种聚酰亚胺成型体的制造方法,其特征在于,包括通过聚对苯二胺与3,3,4,4'-联苯四羧酸,其酯或其二酐2,3的聚酰亚胺树脂粉末, 3',4'-联苯四羧酸,其酯或其二酐在约800-5,000kgf / cm 2的压力下成型,其中加压体在约450-550℃下进行煅烧。 在低压下,将煅烧成型体真空密封在金属胶囊中的步骤,以及在惰性气体气氛例如约460〜550℃下各向同性地进行热压缩的封装成型体的工序 氩气。 由此获得的聚酰亚胺成型体的密度在1.44-1.38g / cm 3的范围内。
摘要:
A polyamide resin composition comprising: (A) from 50 to 92 parts by weight of a crystalline terpolymer polyamide produced from: (a) an equimolar salt of hexamethylenediamine with adipic acid, (b) an equimolar salt of hexamethylenediamine with terephthalic acid, and (c) 12-aminododecanoic acid or .omega.-laurolactam; (B) from 5 to 35 parts by weight of a modified polyolefin grafted with an .alpha.,.beta.-unsaturated carboxylic acid or an anhydride or derivative thereof; and (C) from 3 to 15 parts by weight of polyamide 12, with the total amount of the composition being 100 parts by weight.