公开(公告)号：US20240087955A1

公开(公告)日：2024-03-14

申请号：US18241343

申请日：2023-09-01

申请人： Applied Materials, Inc.

发明人： Yi XU ,  Xianyuan ZHAO ,  Zhimin QI ,  Aixi ZHANG ,  Geraldine VASQUEZ ,  Dien-Yeh WU ,  Wei LEI ,  Xingyao GAO ,  Shirish PETHE ,  Wenting HOU ,  Chao DU ,  Tsung-Han YANG ,  Kyoung-Ho BU ,  Chen-Han LIN ,  Jallepally RAVI ,  Yu LEI ,  Rongjun WANG ,  Xianmin TANG

IPC分类号： H01L21/768

CPC分类号： H01L21/76879 ,  H01L21/76843 ,  H01L21/76856 ,  H01L21/76876

摘要： A method and apparatus for forming tungsten features in semiconductor devices is provided. The method includes exposing a top opening of a feature formed in a substrate to a physical vapor deposition (PVD) process to deposit a tungsten liner layer within the feature. The PVD process is performed in a first processing region of a first processing chamber and the tungsten liner layer forms an overhang portion, which partially obstructs the top opening of the feature. The substrate is transferred from the first processing region of the first processing chamber to a second processing region of a second processing chamber without breaking vacuum. The overhang portion is exposed to nitrogen-containing radicals in the second processing region to inhibit subsequent growth of tungsten along the overhang portion. The feature is exposed to a tungsten-containing precursor gas to form a tungsten fill layer over the tungsten liner layer within the feature.

公开(公告)号：US20240018648A1

公开(公告)日：2024-01-18

申请号：US18220408

申请日：2023-07-11

申请人： Applied Materials, Inc.

发明人： Geraldine VASQUEZ ,  Yi XU ,  Dien-yeh WU ,  Aixi ZHANG ,  Jallepally RAVI ,  Yu LEI

IPC分类号： C23C16/44 ,  H01J37/32 ,  C23C16/458

CPC分类号： C23C16/4408 ,  H01J37/32798 ,  C23C16/4586 ,  H01J2237/3321

摘要： Embodiments of a purge ring for use in a process chamber are provided herein. In some embodiments, a purge ring includes: an annular body having an inner portion and an outer portion, wherein the inner portion includes an inner surface of the annular body, the inner surface comprising a first inner sidewall, a second inner sidewall, and a third inner sidewall, wherein the inner portion has an upper inner notch that defines the first inner sidewall and a lower inner notch that defines the second inner sidewall, wherein a third inner sidewall is disposed between the first inner sidewall and the second inner sidewall, and wherein the first inner sidewall and the second inner sidewall are disposed radially outward of the third inner sidewall.

公开(公告)号：US20240194527A1

公开(公告)日：2024-06-13

申请号：US18197846

申请日：2023-05-16

申请人： Applied Materials, Inc.

发明人： Sahil Jaykumar PATEL ,  Xianyuan ZHAO ,  Wei LEI ,  Aixi ZHANG ,  Yi XU ,  Yu LEI

IPC分类号： H01L21/768 ,  H01L23/532

CPC分类号： H01L21/76877 ,  H01L21/76843 ,  H01L21/76855 ,  H01L23/53266

摘要： Methods and apparatus for processing a substrate are provided. In some embodiments, a method includes depositing an amorphous interlayer atop a first layer on a substrate, wherein the first layer is a metal-containing layer, and depositing a metal layer atop the amorphous interlayer.

公开(公告)号：US20230343643A1

公开(公告)日：2023-10-26

申请号：US17868475

申请日：2022-07-19

申请人： Applied Materials, Inc.

发明人： Chih-Hsun HSU ,  Shiyu YUE ,  Wei LEI ,  Yi XU ,  Jiang LU ,  Yu LEI ,  Ziye XIONG ,  Tsung-Han YANG ,  Zhimin QI ,  Aixi ZHANG ,  Jie ZHANG ,  Liqi WU ,  Rongjun WANG ,  Shihchung CHEN ,  Meng-Shan WU ,  Chun-Chieh WANG ,  Annamalai LAKSHMANAN ,  Yixiong YANG ,  Xianmin TANG

IPC分类号： H01L21/768 ,  H01L23/522

CPC分类号： H01L21/76877 ,  H01L21/76876 ,  H01L21/76843 ,  H01L21/76865 ,  H01L23/5226 ,  H01L21/76826

摘要： A method and apparatus for a gap-fill in semiconductor devices are provided. The method includes forming a metal seed layer on an exposed surface of the substrate, wherein the substrate has features in the form of trenches or vias formed in a top surface of the substrate, the features having sidewalls and a bottom surface extending between the sidewalls. A gradient oxidation process is performed to oxidize exposed portions of the metal seed layer to form a metal oxide, wherein the gradient oxidation process preferentially oxidizes a field region of the substrate over the bottom surface of the features. An etch back process removes or reduces the oxidized portion of the seed layer. A metal gap-fill process fills or partially fills the features with a gap fill material.

公开(公告)号：US20230326791A1

公开(公告)日：2023-10-12

申请号：US17718242

申请日：2022-04-11

申请人： Applied Materials, Inc.

发明人： Zhimin QI ,  Yi XU ,  Shirish A. PETHE ,  Xingyao GAO ,  Shiyu YUE ,  Aixi ZHANG ,  Wei LEI ,  Yu LEI ,  Geraldine VASQUEZ ,  Dien-yeh WU ,  Da HE

IPC分类号： H01L21/768 ,  H01L21/285 ,  C23C14/18 ,  C23C16/14

CPC分类号： H01L21/76879 ,  H01L21/2855 ,  H01L21/28562 ,  H01L21/28568 ,  C23C14/18 ,  C23C16/14

摘要： Embodiments of methods and associated apparatus for filling a feature in a substrate are provided herein. In some embodiments, a method of depositing tungsten in features of a substrate includes: depositing a seed layer consisting essentially of tungsten in the features via a physical vapor deposition (PVD) process; and depositing a bulk layer consisting essentially of tungsten in the features via a chemical vapor deposition (CVD) process to fill the features such that the deposition of the bulk layer is selective to within the features as compared to a field region of the substrate, wherein the CVD process is performed by flowing hydrogen gas (H2) at a first flow rate and a tungsten precursor at a second flow rate, and wherein the first flow rate is less than the second flow rate.

公开(公告)号：US20240178062A1

公开(公告)日：2024-05-30

申请号：US18083075

申请日：2022-12-16

申请人： Applied Materials, Inc.

发明人： Yi XU ,  Yu LEI ,  Aixi ZHANG ,  Rongjun WANG

IPC分类号： H01L21/768 ,  H01L21/285

CPC分类号： H01L21/76877 ,  H01L21/28556

摘要： A method of gap fill may include depositing a sacrificial Si layer in an opening of a feature and on a field of a substrate. In addition, the method may include depositing a metal layer in the opening and on the field, where at least a portion of the sacrificial Si layer is replaced with the metal layer. The method may also include depositing a metal gapfill material in the opening and on the field directly over the metal layer, where the metal gapfill material completely fills the opening.

公开(公告)号：US20240088071A1

公开(公告)日：2024-03-14

申请号：US17944596

申请日：2022-09-14

申请人： Applied Materials, Inc.

发明人： Yi XU ,  Yu LEI ,  Zhimin QI ,  Aixi ZHANG ,  Xianyuan ZHAO ,  Wei LEI ,  Xingyao GAO ,  Shirish A. PETHE ,  Tao HUANG ,  Xiang CHANG ,  Patrick Po-Chun LI ,  Geraldine VASQUEZ ,  Dien-yeh WU ,  Rongjun WANG

IPC分类号： H01L23/00

CPC分类号： H01L24/03 ,  H01L24/05 ,  H01L2224/03452 ,  H01L2224/03845 ,  H01L2224/05026 ,  H01L2224/05082 ,  H01L2224/05157 ,  H01L2224/05184 ,  H01L2924/01027 ,  H01L2924/01074 ,  H01L2924/04941 ,  H01L2924/0496 ,  H01L2924/059 ,  H01L2924/35121

摘要： Methods for reducing resistivity of metal gapfill include depositing a conformal layer in an opening of a feature and on a field of a substrate with a first thickness of the conformal layer of approximately 10 microns or less, depositing a non-conformal metal layer directly on the conformal layer at a bottom of the opening and directly on the field using an anisotropic deposition process. A second thickness of the non-conformal metal layer on the field and on the bottom of the feature is approximately 30 microns or greater. And depositing a metal gapfill material in the opening of the feature and on the field where the metal gapfill material completely fills the opening without any voids.

公开(公告)号：US20240014072A1

公开(公告)日：2024-01-11

申请号：US18212352

申请日：2023-06-21

申请人： Applied Materials, Inc.

发明人： Tsung-Han YANG ,  Zhimin QI ,  Yongqian GAO ,  Rongjun WANG ,  Yi XU ,  Yu LEI ,  Xingyao GAO ,  Chih-Hsun HSU ,  Xi CEN ,  Wei LEI ,  Shiyu YUE ,  Aixi ZHANG ,  Kai WU ,  Xianmin TANG

IPC分类号： H01L21/768 ,  H01J37/32

CPC分类号： H01L21/76879 ,  H01J37/32449 ,  H01J37/32816 ,  H01J37/32422 ,  H01J2237/2001 ,  H01J37/321 ,  H01J2237/332

摘要： A method of forming a semiconductor device structure includes forming a nucleation layer within at least one feature. The method includes exposing the nucleation layer to a nitrogen plasma treatment. The nitrogen plasma treatment preferentially treats the top field and sidewalls while leaving the bottom surface substantially untreated to encourage bottom up metal growth.

公开(公告)号：US20230420295A1

公开(公告)日：2023-12-28

申请号：US18133102

申请日：2023-04-11

申请人： Applied Materials, Inc.

发明人： Tsung-Han YANG ,  Xingyao GAO ,  Shiyu YUE ,  Chih-Hsun HSU ,  Shirish PETHE ,  Rongjun WANG ,  Yi XU ,  Wei LEI ,  Yu LEI ,  Aixi ZHANG ,  Xianyuan ZHAO ,  Zhimin QI ,  Jiang LU ,  Xianmin TANG

IPC分类号： H01L21/768 ,  H01L21/285 ,  H01J37/32

CPC分类号： H01L21/76877 ,  H01L21/76876 ,  H01L21/76865 ,  H01L21/2855 ,  H01J2237/338 ,  H01L21/76856 ,  H01L21/76861 ,  H01J37/32899 ,  H01L21/76843

摘要： A method and apparatus for tungsten gap-fill in semiconductor devices are provided. The method includes performing a gradient oxidation process to oxidize exposed portions of a liner layer, wherein the gradient oxidation process preferentially oxidizes an overhang portion of the liner layer, which obstructs or blocks top openings of one or more features formed within a field region of a substrate. The method further includes performing an etchback process to remove or reduce the oxidized overhang portion of the liner layer, exposing the liner layer to a chemical vapor transport (CVT) process to remove metal oxide remaining from the gradient oxidation process and the etchback process, and performing a tungsten gap-fill process to fill or partially fill the one or more features.