Grain Structure Engineering for Metal Gapfill Materials

    公开(公告)号:US20250038137A1

    公开(公告)日:2025-01-30

    申请号:US18225286

    申请日:2023-07-24

    Abstract: A method for depositing copper onto a substrate includes grain engineering to control the internal structure of the copper. In some embodiments, the method comprises depositing a grain control layer conformally onto a copper seed layer in a structure on the substrate where the grain control layer is a non-conducting material, etching the grain control layer using a direct deep reactive ion etch (DRIE) process to remove portions of the grain control layer on horizontal surfaces within the structure, and depositing a copper material onto the structure such that at least one grain parameter of the copper material is controlled, at least in part, by a remaining portion of the grain control layer on vertical surfaces of the structure. In some embodiments, the deposited copper material in the structure has a grain orientation normal to a horizontal surface of the structure.

    METHODS TO SYNTHESIZE SINGLE SOURCE PRECURSORS AND METHODS TO DEPOSIT NANOWIRE BASED THIN FILMS FOR HIGH EFFICIENCY THERMOELECTRIC DEVICES
    6.
    发明申请
    METHODS TO SYNTHESIZE SINGLE SOURCE PRECURSORS AND METHODS TO DEPOSIT NANOWIRE BASED THIN FILMS FOR HIGH EFFICIENCY THERMOELECTRIC DEVICES 审中-公开
    合成单源电子前驱体的方法和沉积基于纳米级薄膜的高效热电装置的方法

    公开(公告)号:US20160247994A1

    公开(公告)日:2016-08-25

    申请号:US14852125

    申请日:2015-09-11

    CPC classification number: H01L35/24 C07F11/00 H01L35/34

    Abstract: Single source precursors, methods to synthesize single source precursors and methods to deposit nanowire based thin films using single source precursors for high efficiency thermoelectric devices are provided herein. In some embodiments, a method of forming a single source precursor includes mixing a first compound with one of SbX3, SbX5, Sb2(SO4)3 or with one of BiX3, Bi(NO3)3, Bi(OTf)3, Bi(PO4), Bi(OAc)3, wherein the first compound is one of a lithium selenolate, a lithium tellurolate, a monoselenide, or a monotelluride.

    Abstract translation: 本文提供单源前体,合成单源前体的方法和使用单一源前体沉积纳米线基薄膜的方法来实现高效热电器件。 在一些实施方案中,形成单一源前体的方法包括将第一化合物与SbX 3,SbX 5,Sb 2(SO 4)3或BiX 3,Bi(NO 3)3,Bi(OTf)3,Bi(PO 4) ),Bi(OAc)3,其中第一化合物是硒酸锂,锂锂,单硒化物或单碲化物之一。

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