Abstract:
The present invention relates to a catalyst for the conversion of oxygenates to olefins, wherein the catalyst comprises one or more zeolites of the MFI, MEL and/or MWW structure type and particles of one or more metal oxides, the one or more zeolites of the MFI, MEL and/or MWW structure type comprising one or more alkaline earth metals, and the particles of the one or more metal oxides comprising phosphorus, the phosphorus being present at least partly in oxidic form, and the one or more alkaline earth metals being selected from the group consisting of Mg, Ca, Sr, Ba and combinations of two or more thereof, to the preparation and use thereof, and to a process for converting oxygenates to olefins using the catalyst.
Abstract:
The present invention relates to extruded shaped bodies containing at least one metal-organic framework (MOF), methods for their preparation and their use.
Abstract:
The present invention relates to a catalyst for the conversion of oxygenates to olefins, wherein the catalyst comprises one or more zeolites of the MFI, MEL and/or MWW structure type and particles of one or more metal oxides, the one or more zeolites of the MFI, MEL and/or MWW structure type comprising one or more alkaline earth metals, and the particles of the one or more metal oxides comprising phosphorus, the phosphorus being present at least partly in oxidic form, and the one or more alkaline earth metals being selected from the group consisting of Mg, Ca, Sr, Ba and combinations of two or more thereof, to the preparation and use thereof, and to a process for converting oxygenates to olefins using the catalyst.
Abstract:
Aspects of the present invention relate to an improved process for exchanging alkali metal or alkaline earth metal ions in zeolites for ammonium ions. For this exchange, aqueous solutions of ammonium salts, for example ammonium sulfate, ammonium nitrate or ammonium chloride, are currently being used. The resulting “ammonium zeolites” are calcined to convert them, with release of ammonia, to the H form of the zeolites suitable as a catalyst. Certain methods provided herein use ammonium carbonate instead of the ammonium compounds mentioned. As excess ammonium carbonate, in contrast to the nitrates, sulfates or chlorides, can be recycled in the form of carbon dioxide and ammonia, the amount of salt which has to be discharged is lowered significantly.
Abstract:
The invention relates to a catalyst and catalyst layer and process for preparing dimethyl ether from synthesis gas or methanol as well as the use of the catalyst or catalyst layer in this process.
Abstract:
The present invention relates to a catalyst for the conversion of oxygenates to olefins, wherein the catalyst comprises one or more zeolites of the MFI, MEL and/or MWW structure type and particles of one or more metal oxides, the one or more zeolites of the MFI, MEL and/or MWW structure type comprising one or more alkaline earth metals selected from the group consisting of Mg, Ca, Sr, Ba and combinations of two or more thereof, wherein the catalyst displays a water uptake of 9.0 wt.-% or less, as well as to a process for the production thereof and to its use, in particular in a process for converting oxygenates to olefins.
Abstract:
A process for the post-treatment of a zeolitic material having a BEA framework structure, the process comprising (i) providing a zeolitic material having a BEA framework structure, wherein the framework structure of the zeolitic material comprises X2O3 and YO2, wherein Y is a tetravalent element and X is a trivalent element and wherein the molar ratio X2O3:YO2 is greater than 0.02:1; (ii) treating the zeolitic material provided in (i) with a liquid solvent system thereby obtaining a zeolitic material having a molar ratio X2O3:YO2 of at most 0.02:1, and at least partially separating the zeolitic material from the liquid solvent system; (iii) treating the zeolitic material obtained from (ii) with a liquid aqueous system having a pH in the range of 5.5 to 8 and a temperature of at least 75° C.
Abstract:
Described is a process for the production of a zeolitic material having an MFI, MEL, and/or MWW-type framework structure comprising YO2 and X2O3. The process comprises (1) preparing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and one or more solvents; (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material having an MFI, MEL and/or MWW-type framework structure; and (3) impregnating the zeolitic material obtained in step (2) with one or more elements selected from the group of alkaline earth metals. Y is a tetravalent element, and X is a trivalent element. The mixture crystallized in step (2) contains 3 wt.-% or less of one or more elements M based on 100 wt-% of YO2, wherein M stands for sodium.
Abstract:
The present invention relates to a process for the conversion of oxygenates to olefins comprising (i) providing a gas stream comprising one or more oxygenates; and (ii) contacting the gas stream with a catalyst; wherein the catalyst comprises a zeolitic material having an MFI, MEL, and/or MWW-type framework structure comprising YO2 and X2O3, wherein Y is a tetravalent element, and X is a trivalent element, said zeolitic material being obtainable and/or obtained according to a method comprising (1) preparing a mixture comprising one or more sources for YO2, one or more sources for X2O3, and one or more solvents; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material having an MFI, MEL and/or MWW-type framework structure; wherein the mixture crystallized in step (2) contains 3 wt.-% or less of the one or more elements M based on 100 wt.-% of YO2, wherein M stands for sodium.
Abstract translation:本发明涉及一种将含氧化合物转化为烯烃的方法,包括(i)提供包含一种或多种含氧化合物的气流; 和(ii)使气流与催化剂接触; 其中所述催化剂包含具有包含YO 2和X 2 O 3的MFI,MEL和/或MWW型骨架结构的沸石材料,其中Y是四价元素,X是三价元素,所述沸石材料可根据 涉及一种方法,包括(1)制备包含一种或多种YO源的混合物,一种或多种X 2 O 3源和一种或多种溶剂的混合物; 和(2)使步骤(1)中获得的混合物结晶,得到具有MFI,MEL和/或MWW型骨架结构的沸石材料; 其中在步骤(2)中结晶的混合物含有基于100重量%的YO 2的一种或多种元素M的3重量%或更少,其中M代表钠。
Abstract:
The invention relates to a catalyst system and process for preparing dimethyl ether from synthesis gas as well as the use of the catalyst system in this process.