RUBBER-BASED MULTILAYER PRESSURE-SENSITIVE ADHESIVE ASSEMBLY

    公开(公告)号:US20170321089A1

    公开(公告)日:2017-11-09

    申请号:US15525378

    申请日:2015-11-05

    Abstract: The present disclosure relates to a multilayer pressure sensitive adhesive assembly comprising a polymeric foam layer and a first pressure sensitive adhesive layer adjacent to the polymeric foam layer, wherein first the pressure sensitive adhesive comprises: a) a multi-arm block copolymer of the formula Qn-Y, wherein: (i) Q represents an arm of the multi-arm block copolymer and each arm independently has the formula G-R, (ii) n represents the number of arms and is a whole number of at least 3, and (iii) Y is the residue of a multifunctional coupling agent,  wherein each R is a rubbery block comprising a polymerized conjugated diene, a hydrogenated derivative of a polymerized conjugated diene, or combinations thereof; and each G is a glassy block comprising a polymerized monovinyl aromatic monomer; b) a polymeric plasticizer having a weight average molecular weight Mw of at least 10,000 g/mol; c) at least one hydrocarbon tackifier, wherein the hydrocarbon tackifier(s) have a Volatile Organic Compound (VOC) value of less than 1000 ppm, when measured by thermogravimetric analysis according to the weight loss test methods described in the experimental section; and d) optionally, a linear block copolymer of the formula L-(G)m, wherein L is a rubbery block comprising a polymerized olefin, a polymerized conjugated diene, a hydrogenated derivative of a polymerized conjugated diene, or any combinations thereof; and wherein m is 1 or 2; wherein the multilayer pressure sensitive adhesive assembly is obtained by hotmelt co-extrusion of the polymeric foam layer and the first pressure sensitive adhesive layer. The present disclosure also relates to a method of manufacturing such a multilayer pressure sensitive adhesive assembly and uses thereof.

    RUBBER-BASED PRESSURE-SENSITIVE ADHESIVE
    8.
    发明申请

    公开(公告)号:US20170313910A1

    公开(公告)日:2017-11-02

    申请号:US15523456

    申请日:2015-11-05

    Abstract: The present disclosure relates to a pressure sensitive adhesive comprising: a) a multi-arm block copolymer of the formula Qn-Y, wherein: (i) Q represents an arm of the multi-arm block copolymer and each arm independently has the formula G-R, (ii) n represents the number of arms and is a whole number of at least 3, and (iii) Y is the residue of a multifunctional coupling agent,  wherein each R is a rubbery block comprising a polymerized conjugated diene, a hydrogenated derivative of a polymerized conjugated diene, or any combinations thereof; and each G is a glassy block comprising a polymerized monovinyl aromatic monomer; b) a polymeric plasticizer having a weight average molecular weight Mw of at least 10,000 g/mol; c) at least one hydrocarbon tackifier, wherein the hydrocarbon tackifier(s) have a Volatile Organic Compound (VOC) value of less than 1000 ppm, when measured by thermogravimetric analysis according to the weight loss test methods described in the experimental section; and d) optionally, a linear block copolymer of the formula L-(G)m, wherein L is a rubbery block comprising a polymerized olefin, a polymerized conjugated diene, a hydrogenated derivative of a polymerized conjugated diene, or any combinations thereof; and wherein m is 1 or 2. The present disclosure also relates to a method of manufacturing such a pressure sensitive adhesive and uses thereof.

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