摘要:
An environmentally friendly polymerization catalyst for polyalkylene terephthalate which does not use a heavy metal such as antimony, and a method for producing polyalkylene terephthalate using the catalyst. The catalyst for polymerizing a polyalkylene terephthalate is a titanium oxide sol containing an organic solvent as a dispersion medium, the sol has a light transmittance of not less than 50%, the light transmittance being measured by adjusting a concentration of the titanium oxide in the sol to 0.7 g/L and setting an optical path length to 1 cm in a wavelength range of 400 to 800 nm, and the amount of hydroxyl groups per 1 g of titanium oxide is not less than 1.8 mmol.
摘要:
An object of the present invention is to provide an environmentally friendly polymerization catalyst of polyalkylene terephthalate which does not use a heavy metal such as antimony. Another object of the present invention is to provide the method of producing polyalkylene terephthalate using the catalyst.The inventive titanium oxide sol for a catalyst for polymerizing a polyalkylene terephthalate is a titanium oxide sol containing an organic solvent as a dispersion medium, wherein the titanium oxide in the sol has a concentration of 0.7 g/L, the sol has a light transmittance of not less than 50%, the light transmittance being measured by setting an optical path length to 1 cm in a wavelength range of 400 to 800 nm, and the amount of hydroxyl groups per 1 g of titanium oxide is not less than 1.8 mmol.
摘要:
A vinyl alcohol polymer composition (II) is produced by a process of providing a reaction liquid comprising a solution containing a vinyl carboxylate polymer and, a first metal alkoxide (I) having at least one functional group and/or an oligomer (I) having at least one functional group obtained from said metal alkoxide (I); a step of simultaneously effecting (a) saponification of said vinyl carboxylate polymer and (b) reaction in which at least part of the functional groups of said metal alkoxide (I) and/or said oligomer (I) participates, thereby obtaining a vinyl alcohol polymer composition (I); and a step of preparing a solution (A) containing said vinyl alcohol polymer composition (I), followed by adding to the solution (A) a second metal alkoxide (II) and/or an oligomer (II) obtained from the metal alkoxide (II) or another solution (B) containing the metal alkoxide (II) and/or the oligomer (II) derived from the metal alkoxide (II), to prepare an intermediate product solution (C), and then removing the solvent from said solution (C). The vinyl alcohol polymer composition obtained by the above process has excellent gas-barrier properties, in particular excellent gas-barrier properties under high-humidity conditions. The vinyl alcohol polymer composition is suitably usable as a coating agent having good storage stability and little uneven applicability, and as gas-barrier material, in particular laminate having excellent gas-barrier properties under high-humidity conditions.
摘要:
A method of production of a circuit board utilizing electroplating which prevents signal reflection and noise due to unnecessary parts in the circuit patterns when electroplating to form circuit patterns on the board to thereby improve the electrical properties and realize higher density layout of the circuit patterns, including the steps of forming a first electroless plating layer and an overlying first plating resist on a metal foil-clad insulating board, feeding power to the first electroless plating layer to form a first electroplating layer over the first electroless plating layer in resist openings; removing the first plating resist; removing the exposed first electroless plating layer and metal foil to expose the insulating board; forming a second electroless plating layer over the exposed parts of the board and the circuit patterns; forming a second plating resist over that; removing the second electroless plating layer at the resist openings; feeding power to the second electroless plating layer under the second plating resist to form a second electroplating layer over the circuit patterns in the resist openings; removing the second plating resist; and removing the exposed second electroless plating layer.
摘要:
A semiconductor package uses no thermosetting adhesive for mounting a heat slug thereon, which adhesive requires a strict control during the storage and the production thereof. A semiconductor package comprises a circuit board having respective surfaces and an opening; a conductive layer formed on one of the surfaces of the circuit board so that the conductive layers are retracted from a peripheral edge of the opening by a certain distance; a heat slug attached to the one surface of the circuit board by means of solder so that the opening is closed at the one surface and opened at the other surface to form a cavity within which a semiconductor element mounting area is defined; and the heat slug is provided with a groove along a periphery of the semiconductor element mounting area and adjacent the peripheral edge of the opening.
摘要:
A multi-layer lead frame is provided with a lead frame body made of a metal strip and having a plurality of inner leads including respective tips which define an opening. A power supply metal plane is adhered to the inner leads and a ground metal plane is adhered to the power supply metal plane by insulative adhesive layers. These metal planes are provided with first wire bonding areas and through holes in the vicinity thereof. A semiconductor device comprises such a multi-layer lead frame, a semiconductor chip mounted on a stage thereof, bonding-wires electrically connecting the chip to the areas, and a resin integrally molding the multi-layer lead frame, the chip, and the bonding-wires in such a manner that the through holes are filled with the resin.
摘要:
A method of production of a circuit board utilizing electroplating which prevents signal reflection and noise due to unnecessary parts in the circuit patterns when electroplating to form circuit patterns on the board to thereby improve the electrical properties and realize higher density layout of the circuit patterns, including the steps of forming a first electroless plating layer and an overlying first plating resist on a metal foil-clad insulating board, feeding power to the first electroless plating layer to form a first electroplating layer over the first electroless plating layer in resist openings; removing the first plating resist; removing the exposed first electroless plating layer and metal foil to expose the insulating board; forming a second electroless plating layer over the exposed parts of the board and the circuit patterns; forming a second plating resist over that; removing the second electroless plating layer at the resist openings; feeding power to the second electroless plating layer under the second plating resist to form a second electroplating layer over the circuit patterns in the resist openings; removing the second plating resist; and removing the exposed second electroless plating layer.
摘要:
A metal plane support structure of a semiconductor device multi-layer lead frame having one or more metal planes, of different types, arranged in stacked and aligned relationship with and adhered to a corresponding lead frame. Metal planes of a common type are defined in a corresponding metal strip, at longitudinally spaced positions, the metal strip having a pair of side rails along the longitudinal edges thereof, integral support bars extending transversely of the side rails and interconnecting the metal planes to the side rails and section bars extending between and integrally interconnecting the side rails, each section bar disposed between two adjacent metal planes. Separating portions are formed in aligned relationship in the support bars and section bars. The lead frames are defined, further, at longitudinally spaced positions corresponding to the spacing of the metal planes, in a further metal strip having a smaller transverse dimension than that of each metal plane strip. In the assembled relationship of each metal plane with a corresponding lead frame, the side rails are diposed outwardly, in a transverse direction, from the side edges of the lead frame metal strip and are readily removed, along with the support bars and section bars, at the respective separating portions.
摘要:
A multi-layer lead frame is provided with a lead frame body made of a metal strip and having a plurality of inner leads including respective tips which define an opening. A power supply metal plane is adhered to the inner leads and a ground metal plane is adhered to the power supply metal plane by insulative adhesive layers. These metal planes are provided with first wire bonding areas and through holes in the vicinity thereof. A semiconductor device comprises such a multi-layer lead frame, a semiconductor chip mounted on a stage thereof, bonding-wires electrically connecting the chip to the areas, and a resin integrally molding the multi-layer lead frame, the chip, and the bonding-wires in such a manner that the through holes are filled with the resin.
摘要:
A final speed-reduction gearing assembly is mounted within a trans-axle casing which carries an output drive pinion shaft thereon, the gearing assembly comprising a ring gear in mesh with a drive pinion integral with the drive pinion shaft, and a differential gear unit integrally connected at the outer case thereof with the ring gear, the outer case of the unit being rotatably supported at the opposite ends thereof by first and second axially spaced bearings which are respectively mounted on first and second carrier portions of the trans-axle casing. A retainer member is arranged to fasten the first bearing to the first carrier portion of the casing and to be radially detachable for adjustment of a preload axially acting on the bearings, and an annular shim plate is disposed between the first bearing and the first carrier portion in such a way as to be removable radially for adjustment of the preload.