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公开(公告)号:US20230132320A1
公开(公告)日:2023-04-27
申请号:US17918188
申请日:2021-04-09
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Lianzhou Chen , Sohaib Elgimiabi , Dmitriy Salnikov , Jay S. Schlechte , Yaoyao Chen
IPC: C08G59/18 , C08G59/50 , C08G59/32 , C08G59/42 , C09J163/00
Abstract: Provided is a curative part usable in a two-part curable composition. The curative part includes a liquid amine; a heterogeneous dispersant; and core-shell rubber particles having an elastomeric core and a (meth)acrylic shell. The core-shell rubber particles and the heterogeneous dispersant can be collectively shear-dispersed in the liquid amine such that the core-shell rubber particles are substantially non-aggregated and the curative part is phase-stable over a period of at least 3 months at ambient temperature. Advantageously, large amounts of core-shell rubber particles can thus be incorporated into a cured resin matrix, which can afford significantly enhanced impact performance.
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公开(公告)号:US20200017623A1
公开(公告)日:2020-01-16
申请号:US16491051
申请日:2018-03-08
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Sheng Ye , Ying Lin , Michael E. Griffin , Dennis R. Keicher , Jay S. Schlechte , Paul J. Homnick , Richard S. Smith , Thomas P. Klun , Richard J. Pokorny , Steven Y. Yu , Patricia M. Savu , Michael A. Kropp , Ian Dailey , Charlie P. Blackwell
IPC: C08F290/06 , C09D175/16 , C09D4/00 , C08L75/16 , C09J4/00 , C09J151/08 , F21V29/70 , F21V29/60 , B05D3/06 , B05D7/16 , B29C35/08
Abstract: The disclosure relates to compositions, methods of applying such compositions, and methods for curing such compositions to a depth of cure of up to about 30 mm within about 0.5 second to about two minutes per light exposure area.
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公开(公告)号:US20240287247A1
公开(公告)日:2024-08-29
申请号:US18569992
申请日:2022-05-19
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jay S. Schlechte , Yaoyao Chen , Zachary J. Thompson , Lianzhou Chen , Kolby L. White , George M. Stout
CPC classification number: C08G59/5013 , C08G59/245 , C08G59/502 , C08G59/5026 , C08L9/00 , C08G2170/00 , C08L2205/025 , C08L2205/22 , C08L2207/53
Abstract: A curable composition and a method of making a cured composition are provided. The curable composition contains at least two parts with the first part containing three different types of curing agents that contain multiple —NHR1 groups (R1 is hydrogen, alkyl, aryl, aralkyl, or alkaryl) and with the second part containing an epoxy resin. The first part composition and the second part compositions are selected to control the rheology of the curable composition both before and after combination of the first part with the second part.
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公开(公告)号:US10329464B2
公开(公告)日:2019-06-25
申请号:US15548922
申请日:2016-02-01
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Lianzhou Chen , Jay S. Schlechte , George S. Stout , Rachel J. Squires
Abstract: A two-part adhesive is provided comprising: A) a curative part comprising: i) an epoxy curative; and ii) a reaction intermediate which is the reaction product of a suspension of core/shell rubber nanoparticles in a liquid epoxy resin and an excess of the epoxy curative; wherein the curative part comprises greater than 1.1 wt % core/shell rubber nanoparticles; and B) an epoxy part comprising: iii) a liquid epoxy resin; and iv) greater than 9.1 wt % core/shell rubber nanoparticles. In some embodiments, the epoxy part additionally comprises greater than 5.1 wt % solid epoxy resin, such as, e.g., triglycidyl ether of trisphenol-methane. In some embodiments, the sum of the wt % solid epoxy resin and the wt % core/shell rubber nanoparticles in the epoxy part is greater than 41.0%. In some embodiments, the sum of the wt % solid epoxy resin and the wt % core/shell rubber nanoparticles in the mixed adhesive is greater than 26.0%.
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公开(公告)号:US11168237B2
公开(公告)日:2021-11-09
申请号:US17250156
申请日:2019-06-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Hae-Seung H. Lee , Jay S. Schlechte
IPC: B32B27/38 , B32B27/18 , C09J163/00 , C08G59/14 , C08G59/50 , C07D303/02 , C07F7/08 , C07F7/18 , C08K5/5445 , C08G18/10 , C08G18/28 , C08G18/38 , C08G18/71 , C08G59/32 , C08G59/40 , C08K5/5465 , C08K7/20
Abstract: Adhesion promoters, Curable compositions containing the adhesion promoters, cured compositions that are formed from the curable compositions, and articles containing the cured compositions are provided. The adhesion promoter has at least one epoxide group and a plurality of hydrolyzable silyl groups. The curable compositions include an adhesion promoter, an epoxy resin, and a curing agent for the epoxy resin that has at least two amino groups that are primary and/or secondary amino groups.
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公开(公告)号:US20160108257A1
公开(公告)日:2016-04-21
申请号:US14891608
申请日:2014-04-28
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jay S. Schlechte , Patrick J. Hager , Jeffrey R. Janssen , Paul D. Graham
CPC classification number: B24B1/00 , B05D1/40 , B05D3/12 , B05D5/00 , B05D2601/22 , C09D7/61 , C09D7/67
Abstract: A method of providing an easy-clean, water-sheeting coating on a substrate includes: abrading a surface of a substrate using an abrasive article to provide an abraded surface having a surface roughness R?a#191 in a range of from 100 nm to 3500 nm, contacting a coatable composition with the abraded surface, and removing water from the coatable composition. The coatable composition comprises silica nanoparticles and has a pH of 7.5 or less. A kit including the abrasive article and the coatable composition is also disclosed.
Abstract translation: 在基材上提供容易清洁的水涂层涂层的方法包括:使用磨料制品研磨基材的表面,以提供具有表面粗糙度R a a 191的磨损表面,范围为100nm至 3500nm,使可涂覆组合物与磨损表面接触,并从可涂覆组合物中除去水分。 可涂敷组合物包含二氧化硅纳米颗粒,pH值为7.5以下。 还公开了包括磨料制品和可涂覆组合物的试剂盒。
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公开(公告)号:US20130071649A1
公开(公告)日:2013-03-21
申请号:US13678666
申请日:2012-11-16
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Patrick J. Hager , Jay S. Schlechte , Elaine M. Yorkgitis , Naiyong Jing
IPC: C09D183/06 , C08K3/36
CPC classification number: C09D183/06 , B82Y30/00 , C01P2004/64 , C01P2006/12 , C01P2006/22 , C08G77/02 , C08G77/045 , C08G77/18 , C08G77/20 , C08K3/36 , C08K5/0091 , C08K5/5419 , C08K5/5425 , C08K5/5435 , C08K5/548 , C08K9/06 , C09C1/0009 , C09C1/3081 , C09C1/309 , C09D7/62 , C09D7/67 , C09D183/02 , C09D183/04 , Y10T428/259
Abstract: A coating composition is provided comprising a) an aqueous dispersion, having a pH of less than 7.5, of silica nanoparticles having average particle diameters of 40 nanometers or less, b) an alkoxysilane oligomer; c) a silane coupling agent, and d) optionally a metal β-diketone complexing agent. The compositions may be used to prepare coated articles wherein the coating is substantially uniform in thickness, durably adheres to the substrate, and provides hydrophilic and/or antireflection surface properties to the substrate.
Abstract translation: 提供一种涂料组合物,其包含:a)具有平均粒径为40纳米或更小的二氧化硅纳米颗粒的pH小于7.5的水分散体,b)烷氧基硅烷低聚物; c)硅烷偶联剂,和d)任选的金属与二酮络合剂。 组合物可用于制备涂层制品,其中涂层的厚度基本上均匀,持久地粘附到基底上,并为基底提供亲水和/或抗反射表面性质。
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公开(公告)号:US20220185949A1
公开(公告)日:2022-06-16
申请号:US17593866
申请日:2020-04-20
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Hae-Seung Harry Lee , Jay S. Schlechte
IPC: C08G59/50 , C09J163/00 , C08K5/372 , C08G59/62
Abstract: An adhesion promoter, a curable composition containing the adhesion promoter, a cured composition formed from the curable composition, and an article containing the cured composition are provided. The adhesion promoter, which is formed by reacting a polyepoxide with a mercaptosilane that has a hydrolyzable silyl group, has at least one epoxide group and at least one hydrolyzable silyl group. The epoxide groups allow incorporation of the adhesion promoter into the polymeric matrix of the cured composition and the hydrolyzable silyl groups allow bond formation with various substrates.
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公开(公告)号:US20210238461A1
公开(公告)日:2021-08-05
申请号:US17250156
申请日:2019-06-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Hae-Seung H. Lee , Jay S. Schlechte
IPC: C09J163/00 , C08G59/32 , C08G59/40 , C08G18/10 , C08G18/28 , C08G18/38 , C08G18/71 , C08K7/20 , C08K5/5445 , C08K5/5465
Abstract: Adhesion promoters, Curable compositions containing the adhesion promoters, cured compositions that are formed from the curable compositions, and articles containing the cured compositions are provided. The adhesion promoter has at least one epoxide group and a plurality of hydrolyzable silyl groups. The curable compositions include an adhesion promoter, an epoxy resin, and a curing agent for the epoxy resin that has at least two amino groups that are primary and/or secondary amino groups.
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10.
公开(公告)号:US20170253779A1
公开(公告)日:2017-09-07
申请号:US15448277
申请日:2017-03-02
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jay S. Schlechte , Peyton R. Nosbusch , George M. Stout , Michael A. Kropp
Abstract: A curable adhesive composition includes a curable epoxy resin, an amine curing agent, a toughening agent, and aluminum flakes. The aluminum flakes include a fatty acid milling aid on at least a portion of their surfaces. The aluminum flakes were heated after milling. An article includes an adhesive composition cured between at least two members. The cured adhesive composition includes the heat-treated aluminum flakes within a toughened epoxy resin cured with an amine curing agent. The method includes applying the curable adhesive composition of described above to a surface of at least one of two or more members, joining the members so that the curable adhesive composition is sandwiched between the two or more members, and curing the curable adhesive composition to form an adhesive bond between the two or more members.
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