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公开(公告)号:US20220403209A1
公开(公告)日:2022-12-22
申请号:US17638534
申请日:2020-08-21
IPC分类号: C09J7/10
摘要: Provided are adhesive articles and related methods of making and use. The adhesive article includes one or more patterned adhesive layers comprising compositionally and spatially distinct adhesives that are laterally disposed relative to each other. The first and second adhesives are optionally capable of being functionally cured to provide a structural adhesive bond with a substrate. These adhesives can provide high fracture toughness and high modulus characteristics not otherwise possible in a homogeneous adhesive composition. These adhesives can provide some degree of crack arrestment and significantly reduce the need for mechanical fasteners in industrial bonding applications.
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公开(公告)号:US20180291139A1
公开(公告)日:2018-10-11
申请号:US16006659
申请日:2018-06-12
发明人: Scott A. Boyd , Dmitriy Salnikov , David T. Amos
摘要: A composition is provided comprising: a) a curable epoxy resin; and b) 0.01-30% by weight of a polycarbodiimide according to Formula I: R—{—N═C═N—R—}n—N═C═N—R (I) wherein n is an integer between 0 and 100, and wherein each R is independently selected from aromatic and aliphatic groups which contain between 1 and 24 carbons and which are optionally substituted, typically comprising 0.1-20% by weight of the polycarbodiimide. In some embodiments the present disclosure provides sheet materials made of such cured, uncured or partially cured materials. In some embodiments these compositions may be useful in making surfacing films for composite parts and may demonstrate good paint stripper resistance and microcrack resistance.
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公开(公告)号:US20160024356A1
公开(公告)日:2016-01-28
申请号:US14875133
申请日:2015-10-05
IPC分类号: C09J163/00 , C09J121/00 , C09J133/04
CPC分类号: C09J163/00 , C08J7/047 , C08L9/02 , C08L77/10 , C08L81/06 , C08L2666/02 , C08L2666/04 , C09J121/00 , C09J133/04 , Y10T428/254 , Y10T428/31504 , Y10T428/31511 , Y10T428/31721 , Y10T428/31786
摘要: A method for surfacing a polymeric composite article and/or for joining (for example, by bonding or by co-curing) the article and an adherend (for example, a second polymeric composite article) comprises (a) providing a cured or curable polymeric composite article; (b) providing a curable composition comprising (1) at least one thermosetting resin, and (2) at least one preformed, substantially non-functional, particulate modifier comprising at least one elastomer; and (c) directly or indirectly applying the composition to at least a portion of at least one surface of the article.
摘要翻译: 用于表面聚合复合制品和/或用于接合(例如通过粘合或共同固化)制品和被粘物(例如,第二聚合物复合制品)的方法包括(a)提供固化或固化的聚合物 复合制品; (b)提供可固化组合物,其包含(1)至少一种热固性树脂,和(2)至少一种预先形成的,基本上无功能的颗粒改性剂,其包含至少一种弹性体; 和(c)将所述组合物直接或间接施用于制品的至少一个表面的至少一部分。
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公开(公告)号:US10442550B2
公开(公告)日:2019-10-15
申请号:US15482898
申请日:2017-04-10
发明人: Dmitriy Salnikov
IPC分类号: B64D45/02 , B32B7/02 , B32B15/08 , B32B15/20 , B32B27/18 , B32B27/28 , B32B27/32 , B32B27/34 , B32B27/36 , B32B27/38 , B32B27/42
摘要: A layered construction is provided having a storage modulus G′t25 at 25° C., comprising: a) a cured polymeric composite having a storage modulus G′s25 at 25° C.; and b) a cured surfacing film bound thereto; wherein G′t25 is not greatly elevated over G′s25, typically not more than 118% of G′s25. In some embodiments the cured surfacing film comprises an electrically conductive layer, typically a metal layer. In some embodiments the cured surfacing film comprises a cured epoxy resin which may optionally be a chain-extended epoxy resin and may excludes phosphorus. The resulting layered construction may display high erosion resistance, high corrosion resistance, and high resistance to microcracking. In another aspect, methods of making the subject layered constructions are provided.
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公开(公告)号:US09695273B2
公开(公告)日:2017-07-04
申请号:US14345258
申请日:2012-10-25
CPC分类号: C08G59/504 , C08G59/4007 , C08G59/50 , C08G73/0233 , C08K5/17 , C08L63/00 , C08L79/02 , C08L79/04
摘要: Novel oligomers and polymers derived from the reaction of benzoxazine compounds with a mixture of epoxy compounds and amine compounds are disclosed. The compositions are useful in coating, sealants, adhesive and many other applications.
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公开(公告)号:US20170114256A1
公开(公告)日:2017-04-27
申请号:US15397834
申请日:2017-01-04
IPC分类号: C09J163/00 , C09J7/04 , C08G59/24 , C08G59/66 , C08G59/56
CPC分类号: C09J163/00 , C08G59/245 , C08G59/56 , C08G59/66 , C08K5/0025 , C09J7/00 , C09J7/10 , C09J7/30 , C09J2400/263 , C09J2400/283 , C09J2463/00 , Y10T442/10
摘要: Adhesive compositions are provided comprising: a) a base resin comprising an epoxy resin; b) a first epoxy curative; and c) a second epoxy curative; wherein the first and second epoxy curatives are chosen such that the second epoxy curative may remain substantially unreacted in the composition under conditions of temperature and duration that render the first epoxy curative substantially reacted with epoxy resin in the composition. In some embodiments, the first epoxy curative is substantially reacted with epoxy resin in the composition and the second epoxy curative is substantially unreacted in the composition. In some embodiments, the adhesive composition is used in the form of an adhesive film.
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公开(公告)号:US11370908B2
公开(公告)日:2022-06-28
申请号:US17052430
申请日:2019-06-25
发明人: Lianzhou Chen , Dmitriy Salnikov
IPC分类号: C08L63/00 , C09J7/35 , C08G59/24 , C08G59/38 , C08G59/50 , C08G59/60 , C08G75/029 , C08K3/08 , C08K5/18 , C08L81/06 , C08G59/40
摘要: Provided is a curable composition containing a reactive mixture of components including an polyethersulfone having a chemical group reactive with an epoxide, a cycloaliphatic polyepoxide resin, a polyepoxide having a functionality greater than two, a liquid diepoxide resin, a first curative containing 9,9-bis(aminophenyl)fluorene or a derivative therefrom and having a curing onset temperature of from 150° C. to 200° C. The components can further comprise a second curative having a curing onset temperature of from 60° C. to 180° C. When thermally curing this composition, the second epoxy curative starts to cure before the first epoxy curative, thereby inhibiting vertical flow of the adhesive during the curing process.
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公开(公告)号:US09896599B2
公开(公告)日:2018-02-20
申请号:US14776087
申请日:2014-04-22
IPC分类号: C08G67/02 , C09D179/04 , C08K5/00 , C08G73/02 , C08K5/42 , C09J179/04 , C08L79/04
CPC分类号: C09D179/04 , C08G73/0233 , C08K5/0025 , C08K5/42 , C08L79/04 , C09J179/04
摘要: A polymerizable composition is described comprising a benzoxazine, and a tosylate, which when thermolyzed, forms a (meth)acrylamide, a (meth)acrylate, a vinyl ketone, a vinyl ether or a styrenic compound.
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公开(公告)号:US20150165670A1
公开(公告)日:2015-06-18
申请号:US14408188
申请日:2013-06-13
发明人: Larry S. Hebert , Dmitriy Salnikov
CPC分类号: B29C59/005 , B29K2063/00 , B29K2105/0097 , B29K2995/0005 , C08G59/56 , C08G59/66 , C09D5/24 , C09J7/20 , C09J163/00 , C09J2463/00
摘要: A method is provided for making structured hybrid adhesive articles comprising the steps of: a) providing an adhesive article comprising: i) a base resin comprising an epoxy resin, ii) a first epoxy curative, and iii) a second epoxy curative, by reacting the base resin with the first epoxy curative such that the first epoxy curative is substantially reacted with epoxy resin in the article and the second epoxy curative is substantially unreacted in the article; b) embossing the adhesive article with a relief pattern; and c) curing the adhesive article such that the second epoxy curative is substantially reacted with epoxy in the article. In some embodiments, the method additionally comprises a step of embedding a scrim in the adhesive. In some embodiments, the method additionally comprises a step of depositing an electrically conductive layer onto the surface of the adhesive article embossed with the relief pattern.
摘要翻译: 提供了一种用于制造结构化混合粘合剂制品的方法,包括以下步骤:a)提供粘合剂制品,其包括:i)包含环氧树脂的基础树脂,ii)第一环氧固化剂,和iii)第二环氧固化剂,通过使 具有第一环氧固化剂的基础树脂使得第一环氧固化剂基本上与制品中的环氧树脂反应,第二环氧固化剂在制品中基本上未反应; b)用浮雕图案压印粘合剂制品; 和c)固化粘合剂制品,使得第二环氧固化剂在制品中基本上与环氧树脂反应。 在一些实施例中,该方法还包括将稀松布嵌入粘合剂中的步骤。 在一些实施例中,该方法还包括将导电层沉积到用浮雕图案压花的粘合剂制品的表面上的步骤。
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公开(公告)号:US20140374015A1
公开(公告)日:2014-12-25
申请号:US14369326
申请日:2012-12-26
发明人: Dmitriy Salnikov
CPC分类号: F16B19/00 , B29C65/1406 , B29C65/1435 , B29C65/1483 , B29C65/4825 , B29C65/4845 , B29C65/485 , B29C65/542 , B29C66/1122 , B29C66/474 , B29C66/71 , B29C66/721 , B29C66/7212 , B29C66/742 , B32B37/1284 , B32B37/1292 , B32B37/16 , B32B2037/1253 , B32B2310/0831 , C09J5/00 , C09J163/00 , C09J2205/31 , F16B11/006 , F16B37/048 , B29K2077/00 , B29K2027/18 , B29K2071/00 , B29K2071/12 , B29K2307/04
摘要: Articles and methods are presented that are useful in mounting pins or studs on substrates such as composite materials. An anchor according to the present invention comprises a stud attached to a base, where the base is substantially UV-transparent, and optionally a UV-curable adhesive, a pressure sensitive adhesive, an adhesive that is both UV-curable and pressure sensitive, or some combination of the above.
摘要翻译: 提出了可用于在诸如复合材料的基底上安装销钉或螺栓的制品和方法。 根据本发明的锚固件包括附接到基部的螺柱,其中基部基本上是紫外线透明的,以及可选地可UV固化的粘合剂,压敏粘合剂,可UV固化和压敏的粘合剂,或 以上的一些组合。
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