摘要:
Relief plates and printing plates are produced by a positive-working process, using a photopolymerizable layer which contains one or more photopolymerizable, olefinically unsaturated compounds, one or more photoinitiators which can be activated by UV light, and a combination of a phenothiazinium, phenoxazinium, phenazinium or acridinium dye with a mild reducing agent which, on exposure to visible light, is capable of reducing the dye in the excited electronic state. The photopolymerizable layer is exposed imagewise to light having a wavelength longer than 450 nm, and simultaneously or subsequently exposed uniformly to light having a wavelength of from 300 to 420 nm, after which the unpolymerized areas of the layer are removed.
摘要:
A photopolymerizable recording composition which comprises a mixture, containing a photoinitiator, of (a) a photopolymerizable olefinically unsaturated monomer and (b) an organic polymeric binder, wherein the photoinitiator is an acylphosphine oxide compound of the formula R.sup.1 R.sup.2 PO-CO-R.sup.3, where R.sup.1 and R.sup.2 are certain organic radicals and R.sup.3 is tert.-alkyl or a cyclic radical with two substituents in the ortho-position to the carbonyl group. The recording compositions have a high reactivity when irradiated with UV light and are used in particular for the preparation of printing plates, relief plates and photoresists.
摘要:
A photopolymerizable recording composition which comprises a mixture, containing a photoinitiator, of (a) a photopolymerizable olefinically unsaturated monomer and (b) an organic polymeric binder, wherein the photoinitiator is an acylphosphine oxide compound of the formula R.sup.1 R.sup.2 PO--CO--R.sup.3, where R.sup.1 and R.sup.2 are certain organic radicals and R.sup.3 is tert.-alkyl or a cyclic radical with two substituents in the ortho-position to the carbonyl group. The recording compositions have a high reactivity when irradiated with UV light and are used in particular for the preparation of printing plates, relief plates and photo-resists.
摘要:
A photosensitive multi-layer material comprising a base and a photosensitive layer which has a polyamide binder and is soluble or dispersible in an alcoholic solvent contains two layers between the base and the photosensitive layer, namely (a) an adhesion-promoting layer, adjacent to the base, which is derived from a polyurethane binder, prepared by reacting a hydroxyl-containing epoxy resin and a polyisocyanate, and a pigment combination in which a white zinc sulfide pigment is the essential constituent, and (b) an adhesive layer, adjacent to the photosensitive layer, which consists of a baked mixture of an alcohol-soluble copolyamide and a melamine-formaldehyde resin.
摘要:
A photosensitive multi-layer material comprising a base, which may or may not be provided with an adhesion-promoting layer, and a photopolymerizable layer, consisting of a mixture of a photoinitiator, a binder and a photopolymerizable monomer, possesses, between the base and the photopolymerizable layer, an adhesive layer of a hardened mixture of a binder and an etherified melamine-formaldehyde condensate, hardenable at 60.degree.-120.degree. C.
摘要:
Photopolymerizable compositions for the production of printing plates and relief plates, consisting essentially of a photoinitiator-containing mixture of olefinically unsaturated photopolymerizable compounds with polymeric binders, contain up to 1% by weight of a compound having the structural element of anthrone, e.g. bianthrone and 9,9'-bianthryl, which results in an improved relief image in the production of relief plates.
摘要:
Novel photopolymerizable recording materials, in particular for the production of printing plates and relief plates, can be developed with water or an aqueous alkaline solution and predominantly consist of a photoinitiator-containing mixture of (a) one or more low molecular weight compounds having one or more photopolymerizable olefinically unsaturated double bonds and (b) one or more organic polymeric binders and contain a bisacylphosphine oxide as the photoinitiator.These recording materials are useful for the production of printing plates and relief plates.
摘要:
A mixture Ia which comprises a composition IIa consisting of a) 1 to 95% by weight of a solid III, preferably a basic solid III, having a primary particle size of 5 nm to 20 microns, and b) 5 to 99% by weight of a polymeric mass IV obtainable by polymerizing b1) 5 to 100% by weight, based on the mass IV of a condensation product V of α) at least one compound VI which is capable to react with a carboxylic acid or a sulfonic acid or a derivative thereof or a mixture of two or more thereof, and β) at least one mole per mole of the compound VI of a carboxylic acid or a sulfonic acid VII which exhibits at least one radically polymerizable functional group, or a derivative thereof or a mixture of two or more thereof and b2) 0 to 95% by weight, based on the mass IV, of a further compound VIII having an average molecular weight (number average) of at least 5000 and having polyether segments in the main or side chain, wherein the proportion by weight of the composition IIa in the mixture Ia is 1 to 100% by weight.
摘要:
The present invention relates to composite elements comprising at least one layer A which comprises at least one solid electrolyte Al, at least one adhesion-promoting layer B having a thickness of
摘要:
A membrane comprising a composition including (a) 1 to 99 wt-% of at least one polyurethane elastomer comprising at least one hard segment and at least one soft segment, and (b) 99 to 1 wt-% of a solid, wherein said solid is incorporated in said at least one polyurethane elastomer.