Process for Ion Exchange on Zeolites
    4.
    发明申请
    Process for Ion Exchange on Zeolites 审中-公开
    沸石离子交换方法

    公开(公告)号:US20130129612A1

    公开(公告)日:2013-05-23

    申请号:US13677868

    申请日:2012-11-15

    Applicant: BASF SE

    Abstract: Aspects of the present invention relate to an improved process for exchanging alkali metal or alkaline earth metal ions in zeolites for ammonium ions. For this exchange, aqueous solutions of ammonium salts, for example ammonium sulfate, ammonium nitrate or ammonium chloride, are currently being used. The resulting “ammonium zeolites” are calcined to convert them, with release of ammonia, to the H form of the zeolites suitable as a catalyst. Certain methods provided herein use ammonium carbonate instead of the ammonium compounds mentioned. As excess ammonium carbonate, in contrast to the nitrates, sulfates or chlorides, can be recycled in the form of carbon dioxide and ammonia, the amount of salt which has to be discharged is lowered significantly.

    Abstract translation: 本发明的方面涉及用于在铵离子的沸石中交换碱金属或碱土金属离子的改进方法。 对于这种交换,目前正在使用铵盐的水溶液,例如硫酸铵,硝酸铵或氯化铵。 将所得的“铵沸石”煅烧以将其转化为氨释放到适合作为催化剂的沸石的H形式。 本文提供的某些方法使用碳酸铵代替所提及的铵化合物。 作为过量的碳酸铵,与硝酸盐相比,硫酸盐或氯化物可以以二氧化碳和氨的形式再循环,必须排出的盐的量显着降低。

    Post-treatment of deboronated zeolite beta

    公开(公告)号:US10179741B2

    公开(公告)日:2019-01-15

    申请号:US14436738

    申请日:2013-10-09

    Applicant: BASF SE

    Abstract: A process for the post-treatment of a zeolitic material having a BEA framework structure, the process comprising (i) providing a zeolitic material having a BEA framework structure, wherein the framework structure of the zeolitic material comprises X2O3 and YO2, wherein Y is a tetravalent element and X is a trivalent element and wherein the molar ratio X2O3:YO2 is greater than 0.02:1; (ii) treating the zeolitic material provided in (i) with a liquid solvent system thereby obtaining a zeolitic material having a molar ratio X2O3:YO2 of at most 0.02:1, and at least partially separating the zeolitic material from the liquid solvent system; (iii) treating the zeolitic material obtained from (ii) with a liquid aqueous system having a pH in the range of 5.5 to 8 and a temperature of at least 75° C.

    Process for the Conversion of Oxygenates to Olefins
    9.
    发明申请
    Process for the Conversion of Oxygenates to Olefins 有权
    将氧化物转化为烯烃的方法

    公开(公告)号:US20140142361A1

    公开(公告)日:2014-05-22

    申请号:US14076723

    申请日:2013-11-11

    Applicant: BASF SE

    CPC classification number: C07C1/20 C07C2529/40 C07C11/02

    Abstract: The present invention relates to a process for the conversion of oxygenates to olefins comprising (i) providing a gas stream comprising one or more oxygenates; and (ii) contacting the gas stream with a catalyst; wherein the catalyst comprises a zeolitic material having an MFI, MEL, and/or MWW-type framework structure comprising YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element, said zeolitic material being obtainable and/or obtained according to a method comprising (1) preparing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and one or more solvents; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material having an MFI, MEL and/or MWW-type framework structure; wherein the mixture crystallized in step (2) contains 3 wt.-% or less of the one or more elements M based on 100 wt.-% of YO2, wherein M stands for sodium.

    Abstract translation: 本发明涉及一种将含氧化合物转化为烯烃的方法,包括(i)提供包含一种或多种含氧化合物的气流; 和(ii)使气流与催化剂接触; 其中所述催化剂包含具有包含YO 2和X 2 O 3的MFI,MEL和/或MWW型骨架结构的沸石材料,其中Y是四价元素,X是三价元素,所述沸石材料可根据 涉及一种方法,包括(1)制备包含一种或多种YO源的混合物,一种或多种X 2 O 3源和一种或多种溶剂的混合物; 和(2)使步骤(1)中获得的混合物结晶,得到具有MFI,MEL和/或MWW型骨架结构的沸石材料; 其中在步骤(2)中结晶的混合物含有基于100重量%的YO 2的一种或多种元素M的3重量%或更少,其中M代表钠。

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