Process for the synthesis of amine ethers from secondary amino oxides
    1.
    发明申请
    Process for the synthesis of amine ethers from secondary amino oxides 有权
    从仲氨基氧化物合成胺醚的方法

    公开(公告)号:US20050043552A1

    公开(公告)日:2005-02-24

    申请号:US10919776

    申请日:2004-08-17

    摘要: An amine ether of formula A wherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L; E′ is C1-C36 alkyl; C3-C18 alkenyl; C2-C18 alkinyl; C5-C18 cydoalkyl; C5-C18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C2-C7alkyl or C3-C7alkenyl substituted by halogen; C7-C15 aralkyl or C7-C15 aralkyl substituted by C1-C4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C4-C18alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR21 or C(O)—R22; or T′ is C5-C12cycloalkyl; C5-C12 cycloalkyl which is interrupted by at least one O or —NR18—; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR18—; or T′ is —C(G1)(G2)—T″; or C1-C18alkyl or C5-C12cycloalkyl substituted by T″ is hydrogen, halogen, NO2, cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G1 and G2, an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E1—H or H—L—H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.

    摘要翻译: 式A的胺醚,其中a为1或2; 当a为1时,E为E'; 当a为2时,E为L; E'是C 1 -C 36烷基; C3-C18烯基; C2-C18炔基; C5-C18环烷基; C5-C18环烯基; 7-12个碳原子的饱和或不饱和脂族二环或三环烃基团; C 2 -C 7烷基或被卤素取代的C 3 -C 7链烯基; 被C 1 -C 4烷基或苯基取代的C 7 -C 15芳烷基或C 7 -C 15芳烷基; 或E'是如权利要求1所述的式(VII)的基团; T'是叔C4-C18烷基或苯基,其各自为未取代的或被卤素,OH,COOR21或C(O)-R22取代; 或T'为C 5 -C 12环烷基; 被至少一个O或-NR 18 - 中断的C 5 -C 12环烷基; 具有7-18个碳原子的多环烷基或被至少一个O或-NR 18 - 中断的相同基团; 或T'为-C(G1)(G2)-T“; 或被T“取代的C 1 -C 18烷基或C 5 -C 12环烷基是氢,卤素,NO 2,氰基,或是包含1-50个碳原子的一价有机基团; 或T“和T'一起形成二价有机连接基团,与受阻胺氮原子和被G1和G2取代的季碳原子一起形成任选取代的五元或六元环结构; 并且所有其它残基如权利要求1中所定义,通过在有机氢过氧化物和催化量的铜或其盐的存在下与烃E1-H或HLH反应,由相应的N-氧基受阻胺前体以良好的产率获得 铜化合物。 本发明的产品可用作有机材料的聚合调节剂和/或光稳定剂。

    Process for the synthesis of amine ethers from secondary amino oxides

    公开(公告)号:US07402675B2

    公开(公告)日:2008-07-22

    申请号:US10919776

    申请日:2004-08-17

    IPC分类号: C07D211/54

    摘要: An amine ether of formula A wherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L; E′ is C1-C36 alkyl; C3-C18 alkenyl; C2-C18 alkinyl; C5-C18 cycloalkyl; C5-C18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C2-C7alkyl or C3-C7alkenyl substituted by halogen; C7-C15 aralkyl or C7-C15 aralkyl substituted by C1-C4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C4-C18alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR21 or C(O)—R22; or T′ is C5-C12cycloalkyl; C5-C12cycloalkyl which is interrupted by at least one O or —NR18—; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR18—; or T′ is —C(G1)(G2)-T″; or C1-C18alkyl or C5-C12cycloalkyl substituted by T″ is hydrogen, halogen, NO2, cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G1 and G2, an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E1-H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.

    Photoresist compositions
    5.
    发明授权
    Photoresist compositions 有权
    光刻胶组合物

    公开(公告)号:US08507569B2

    公开(公告)日:2013-08-13

    申请号:US13255543

    申请日:2010-03-17

    IPC分类号: H05B6/68 C08G61/04

    摘要: The present invention relates to a radically polymerizable composition comprising a hydroxylamine ester used to manufacture color filters. The invention further relates to novel hydroxylamine esters. The invention further relates to the use of hydroxylamine esters in all liquid crystal display components requiring post-baking. The present invention relates to a radically polymerizable composition comprising: (a) at least one alkaline developable resin; (b) at least one acrylate monomer; (c) at least a photoinitiator; (d) at least one hydroxylamine ester compound of formula (I) wherein Ra represents an acyl radical; one of Rb and Rc represents hydrogen and the other one represents a substituent; or Rb and Rc both represent hydrogen or identical or different substituents; or Rb and Rc together represent oxygen; or Rb and Rc together form a ring; R1-R4 each represent C1-C6 alkyl; and R5 and R6 each represent independently of one another hydrogen, C1-C6 alkyl or C6-C10 aryl; or R5 and R6 together represent oxygen.

    摘要翻译: 本发明涉及一种可自由基聚合的组合物,其包含用于制造滤色器的羟胺酯。 本发明还涉及新的羟胺酯。 本发明还涉及在需要后烘烤的所有液晶显示组件中使用羟胺酯。 本发明涉及可自由基聚合的组合物,其包含:(a)至少一种碱性显影树脂; (b)至少一种丙烯酸酯单体; (c)至少一种光引发剂; (d)至少一种式(I)的羟胺酯化合物,其中R a表示酰基; Rb和Rc之一表示氢,另一个表示取代基; 或Rb和Rc都表示氢或相同或不同的取代基; 或Rb和Rc一起代表氧; 或Rb和Rc一起形成环; R1-R4各自表示C1-C6烷基; R 5和R 6各自独立地表示氢,C 1 -C 6烷基或C 6 -C 10芳基; 或R5和R6一起表示氧。

    Process for the oxidation of secondary amines into the corresponding nitroxides
    6.
    发明授权
    Process for the oxidation of secondary amines into the corresponding nitroxides 有权
    将仲胺氧化成相应的硝基氧的方法

    公开(公告)号:US08134009B2

    公开(公告)日:2012-03-13

    申请号:US12854677

    申请日:2010-08-11

    摘要: The invention relates to a process for the preparation of secondary nitroxide radicals from their corresponding secondary amines by oxidation with an organic peracid, comprising the steps a) adding to a reaction vessel a secondary amine, optionally together with an organic solvent and in one batch a base selected from the group consisting of alkali metal, alkaline earth metal or ammonium bicarbonates and alkaline earth metal or ammonium carbonates or mixtures thereof in the form of a solid together with water or as an aqueous slurry; b) dosing a peracid under stirring to the reaction mixture in an amount of 1.0 to 2.5 mol per mol of secondary amine; and c) isolating the organic phase.

    摘要翻译: 本发明涉及通过用有机过酸氧化从其相应的仲胺制备二级氮氧自由基的方法,包括以下步骤:a)向反应容器中加入仲胺,任选与有机溶剂一起加入一次 碱选自碱金属,碱土金属或碳酸氢铵,碱土金属或铵的碳酸盐或其混合物,其形式为水,或与水相混合; b)在搅拌下将过酸给予反应混合物,其量为每摩尔仲胺为1.0至2.5摩尔; 和c)分离有机相。

    Triazine Containing Electrode Materials for Secondary Batteries
    8.
    发明申请
    Triazine Containing Electrode Materials for Secondary Batteries 审中-公开
    含有二次电池用电极材料的三嗪

    公开(公告)号:US20100233537A1

    公开(公告)日:2010-09-16

    申请号:US12225333

    申请日:2007-03-12

    摘要: The invention relates to a stable secondary battery utilizing as active element the oxidation and reduction cycle of a sterically hindered nitroxide radical, which is bonded to a triazine structural element. Further aspects of the invention are a method for providing such a secondary battery, the use of the respective compounds as active elements in secondary batteries and selected novel nitroxide compounds as such.

    摘要翻译: 本发明涉及一种稳定的二次电池,其利用与三嗪结构元件结合的空间位阻的氮氧自由基的氧化和还原循环作为活性元素。 本发明的另外的方面是提供这种二次电池的方法,各种化合物作为二次电池中的活性元素的用途以及选择的新的氮氧化物化合物。