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公开(公告)号:US20240234131A1
公开(公告)日:2024-07-11
申请号:US18584540
申请日:2024-02-22
Applicant: Applied Materials, Inc.
Inventor: Purvam Dineshbhai Modi , Bhargav S. Citla , Srinivas D. Nemani , Ellie Y. Yieh
IPC: H01L21/02 , H01J37/32 , H01L21/3065 , H01L21/311
CPC classification number: H01L21/02274 , H01J37/32146 , H01L21/3065 , H01L21/31116 , H01J2237/332 , H01J2237/334
Abstract: Exemplary processing methods may include providing a silicon-containing precursor to a processing region of a semiconductor processing chamber. A substrate may be housed in the processing region. The substrate may define a feature. The methods may include forming plasma effluents of the silicon-containing precursor. The methods may include depositing a silicon-containing material on the substrate. The methods may include providing an oxygen-containing precursor to the processing region, forming plasma effluents of the oxygen-containing precursor, and contacting the silicon-containing material with the plasma effluents of the oxygen-containing precursor to form a silicon-and-oxygen-containing material. The methods may include providing a fluorine-containing precursor to the processing region, forming plasma effluents of the fluorine-containing precursor, and etching the silicon-and-oxygen-containing material from a top, a sidewall, or both of the feature with the plasma effluents of the fluorine-containing precursor.
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公开(公告)号:US20240234128A1
公开(公告)日:2024-07-11
申请号:US18095279
申请日:2023-01-10
Applicant: Applied Materials, Inc.
Inventor: Taiki Hatakeyama , Bhargav S. Citla , Qiang Ma , Biao Liu , Srinivas D. Nemani
IPC: H01L21/02 , H01J37/32 , H01L21/311
CPC classification number: H01L21/02167 , H01J37/32146 , H01L21/02274 , H01L21/0228 , H01L21/31116 , H01J2237/334
Abstract: Exemplary processing methods may include providing a silicon-containing precursor and a carbon-containing precursor to a processing region of a semiconductor processing chamber. A substrate may be housed in the processing region. The substrate may define a feature within the substrate. The methods may include forming plasma effluents of the silicon-containing precursor and the carbon-containing precursor. The methods may include depositing a silicon-and-carbon-containing material on the substrate. The methods may include providing a hydrogen-containing precursor to the processing region of the semiconductor processing chamber, forming plasma effluents of the hydrogen-containing precursor, and etching the silicon-and-carbon-containing material from a sidewall of the feature within the substrate. The methods may include providing a nitrogen-containing precursor to the processing region of the semiconductor processing chamber, forming plasma effluents of the nitrogen-containing precursor, and doping the silicon-and-carbon-containing material with nitrogen.
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公开(公告)号:US20250022704A1
公开(公告)日:2025-01-16
申请号:US18221240
申请日:2023-07-12
Applicant: Applied Materials, Inc.
Inventor: Qiang Ma , Biao Liu , Bhargav S. Citla , Srinivas D. Nemani , Ellie Y. Yieh , Taiki Hatakeyama , Shreyas Shukla , Mei-Yee Shek
IPC: H01L21/02 , H01J37/32 , H01L21/311
Abstract: Exemplary processing methods may include providing a silicon-containing precursor to a processing region of a semiconductor processing chamber. A substrate may be housed in the processing region. The substrate may define a feature. The methods may include forming plasma effluents of the silicon-containing precursor. The methods may include depositing a silicon-containing material on the substrate. The methods may include providing an oxygen-containing precursor to the processing region, forming plasma effluents of the oxygen-containing precursor, and contacting the silicon-containing material with the plasma effluents of the oxygen-containing precursor to form a silicon-and-oxygen-containing material. The methods may include providing a fluorine-containing precursor to the processing region, forming plasma effluents of the fluorine-containing precursor, and etching the silicon-and-oxygen-containing material from a top, a sidewall, or both of the feature with the plasma effluents of the fluorine-containing precursor.
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公开(公告)号:US20230377875A1
公开(公告)日:2023-11-23
申请号:US18229285
申请日:2023-08-02
Applicant: Applied Materials, Inc.
Inventor: Bhargav S. Citla , Soham Asrani , Joshua Rubnitz , Srinivas D. Nemani , Ellie Y. Yieh
IPC: H01L21/02 , H01L21/3065 , H01J37/32 , H01L21/311
CPC classification number: H01L21/02274 , H01L21/3065 , H01J37/32146 , H01L21/31116 , H01J2237/332 , H01J2237/334
Abstract: Exemplary processing methods may include forming a plasma of a silicon-containing precursor. The methods may include depositing a flowable film on a semiconductor substrate with plasma effluents of the silicon-containing precursor. The processing region may be at least partially defined between a faceplate and a substrate support on which the semiconductor substrate is seated. A bias power may be applied to the substrate support from a bias power source. The methods may include forming a plasma of a hydrogen-containing precursor within the processing region of the semiconductor processing chamber. The methods may include etching the flowable film from a sidewall of the feature within the semiconductor substrate with plasma effluents of the hydrogen-containing precursor. The methods may include densifying remaining flowable film within the feature defined within the semiconductor substrate with plasma effluents of the hydrogen-containing precursor.
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公开(公告)号:US11566325B2
公开(公告)日:2023-01-31
申请号:US17120494
申请日:2020-12-14
Applicant: Applied Materials, Inc.
Inventor: Mei-Yee Shek , Bhargav S. Citla , Joshua Rubnitz , Jethro Tannos , Chentsau Chris Ying , Srinivas D. Nemani , Ellie Y. Yieh
IPC: C23C16/36 , C01B21/082 , C23C16/44 , C23C16/50 , C09D1/00
Abstract: Methods for plasma enhanced chemical vapor deposition (PECVD) of silicon carbonitride films are described. A flowable silicon carbonitride film is formed on a substrate surface by exposing the substrate surface to a precursor and a reactant, the precursor having a structure of general formula (I) or general formula (II) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, and R12 are independently selected from hydrogen (H), substituted or unsubstituted alkyl, substituted or unsubstituted alkoxy, substituted or unsubstituted vinyl, silane, substituted or unsubstituted amine, or halide; purging the processing chamber of the silicon precursor, and then exposing the substrate to an ammonia plasma.
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公开(公告)号:US11049731B2
公开(公告)日:2021-06-29
申请号:US16586806
申请日:2019-09-27
Applicant: Applied Materials, Inc.
Inventor: Erica Chen , Chentsau Chris Ying , Bhargav S. Citla , Jethro Tannos , Matthew August Mattson
IPC: H01L21/322 , H01L21/425 , H01L21/02
Abstract: A method of converting films is disclosed. A method of modifying films is also disclosed. Some methods advantageously convert films from a first elemental composition to a second elemental composition. Some methods advantageously modify film properties without modifying film composition.
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公开(公告)号:US20210189555A1
公开(公告)日:2021-06-24
申请号:US17120494
申请日:2020-12-14
Applicant: Applied Materials, Inc.
Inventor: Mei-Yee Shek , Bhargav S. Citla , Joshua Rubnitz , Jethro Tannos , Chentsau Chris Ying , Srinivas D. Nemani , Ellie Y. Yieh
IPC: C23C16/36 , C01B21/082 , C09D1/00 , C23C16/50 , C23C16/44
Abstract: Methods for plasma enhanced chemical vapor deposition (PECVD) of silicon carbonitride films are described. A flowable silicon carbonitride film is formed on a substrate surface by exposing the substrate surface to a precursor and a reactant, the precursor having a structure of general formula (I) or general formula (II) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, and R12 are independently selected from hydrogen (H), substituted or unsubstituted alkyl, substituted or unsubstituted alkoxy, substituted or unsubstituted vinyl, silane, substituted or unsubstituted amine, or halide; purging the processing chamber of the silicon precursor, and then exposing the substrate to an ammonia plasma.
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公开(公告)号:US10950429B2
公开(公告)日:2021-03-16
申请号:US16396167
申请日:2019-04-26
Applicant: Applied Materials, Inc.
Inventor: Bhargav S. Citla , Mei-Yee Shek , Srinivas D. Nemani
IPC: H01L21/02 , H01L21/033 , C23C14/06 , C23C14/02 , C23C14/35
Abstract: Embodiments described herein provide for post deposition anneal of a substrate, having an amorphous carbon layer deposited thereon, to desirably reduce variations in local stresses thereacross. In one embodiment, a method of processing a substrate includes positioning a substrate, having an amorphous carbon layer deposited thereon, in a first processing volume, flowing an anneal gas into the first processing volume, heating the substrate to an anneal temperature of not more than about 450° C., and maintaining the substrate at the anneal temperature for about 30 seconds or more. Herein, the amorphous carbon layer was deposited on the substrate using a method which included positioning the substrate on a substrate support disposed in a second processing volume, flowing a processing gas into the second processing volume, applying pulsed DC power to a carbon target disposed in the second processing volume, forming a plasma of the processing gas, and depositing the amorphous carbon layer on the substrate.
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公开(公告)号:US11972943B2
公开(公告)日:2024-04-30
申请号:US16578050
申请日:2019-09-20
Applicant: APPLIED MATERIALS, INC.
Inventor: Bhargav S. Citla , Jethro Tannos , Srinivas D Nemani , Joshua Rubnitz
IPC: H01L21/02 , C23C16/455 , H01J37/32
CPC classification number: H01L21/02274 , C23C16/45536 , H01J37/321 , H01L21/02164
Abstract: Methods and apparatus for depositing a dielectric material include: providing a first gas mixture into a processing chamber having a substrate disposed therein; forming a first remote plasma comprising first radicals in a remote plasma source and delivering the first radicals to an interior processing region in the processing chamber to form a layer of dielectric material in an opening in a material layer disposed on the substrate in a presence of the first gas mixture and the first radicals; terminating the first remote plasma and applying a first RF bias power to the processing chamber to form a first bias plasma; contacting the layer of dielectric material with the first bias plasma to form a first treated layer of dielectric material; and subsequently forming a second remote plasma comprising second radicals in the remote plasma source and delivering the second radicals to the interior processing region in the processing chamber in a presence of a second gas mixture while applying a second RF bias power to the processing chamber to form a second bias plasma, wherein the second radicals and second bias plasma contact the first treated layer of dielectric material to increase a hydrophobicity or a viscosity of the first treated layer of dielectric material.
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公开(公告)号:US20240038527A1
公开(公告)日:2024-02-01
申请号:US17873597
申请日:2022-07-26
Applicant: Applied Materials, Inc.
Inventor: Bhargav S. Citla , Srinivas D. Nemani , Purvam Modi , Ellie Y. Yieh
IPC: H01L21/02 , H01L21/321 , H01L21/3065
CPC classification number: H01L21/02274 , H01L21/3211 , H01L21/3065 , H01L21/02126
Abstract: A method includes depositing a flowable film on a substrate by providing a first input flow, the first input flow including plasma effluents of a first precursor, removing a portion of the flowable film from a sidewall of a feature defined within the substrate to obtain a remaining portion of the flowable film by providing a second input flow, the second input flow including plasma effluents of a second precursor, reducing hydrogen content of the remaining portion of the flowable film to obtain a densified film by providing a third input flow, the third input flow including plasma effluents of a third precursor, and treating the densified film in accordance with a film treatment process.
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