公开(公告)号：US20210198543A1

公开(公告)日：2021-07-01

申请号：US16754827

申请日：2018-06-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Chao Yang ,  Christopher B. Walker, JR. ,  Daniel J. O'Neal

IPC: C09J183/04 ,  H04R7/06 ,  C08K5/14 ,  C09J9/00

Abstract: Thin films are provided comprising a damping adhesive comprising a polysiloxane or mixture of polysiloxanes and exhibiting a tan delta of at least 0.42 for every temperature between 20° C. and 250° C. and a tan delta at 250° C. that is no more than 0.20 greater than the minimum tan delta measured in the range of 20° C. to 250° C.; in some cases exhibiting a tan delta of at least 0.42 for every temperature between 20° C. and 200° C. and a tan delta at 200° C. that is no more than 0.08 greater than the minimum tan delta measured in the range of 20° C. to 200° C.; in some cases obtained by crosslinking polysiloxane(s) by e-beam or peroxide. Microspeaker diaphragm materials, subassemblies and transfer tapes comprising such films are also provided.

公开(公告)号：US20140212651A1

公开(公告)日：2014-07-31

申请号：US14228656

申请日：2014-03-28

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Richard J. Pokorny ,  Thomas P. Klun ,  Christopher B. Walker, JR. ,  David B. Olson ,  Joan M. Noyola ,  Michelle L. Toy ,  Evan L. Schwartz

IPC: C09D7/12

CPC classification number: C09D7/125 ,  C08F220/24 ,  C08F2220/285 ,  C08J7/047 ,  C09D5/1618 ,  C09D7/1233 ,  C09D7/63 ,  C09D7/65 ,  Y10S525/92 ,  Y10T428/249953 ,  Y10T428/31544 ,  Y10T428/31663

Abstract: Presently described are coating compositions comprising a polymerizable resin composition and a non-ionic unpolymerizable surfactant. In some embodiments, the coating comprises greater than 10 wt-% of non-ionic unpolymerizable surfactant. In other embodiments, the coating composition comprises an an additive comprising a silicone group or a fluorinated group and a hydrophobic group. Also described are articles comprising the cured coating compositions. In one embodiment, an article is described comprising a cured coating wherein the cured coating exhibits a property of an initially visible simulated fingerprint reducing in visibility in 1-20 minutes. Also described is a method of determining the fingerprint visibility of a coating composition and a polyacylate composition useful as an additive. In another embodiment a coated surface is described comprising a polymeric organic material comprising a plurality of pores wherein a portion of the pores are interconnected and comprise a lipophilic liquid.

Abstract translation: 目前描述的是包含可聚合树脂组合物和非离子不可聚合表面活性剂的涂料组合物。 在一些实施方案中，涂层包含大于10重量％的非离子不可聚合表面活性剂。 在其它实施方案中，涂料组合物包含包含硅氧烷基团或氟化基团和疏水基团的添加剂。 还描述了包含固化的涂料组合物的制品。 在一个实施方案中，描述了包含固化涂层的制品，其中固化的涂层表现出在1-20分钟内可见度的最初可见的模拟指纹的性质降低。 还描述了确定涂料组合物和可用作添加剂的聚丙烯酸酯组合物的指纹可见性的方法。 在另一个实施方案中，描述了涂覆的表面，其包括包含多个孔的聚合有机材料，其中一部分孔相互连接并且包含亲油性液体。

公开(公告)号：US20210280337A1

公开(公告)日：2021-09-09

申请号：US16948540

申请日：2020-09-23

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Ankit Mahajan ,  James Zhu ,  Saagar A. Shah ,  Mikhail L. Pekurovsky ,  Vivek Krishnan ,  Kevin T. Reddy ,  Christopher B. Walker, JR. ,  Michael A. Kropp ,  Kara A. Meyers ,  Teresa M. Goeddel ,  Thomas J. Metzler ,  Jonathan W. Kemling ,  Roger W. Barton

IPC: H01B7/06 ,  H01B7/02 ,  H01B13/00 ,  H01B13/008

Abstract: A stretchable conductor includes a substrate with a first major surface, wherein the substrate is an elastomeric material. An elongate wire is on the first major surface of the substrate; the wire includes a first end and a second end, and further includes at least one arcuate region between the first end and the second end. At least one portion of the arcuate region of the wire in the region has a first surface area portion embedded in the surface of the substrate and a second surface area portion unembedded on the substrate and exposed in an amount sufficient to render at least an area of the substrate in the region electrically conductive. The unembedded second surface portion of the arcuate region may lie above or below a plane of the substrate. Composite articles including a stretchable conductor in durable electrical contact with a conductive fabric are also disclosed.

公开(公告)号：US20130088782A1

公开(公告)日：2013-04-11

申请号：US13690064

申请日：2012-11-30

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Christopher B. Walker, JR. ,  Marc D. Radcliffe ,  Thomas P. Klun ,  Lan H. Liu ,  Richard J. Pokorny ,  William D. Coggio ,  Chuntao Cao ,  Mark J. Pellerite ,  Paul C. Kelley ,  Robert J. Fleming

IPC: G02B1/11

CPC classification number: G02B1/111 ,  Y10T428/24942 ,  Y10T428/25 ,  Y10T428/254 ,  Y10T428/256 ,  Y10T428/265 ,  Y10T428/269 ,  Y10T428/3154 ,  Y10T428/31935

Abstract: Antireflective films are described having a surface layer comprising a the reaction product of a polymerizable low refractive index composition comprising at least one free-radically polymerizable fluoropolymer and surface modified inorganic nanoparticles. A high refractive index layer is coupled to the low refractive index layer. In one embodiment, the high refractive index layer comprises surface modified inorganic nanoparticles dispersed in a crosslinked organic material. The antireflective film is preferably durable, exhibiting a haze of less than 1.0% after 25 wipes with steel wool using a 3.2 cm mandrel and a mass of 1000 grams.

Abstract translation: 描述了具有包含包含至少一种可自由基聚合的含氟聚合物和表面改性的无机纳米颗粒的可聚合低折射率组合物的反应产物的表面层的抗反射膜。 高折射率层耦合到低折射率层。 在一个实施方案中，高折射率层包含分散在交联的有机材料中的表面改性的无机纳米颗粒。 抗反射膜优选耐用，在使用3.2cm心轴和质量为1000克的钢丝绒进行25次擦拭之后，其雾度小于1.0％。

公开(公告)号：US20180319204A1

公开(公告)日：2018-11-08

申请号：US15775083

申请日：2016-12-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： John C. Clark ,  Samad Javid ,  Vivek Krishnan ,  Alexander J. Kugel ,  Aaron K. Nienaber ,  Chris A. Pommer ,  Christopher B. Walker, JR.

IPC: B44C1/18 ,  B44C1/17 ,  B44C1/175 ,  B32B5/16 ,  B32B7/12 ,  B32B37/00

CPC classification number: B44C1/18 ,  B32B5/16 ,  B32B7/12 ,  B32B37/025 ,  B32B2307/418 ,  B32B2451/00 ,  B44C1/1725 ,  B44C1/1756

Abstract: Described herein is decorative article having a coefficient of friction less than 0.3 wherein the decorative articles comprises: (i) a microsphere layer comprising a plurality of microspheres, wherein the microsphere layer comprises a monolayer of microspheres and wherein the plurality of microspheres are in a microscopic periodic pattern; and (ii) a bead bonding layer disposed on the microsphere layer, wherein the plurality of microspheres are partially embedded in the bead bonding layer. Also disclosed herein are transfer articles and methods of making the decorative articles and transfer articles.

公开(公告)号：US20160145458A1

公开(公告)日：2016-05-26

申请号：US14900185

申请日：2014-06-26

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Christopher B. Walker, JR. ,  John C. Clark ,  Tatsuo Fukushi ,  Thomas P. Klun ,  Vivek Krishnan ,  Alexander J. Kugel ,  Lan H. Liu ,  Jingjing Ma ,  Steven J. McMan

IPC: C09D127/18 ,  C09D127/16 ,  C09D127/12 ,  C09D127/20

Abstract: There is provided an article comprising at least a first surface having a fluorine-containing polymeric binder resin layer and a plurality of microspheres partially embedded in a first major surface of the binder resin layer and adhered thereto; wherein the fluorine-containing polymer is derived in part from at least one partially fluorinated, or non-fluorinated, monomer; and wherein the article exhibits a stain resistance to yellow mustard at elevated temperature and humidity as measured by the change in b* of less than 50. There are also provided such articles wherein the fluorine-containing polymer is derived in part from at least one partially fluorinated, or non-fluorinated, monomer; and wherein the fluorine content along the polymeric backbone of the fluorine-containing polymer is from about 27% to 72% by weight. There are also provided such articles wherein the article is a thermoformable article exhibiting chemical resistance according to ASTM D5402-06.

Abstract translation: 提供一种制品，其至少包括具有含氟聚合物粘合剂树脂层的第一表面和部分地嵌入粘合剂树脂层的第一主表面并粘合到其上的多个微球; 其中所述含氟聚合物部分地衍生自至少一种部分氟化的或非氟化的单体; 并且其中所述制品在通过b *的变化小于50测量的高温和湿度下对黄芥子具有耐污染性。还提供了这样的制品，其中所述含氟聚合物部分地衍生自部分 氟化或非氟化的单体; 并且其中沿着含氟聚合物的聚合物主链的氟含量为约27％至72％重量。 还提供了这样的制品，其中制品是根据ASTM D5402-06具有耐化学性的热成型制品。

公开(公告)号：US20230131805A1

公开(公告)日：2023-04-27

申请号：US17912014

申请日：2021-03-03

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Chao Yang ,  Christopher B. Walker, JR.

IPC: H04R31/00 ,  H04R7/02 ,  C08J3/24 ,  C08J3/28

Abstract: The invention provides a diaphragm for a microspeaker and a manufacturing method thereof. The diaphragm is a single-layer diaphragm or a multi-layer diaphragm and comprises at least one layer of a chemically cross-linked thermoplastic polyester elastomer, wherein: the chemically cross-linked thermoplastic polyester elastomer has a loss factor less than or equal to 0.4 at a temperature range not higher than a softening temperature of thermoplastic polyester elastomer before chemical crosslinking plus 40° C., as measured by a rheological curve; and the diaphragm further has a yield strain in the range of 7% to 30%. The diaphragm for a microspeaker according to the technical solution of the present invention is easy to be prepared by thermoforming, and has appropriate modulus, good strength, elasticity, and thermal stability.

公开(公告)号：US20170204234A1

公开(公告)日：2017-07-20

申请号：US15479496

申请日：2017-04-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Christopher B. Walker, JR. ,  Joseph D. Rule ,  Vivek Krishnan ,  John C. Clark ,  Steven J. McMan ,  Toheeb B. Alabi ,  Charlie C. Ho ,  Ryan E. Marx ,  Alexander J. Kugel

IPC: C08J5/18 ,  B32B27/36 ,  B32B27/08 ,  B32B27/40 ,  C08K7/18 ,  B32B3/08

CPC classification number: C08J5/18 ,  B32B3/085 ,  B32B27/08 ,  B32B27/20 ,  B32B27/306 ,  B32B27/308 ,  B32B27/36 ,  B32B27/40 ,  B32B2037/243 ,  B32B2255/00 ,  B32B2260/025 ,  B32B2260/046 ,  B32B2264/101 ,  B32B2264/104 ,  B32B2307/418 ,  B32B2451/00 ,  B44C5/0476 ,  C08J2375/04 ,  C08K3/08 ,  C08K3/22 ,  C08K3/40 ,  C08K7/18 ,  C08K7/20 ,  C09D7/70 ,  C09D183/04 ,  Y10T428/24893 ,  Y10T428/252 ,  Y10T428/254

Abstract: There is provided an article comprising at least a first surface having a first binder layer selected from at least one of linear resins and resins having low cross link densities, where the first binder layer has a first major surface opposite a second major surface; and a plurality of microspheres at least partially embedded in the first major surface of the first binder layer. There is also provided an article comprising a first surface having a first binder layer selected from at least one of linear resins and resins having low cross link densities; and a plurality of microspheres at least partially embedded a the first major surface of the first binder layer, where for at least a portion of the first major surface the plurality of microspheres covers 30% to 50% of that portion, and the microspheres are substantially uniformly spaced.

公开(公告)号：US20170174854A1

公开(公告)日：2017-06-22

申请号：US15129099

申请日：2015-04-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： John C. Clark ,  Alexander J. Kugel ,  Benjamin R. Coonce ,  Vivek Krishnan ,  Christopher B. Walker, JR.

IPC: C08J7/04 ,  B44C5/04 ,  B44C1/17

CPC classification number: C08J7/047 ,  B32B5/024 ,  B32B7/12 ,  B32B25/16 ,  B32B27/065 ,  B32B27/08 ,  B32B27/12 ,  B32B27/20 ,  B32B27/281 ,  B32B27/30 ,  B32B27/302 ,  B32B27/304 ,  B32B27/306 ,  B32B27/308 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B27/365 ,  B32B27/40 ,  B32B27/42 ,  B32B2264/02 ,  B32B2264/101 ,  B32B2264/105 ,  B32B2264/107 ,  B32B2266/0278 ,  B32B2270/00 ,  B32B2274/00 ,  B32B2307/4026 ,  B32B2307/41 ,  B32B2307/414 ,  B32B2307/51 ,  B32B2307/54 ,  B32B2307/546 ,  B32B2307/554 ,  B32B2307/584 ,  B32B2307/736 ,  B32B2437/00 ,  B32B2437/02 ,  B32B2451/00 ,  B32B2509/00 ,  B32B2605/003 ,  B44C1/17 ,  B44C1/1708 ,  B44C5/0476 ,  C08J2327/18 ,  C08J2475/08

Abstract: There is provided an article having a compliant article where the compliant article comprises an polymer layer and a first layer disposed along a first major surface of the polymer layer; and a plurality of microspheres partially embedded and adhered to a major surface of the first layer opposite the surface that is disposed along the first major surface of the polymer layer, wherein the article has a compression modulus of less than or equal to 0.5 MPa. There is also provided an article having a compliant article where the compliant article comprises a polymer layer; and a plurality of microspheres partially embedded and adhered to a major surface of the compliant article, where the article has a compression modulus of less than or equal to 0.5 MPa, and further where the article is a decorative article.

公开(公告)号：US20160347026A1

公开(公告)日：2016-12-01

申请号：US15117494

申请日：2015-02-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Alexander J. Kugel ,  John C. Clark ,  Vivek Krishnan ,  Christopher B. Walker, JR.

IPC: B32B3/16 ,  B32B27/14 ,  B32B27/40

CPC classification number: B32B3/16 ,  B32B3/00 ,  B32B3/30 ,  B32B7/00 ,  B32B7/02 ,  B32B7/12 ,  B32B9/00 ,  B32B27/00 ,  B32B27/06 ,  B32B27/08 ,  B32B27/14 ,  B32B27/18 ,  B32B27/20 ,  B32B27/28 ,  B32B27/286 ,  B32B27/40 ,  B32B2260/00 ,  B32B2260/025 ,  B32B2264/00 ,  B32B2307/308 ,  B32B2307/50 ,  B32B2307/546 ,  B32B2451/00

Abstract: There is provided an article a binder resin layer comprising an aliphatic polyurethane polymer comprising a plurality of soft segments, and a plurality of hard segments, where the soft segments comprise poly(alkoxy) polyol, and where the poly(alkoxy) polyol is essentially free of crosslinker; and a plurality of microspheres partially embedded and adhered to a first major surface of the binder resin layer, wherein the specific chemical identities and relative amounts of the segments and moieties of the aliphatic polyurethane polymer are sufficient to impart a glass transition temperature of 10° C. or less in the article and a storage modulus in the article that changes less than 15 MPa from 25° C. to 175° C.

Abstract translation: 提供了一种粘合剂树脂层，其包含包含多个软链段的脂族聚氨酯聚合物和多个硬链段，其中软链段包含聚（烷氧基）多元醇，并且其中所述聚（烷氧基）多元醇基本上是游离的 的交联剂; 以及部分地嵌入并粘附到粘合剂树脂层的第一主表面上的多个微球，其中脂族聚氨酯聚合物的链段和部分的具体化学特性和相对量足以使玻璃化转变温度为10℃ 或更低的制品中，储存模量从25℃变化至175℃变化小于15MPa。