MULTILAYER PRESSURE-SENSITIVE ADHESIVE ASSEMBLY

    公开(公告)号:US20220177739A1

    公开(公告)日:2022-06-09

    申请号:US17270701

    申请日:2019-08-15

    Abstract: The present disclosure relates to a multilayer pressure sensitive adhesive assembly comprising at least a first pressure sensitive adhesive layer and a second pressure sensitive adhesive layer adjacent to the first pressure sensitive adhesive layer, wherein the first pressure sensitive adhesive layer and the second pressure sensitive adhesive layer comprise a polymer base material selected from the group of polyacrylates, wherein the second pressure sensitive adhesive layer has a thickness no greater than 250 micrometres and comprises silica nanoparticles having an average particle size no greater than 400 nm when measured by Dynamic Light Scattering (DLS) techniques according to the test method described in the experimental section, and wherein the first pressure sensitive adhesive layer has a thickness in a range from 250 to 5000 micrometres and is substantially free of particulate filler material. According to another aspect, the present disclosure is directed to an article comprising a medium surface energy substrate and a multilayer pressure sensitive adhesive assembly as described above adjacent to the medium surface energy substrate. In another aspect, the present disclosure relates to the use of a multilayer pressure sensitive adhesive assembly as described above for the bonding to a medium surface energy substrate or a high surface energy substrate.

    ADHESIVE FILM, ADHESIVE SYSTEM, AND RELATED PROCESSES

    公开(公告)号:US20250066646A1

    公开(公告)日:2025-02-27

    申请号:US18720807

    申请日:2022-12-16

    Abstract: An adhesive film includes a first (meth)acrylate copolymer containing at least 55 weight percent (wt. %) of linear or branched alkyl (meth)acrylate monomer units, from 15 to 40 wt. % of (meth)acrylic acid monomer units, and 0.1 to 5 wt. % of monomer units of a crosslinking monomer having more than one (meth)acrylate group. If the first (meth)acrylate copolymer comprises 15 wt. % (meth)acrylic acid monomer units, the first (meth)acrylate copolymer comprises at least five wt. % monomer units of a high Tg monomer. The adhesive film comprises not more than five wt. % of a further (meth)acrylate copolymer comprising from 0.1 to 15 wt. % of (meth)acrylic acid monomer units. The adhesive film can be a multilayer adhesive assembly including a first layer of the first (meth)acrylate copolymer and a second adhesive layer adjacent to the first layer. A process for making and a system including the adhesive film and a primer are also described.

    PRESSURE-SENSITIVE ADHESIVE COMPOSITION WITH TRANSPARENCY CHARACTERISTICS

    公开(公告)号:US20220169897A1

    公开(公告)日:2022-06-02

    申请号:US17442410

    申请日:2020-03-20

    Abstract: The present disclosure relates to a pressure sensitive adhesive composition comprising a blend of: a) a (meth)acrylate-based (co)polymer base component; and b) a (meth)acrylate-based copolymeric additive comprising the free-radical random copolymerization reaction product of a copolymerizable material comprising: i. C1-C32 acrylic acid ester monomer units; ii. greater than 10 wt. % of C1-C18 methacrylic acid ester monomer units, based on the total weight of the (meth)acrylate-based copolymeric additive; and iii. ethylenically unsaturated monomer units having a functional group, which are copolymerizable with monomer units (i) and/or (ii); wherein the (meth)acrylate-based copolymeric additive has a weight average molecular weight (Mw) greater than 10,000 Daltons and a Tg no greater than 50° C., as estimated by the Fox equation. According to another aspect, the present disclosure is directed to a multilayer pressure sensitive adhesive assembly comprising at least a first polymer layer and a second pressure sensitive adhesive layer adjacent to the first polymer layer, wherein the second pressure sensitive adhesive layer has a composition as described above. According to still another aspect of the present disclosure, it is provided a method for manufacturing a pressure sensitive adhesive composition as described above. In yet another aspect, the present disclosure relates to the use of a pressure sensitive adhesive composition or multilayer pressure sensitive adhesive assembly as described above for the bonding to a medium surface energy substrate or a high surface energy substrate.

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