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公开(公告)号:US08889235B2
公开(公告)日:2014-11-18
申请号:US12772518
申请日:2010-05-03
申请人: Anupama Mallikarjunan , Raymond Nicholas Vrtis , Laura M. Matz , Mark Leonard O'Neill , Andrew David Johnson , Manchao Xiao
发明人: Anupama Mallikarjunan , Raymond Nicholas Vrtis , Laura M. Matz , Mark Leonard O'Neill , Andrew David Johnson , Manchao Xiao
IPC分类号: H05H1/24 , H01L21/02 , H01L21/314 , H01L21/768 , C23C16/36
CPC分类号: C23C16/36 , H01L21/02167 , H01L21/02211 , H01L21/02274 , H01L21/3148 , H01L21/76831 , H01L21/76834
摘要: A process for forming a silicon carbonitride barrier dielectric film between a dielectric film and a metal interconnect of an integrated circuit substrate, comprising the steps of; providing the integrated circuit substrate having a dielectric film; contacting the substrate with a barrier dielectric film precursor comprising: RxR′y(NR″R′″)zSi wherein R, R′, R″ and R′″ are each individually selected from hydrogen, linear or branched saturated or unsaturated alkyl, or aromatic; wherein x÷y+z=4; z=1-3; but R, R′ cannot both be hydrogen; forming the silicon carbonitride barrier dielectric film with C/Si ratio >0.8 and a N/Si ratio >0.2 on the integrated circuit substrate.
摘要翻译: 一种在电介质膜和集成电路基板的金属互连之间形成碳氮化硅阻挡电介质膜的方法,包括以下步骤: 提供具有电介质膜的集成电路基板; 将衬底与阻挡电介质膜前体接触,包括:RxR'y(NR“R”“)zSi其中R,R',R”和R“”各自独立地选自氢,直链或支链饱和或不饱和的烷基,或 芳香; 其中x÷y + z = 4; z = 1-3; 但R,R'不能都是氢; 在集成电路基板上形成C / Si比> 0.8且N / Si比> 0.2的碳氮化硅势垒电介质膜。
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公开(公告)号:US20100291321A1
公开(公告)日:2010-11-18
申请号:US12772518
申请日:2010-05-03
申请人: Anupama Mallikarjunan , Raymond Nicholas Vrtis , Laura M. Matz , Mark Leonard O'Neill , Andrew David Johnson , Manchao Xiao
发明人: Anupama Mallikarjunan , Raymond Nicholas Vrtis , Laura M. Matz , Mark Leonard O'Neill , Andrew David Johnson , Manchao Xiao
IPC分类号: H05H1/24
CPC分类号: C23C16/36 , H01L21/02167 , H01L21/02211 , H01L21/02274 , H01L21/3148 , H01L21/76831 , H01L21/76834
摘要: A process for forming a silicon carbonitride barrier dielectric film between a dielectric film and a metal interconnect of an integrated circuit substrate, comprising the steps of; providing the integrated circuit substrate having a dielectric film; contacting the substrate with a barrier dielectric film precursor comprising: RxR′y(NR″R′″)zSi wherein R, R′, R″ and R′″ are each individually selected from hydrogen, linear or branched saturated or unsaturated alkyl, or aromatic; wherein x÷y+z=4; z=1-3; but R, R′ cannot both be hydrogen; forming the silicon carbonitride barrier dielectric film with C/Si ratio>0.8 and a N/Si ratio>0.2 on the integrated circuit substrate.
摘要翻译: 一种在电介质膜和集成电路基板的金属互连之间形成碳氮化硅阻挡电介质膜的方法,包括以下步骤: 提供具有电介质膜的集成电路基板; 将衬底与阻挡电介质膜前体接触,包括:RxR'y(NR“R”“)zSi其中R,R',R”和R“”各自独立地选自氢,直链或支链饱和或不饱和的烷基,或 芳香; 其中x÷y + z = 4; z = 1-3; 但R,R'不能都是氢; 在集成电路基板上形成C / Si比> 0.8且N / Si比> 0.2的碳氮化硅势垒电介质膜。
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公开(公告)号:US20090096106A1
公开(公告)日:2009-04-16
申请号:US12244426
申请日:2008-10-02
IPC分类号: H01L23/52 , H01L21/311
CPC分类号: H01L21/31144 , C23C16/30 , G03F7/091 , H01L21/02126 , H01L21/0214 , H01L21/02203 , H01L21/02216 , H01L21/02219 , H01L21/02274 , H01L21/02304 , H01L21/0276 , H01L21/31629 , H01L21/31633 , H01L21/318
摘要: A method of forming a feature in a substrate comprising the steps of: forming a dielectric layer on a substrate; forming an antireflective coating over the dielectric layer; forming a photoresist pattern over the antireflective coating; etching the dielectric layer through the patterned photoresist; and removing the antireflective coating and the photoresist, wherein the antireflective coating is a film represented by the formula SivOwCxNuHyFz, wherein v+w+x+u+y+z=100%, v is from 1 to 35 atomic %, w is from 1 to 40 atomic %, x is from 5 to 80 atomic %, u is from 0 to 50 atomic %, y is from 10 to 50 atomic % and z is from 0 to 15 atomic %, wherein the antireflective coating is formed by the chemical vapor deposition of a composition comprising (1) at least one precursor selected from the group consisting of an organosilane, an organosiloxane, and an aminosilane; and (2) a hydrocarbon, and wherein the hydrocarbon is substantially not removed from the antireflective coating.
摘要翻译: 一种在衬底中形成特征的方法,包括以下步骤:在衬底上形成电介质层; 在电介质层上形成抗反射涂层; 在抗反射涂层上形成光致抗蚀剂图案; 通过图案化的光致抗蚀剂蚀刻介电层; 并且去除抗反射涂层和光致抗蚀剂,其中抗反射涂层是由式SivOwCxNuHyFz表示的膜,其中v + w + x + u + y + z = 100%,v为1至35原子%,w为 1至40原子%,x为5至80原子%,u为0至50原子%,y为10至50原子%,z为0至15原子%,其中抗反射涂层由 组合物的化学气相沉积,其包含(1)至少一种选自有机硅烷,有机硅氧烷和氨基硅烷的前体; 和(2)烃,其中烃基本上不从抗反射涂层中除去。
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公开(公告)号:US20090095346A1
公开(公告)日:2009-04-16
申请号:US12244455
申请日:2008-10-02
申请人: Patrick Timothy Hurley , Robert Gordon Ridgeway , Raymond Nicholas Vrtis , Mark Leonard O'Neill , Andrew David Johnson
发明人: Patrick Timothy Hurley , Robert Gordon Ridgeway , Raymond Nicholas Vrtis , Mark Leonard O'Neill , Andrew David Johnson
CPC分类号: C23C16/30 , H01L21/3148 , H01L31/02168 , H01L31/0236 , H01L31/02363 , H01L31/18 , Y02E10/50 , Y02E10/547
摘要: A process is provided for making a photovoltaic device comprising a silicon substrate comprising a p-n junction, the process comprising the steps of: forming an amorphous silicon carbide antireflective coating over at least one surface of the silicon substrate by chemical vapor deposition of a composition comprising a precursor selected from the group consisting of an organosilane, an aminosilane, and mixtures thereof, wherein the amorphous silicon carbide antireflective coating is a film represented by the formula SivCxNuHyFz, wherein v+x+u+y+z=100%, v is from 1 to 35 atomic %, x is from 5 to 80 atomic %, u is from 0 to 50 atomic %, y is from 10 to 50 atomic % and z is from 0 to 15 atomic %.
摘要翻译: 提供了一种用于制造包括包括pn结的硅衬底的光伏器件的方法,该方法包括以下步骤:通过化学气相沉积在含硅化合物的组合物的化学气相沉积中在硅衬底的至少一个表面上形成非晶碳化硅抗反射涂层 选自有机硅烷,氨基硅烷及其混合物的前体,其中非晶碳化硅抗反射涂层是由式SivCxNuHyFz表示的膜,其中v + x + u + y + z = 100%,v来自 1〜35原子%,x为5〜80原子%,u为0〜50原子%,y为10〜50原子%,z为0〜15原子%。
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公开(公告)号:US08987039B2
公开(公告)日:2015-03-24
申请号:US12244455
申请日:2008-10-02
申请人: Patrick Timothy Hurley , Robert Gordon Ridgeway , Raymond Nicholas Vrtis , Mark Leonard O'Neill , Andrew David Johnson
发明人: Patrick Timothy Hurley , Robert Gordon Ridgeway , Raymond Nicholas Vrtis , Mark Leonard O'Neill , Andrew David Johnson
IPC分类号: H01L31/18 , C23C16/30 , H01L21/314 , H01L31/0216 , H01L31/0236 , H01L31/04
CPC分类号: C23C16/30 , H01L21/3148 , H01L31/02168 , H01L31/0236 , H01L31/02363 , H01L31/18 , Y02E10/50 , Y02E10/547
摘要: A process is provided for making a photovoltaic device comprising a silicon substrate comprising a p-n junction, the process comprising the steps of: forming an amorphous silicon carbide antireflective coating over at least one surface of the silicon substrate by chemical vapor deposition of a composition comprising a precursor selected from the group consisting of an organosilane, an aminosilane, and mixtures thereof, wherein the amorphous silicon carbide antireflective coating is a film represented by the formula SivCxNuHyFz, wherein v+x+u+y+z=100%, v is from 1 to 35 atomic %, x is from 5 to 80 atomic %, u is from 0 to 50 atomic %, y is from 10 to 50 atomic % and z is from 0 to 15 atomic %.
摘要翻译: 提供了一种用于制造包括包括pn结的硅衬底的光伏器件的方法,该方法包括以下步骤:通过化学气相沉积在含硅化合物的组合物的化学气相沉积中在硅衬底的至少一个表面上形成非晶碳化硅抗反射涂层 选自有机硅烷,氨基硅烷及其混合物的前体,其中非晶碳化硅抗反射涂层是由式SivCxNuHyFz表示的膜,其中v + x + u + y + z = 100%,v来自 1〜35原子%,x为5〜80原子%,u为0〜50原子%,y为10〜50原子%,z为0〜15原子%。
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公开(公告)号:US07581549B2
公开(公告)日:2009-09-01
申请号:US11178545
申请日:2005-07-12
申请人: Andrew David Johnson , Hoshang Subawalla , Bing Ji , Raymond Nicholas Vrtis , Eugene Joseph Karwacki, Jr. , Robert Gordon Ridgeway , Peter James Maroulis , Mark Leonard O'Neill , Aaron Scott Lukas , Stephen Andrew Motika
发明人: Andrew David Johnson , Hoshang Subawalla , Bing Ji , Raymond Nicholas Vrtis , Eugene Joseph Karwacki, Jr. , Robert Gordon Ridgeway , Peter James Maroulis , Mark Leonard O'Neill , Aaron Scott Lukas , Stephen Andrew Motika
CPC分类号: C23C16/4405
摘要: A process for removing carbon-containing residues from a substrate is described herein. In one aspect, there is provided a process for removing carbon-containing residue from at least a portion of a surface of a substrate comprising: providing a process gas comprising an oxygen source, a fluorine source, an and optionally additive gas wherein the molar ratio of oxygen to fluorine contained within the process gas ranges from about 1 to about 10; activating the process gas using at least one energy source to provide reactive species; and contacting the surface of the substrate with the reactive species to volatilize and remove the carbon-containing residue from the surface.
摘要翻译: 本文描述了用于从基底去除含碳残留物的方法。 一方面,提供了从基材表面的至少一部分去除含碳残余物的方法,其包括:提供包含氧源,氟源和任选添加气体的工艺气体,其中摩尔比 在工艺气体中所含的氧与氟的含量范围为约1至约10; 使用至少一个能量源来激活所述工艺气体以提供反应性物质; 并使基材的表面与反应性物质接触,从表面挥发并除去含碳残渣。
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公开(公告)号:US20100022095A1
公开(公告)日:2010-01-28
申请号:US12360588
申请日:2009-01-27
IPC分类号: H01L21/3065 , H01L21/302 , H01L21/306 , C01B23/00
CPC分类号: B08B7/0035 , C23C16/4405 , C23F4/00 , H01L21/32135 , H01L21/32136 , H01L21/67028
摘要: This invention relates to a process for selective removal of materials, such as: silicon, molybdenum, tungsten, titanium, zirconium, hafnium, vanadium, tantalum, niobium, boron, phosphorus, germanium, arsenic, and mixtures thereof, from silicon dioxide, silicon nitride, nickel, aluminum, TiNi alloy, photoresist, phosphosilicate glass, boron phosphosilicate glass, polyimides, gold, copper, platinum, chromium, aluminum oxide, silicon carbide and mixtures thereof. The process is related to the important applications in the cleaning or etching process for semiconductor deposition chambers and semiconductor tools, devices in a micro electro mechanical system (MEMS), and ion implantation systems. Methods of forming XeF2 by reacting Xe with a fluorine containing chemical are also provided, where the fluorine containing chemical is selected from the group consisting of F2, NF3, C2F6, CF4, C3F8, SF6, a plasma containing F atoms generated from an upstream plasma generator and mixtures thereof.
摘要翻译: 本发明涉及从二氧化硅,硅,硅,钼,钨,钨,钛,锆,铪,钒,钽,铌,硼,磷,锗,砷及其混合物中选择性地去除材料的方法 氮化物,镍,铝,TiNi合金,光致抗蚀剂,磷硅酸盐玻璃,硼磷硅酸盐玻璃,聚酰亚胺,金,铜,铂,铬,氧化铝,碳化硅及其混合物。 该过程涉及用于半导体沉积室和半导体工具,微机电系统(MEMS)中的器件和离子注入系统的清洁或蚀刻工艺中的重要应用。 还提供了通过使Xe与含氟化合物反应形成XeF 2的方法,其中含氟化学物质选自由F2,NF3,C2F6,CF4,C3F8,SF6组成的组,含有从上游等离子体产生的F原子的等离子体 发电机及其混合物。
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公开(公告)号:US08278222B2
公开(公告)日:2012-10-02
申请号:US12360588
申请日:2009-01-27
IPC分类号: H01L21/302 , H01L21/461
CPC分类号: B08B7/0035 , C23C16/4405 , C23F4/00 , H01L21/32135 , H01L21/32136 , H01L21/67028
摘要: This invention relates to a process for selective removal of materials, such as: silicon, molybdenum, tungsten, titanium, zirconium, hafnium, vanadium, tantalum, niobium, boron, phosphorus, germanium, arsenic, and mixtures thereof, from silicon dioxide, silicon nitride, nickel, aluminum, TiNi alloy, photoresist, phosphosilicate glass, boron phosphosilicate glass, polyimides, gold, copper, platinum, chromium, aluminum oxide, silicon carbide and mixtures thereof. The process is related to the important applications in the cleaning or etching process for semiconductor deposition chambers and semiconductor tools, devices in a micro electro mechanical system (MEMS), and ion implantation systems. Methods of forming XeF2 by reacting Xe with a fluorine containing chemical are also provided, where the fluorine containing chemical is selected from the group consisting of F2, NF3, C2F6, CF4, C3F8, SF6, a plasma containing F atoms generated from an upstream plasma generator and mixtures thereof.
摘要翻译: 本发明涉及从二氧化硅,硅,硅,钼,钨,钨,钛,锆,铪,钒,钽,铌,硼,磷,锗,砷及其混合物中选择性地去除材料的方法 氮化物,镍,铝,TiNi合金,光致抗蚀剂,磷硅酸盐玻璃,硼磷硅酸盐玻璃,聚酰亚胺,金,铜,铂,铬,氧化铝,碳化硅及其混合物。 该过程涉及用于半导体沉积室和半导体工具,微机电系统(MEMS)中的器件和离子注入系统的清洁或蚀刻工艺中的重要应用。 还提供了通过使Xe与含氟化合物反应形成XeF 2的方法,其中含氟化学物质选自由F2,NF3,C2F6,CF4,C3F8,SF6组成的组,含有从上游等离子体产生的F原子的等离子体 发电机及其混合物。
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公开(公告)号:US20100120262A1
公开(公告)日:2010-05-13
申请号:US12609542
申请日:2009-10-30
申请人: Vasil Vorsa , Andrew David Johnson , Manchao Xiao
发明人: Vasil Vorsa , Andrew David Johnson , Manchao Xiao
IPC分类号: H01L21/318
CPC分类号: H01L21/02219 , C23C16/345 , C23C16/36 , H01L21/0217 , H01L21/02274
摘要: The present invention is a method to increase the intrinsic compressive stress in plasma enhanced chemical vapor deposition (PECVD) silicon nitride (SiN) and silicon carbonitride (SiCN) thin films, comprising depositing the film from an amino vinylsilane-based precursor. More specifically the present invention uses the amino vinylsilane-based precursor selected from the formula: [RR1N]xSiR3y(R2)z, where x+y+z=4, x=1-3, y=0-2, and z=1-3; R, R1 and R3 can be hydrogen, C1 to C10 alkane, alkene, or C4 to C12 aromatic; each R2 is a vinyl, allyl or vinyl-containing functional group.
摘要翻译: 本发明是增加等离子体增强化学气相沉积(PECVD)氮化硅(SiN)和碳氮化硅(SiCN)薄膜中的固有压应力的方法,包括从氨基乙烯基硅烷前体沉积膜。 更具体地说,本发明使用选自下式的氨基乙烯基硅烷基前体:[RR1N] xSiR3y(R2)z,其中x + y + z = 4,x = 1-3,y = 0-2,z = 1-3; R,R 1和R 3可以是氢,C 1至C 10烷烃,烯烃或C 4至C 12芳族; 每个R 2是乙烯基,烯丙基或含乙烯基的官能团。
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公开(公告)号:US08580993B2
公开(公告)日:2013-11-12
申请号:US12609542
申请日:2009-10-30
申请人: Vasil Vorsa , Andrew David Johnson , Manchao Xiao
发明人: Vasil Vorsa , Andrew David Johnson , Manchao Xiao
IPC分类号: C07F7/10
CPC分类号: H01L21/02219 , C23C16/345 , C23C16/36 , H01L21/0217 , H01L21/02274
摘要: The present invention is a method to increase the intrinsic compressive stress in plasma enhanced chemical vapor deposition (PECVD) silicon nitride (SiN) and silicon carbonitride (SiCN) thin films, comprising depositing the film from an amino vinylsilane-based precursor. More specifically the present invention uses the amino vinylsilane-based precursor selected from the formula: [RR1N]xSiR3y(R2)z, where x+y+z=4, x=1-3, y=0-2, and z=1-3; R, R1 and R3 can be hydrogen, C1 to C10 alkane, alkene, or C4 to C12 aromatic; each R2 is a vinyl, allyl or vinyl-containing functional group.
摘要翻译: 本发明是增加等离子体增强化学气相沉积(PECVD)氮化硅(SiN)和碳氮化硅(SiCN)薄膜中的固有压应力的方法,包括从氨基乙烯基硅烷前体沉积膜。 更具体地说,本发明使用选自下式的氨基乙烯基硅烷基前体:[RR1N] xSiR3y(R2)z,其中x + y + z = 4,x = 1-3,y = 0-2,z = 1-3; R,R 1和R 3可以是氢,C 1至C 10烷烃,烯烃或C 4至C 12芳族; 每个R 2是乙烯基,烯丙基或含乙烯基的官能团。
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