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    Surface active metal chelated nutrients for bioremediation of hydrocarbon contaminated soils and water
    3.
    发明授权
    Surface active metal chelated nutrients for bioremediation of hydrocarbon contaminated soils and water 失效
    表面活性金属螯合营养物质用于碳氢化合物污染土壤和水的生物修复

    公开(公告)号：US5571715A

    公开(公告)日：1996-11-05

    申请号：US375748

    申请日：1995-01-20

    申请人： Ramesh Varadaraj ,  Stanley J. Brois ,  Jan Bock ,  Cornelius H. Brons

    发明人： Ramesh Varadaraj ,  Stanley J. Brois ,  Jan Bock ,  Cornelius H. Brons

    IPC分类号： B09C1/10 ,  C02F1/68 ,  C11D3/32 ,  C12N1/38

    CPC分类号： C02F1/682 ,  B09C1/10 ,  C11D3/32 ,  C12N1/38 ,  Y10S210/925 ,  Y10S516/02 ,  Y10S516/07

    摘要： The present invention provides for enhanced bioremediation of hydrocarbon contaminated soils and waters by treating soil or water with a composition comprising of a metal chelated macrocyclic amido amines or mixtures thereof represented by the structural formula: ##STR1## where R is selected from linear or branched alkanes with 8 to 22 carbons, linear or branched alkenes with 4 to 22 carbon atoms;T.sub.1, T.sub.2 and T.sub.3 are independently selected from ethylene, trimethylene, CH.sub.2 CH.sub.2 (NHCH.sub.2 CH.sub.2).sub.x where x is an integer from 1 to 10;MaQb is a metal compound wherein M is a cation selected from cations of Fe, Co, Ni, Cu, Zn, and Mn; and,Q is an anion selected from nitrate, phosphate anions; and a and b are integers from 1 to 3 necessary to satisfy the valence requirements of M and Q.a phosphorous source, and a diluent.

    摘要翻译： 本发明通过用包含金属螯合的大环酰氨基胺或其混合物的组合物处理土壤或水来提供碳氢化合物污染的土壤和水的增强的生物修复，其结构式如下：其中R选自直链或支链烷烃 具有8至22个碳，具有4至22个碳原子的直链或支链烯烃; T1，T2和T3独立地选自乙烯，三亚甲基，CH 2 CH 2（NHCH 2 CH 2）x，其中x是1至10的整数; MaQb是金属化合物，其中M是选自Fe，Co，Ni，Cu，Zn和Mn的阳离子的阳离子; Q为选自硝酸盐，磷酸盐阴离子的阴离子; a和b是满足M和Q价态要求所必需的1至3的整数，磷源和稀释剂。

    Bioremediation of hydrocarbon contaminated soil
    4.
    发明授权
    Bioremediation of hydrocarbon contaminated soil 失效
    碳氢化合物污染土壤的生物修复

    公开(公告)号：US5436160A

    公开(公告)日：1995-07-25

    申请号：US190391

    申请日：1994-02-02

    申请人： Ramesh Varadaraj ,  Jan Bock ,  Max L. Robbins

    发明人： Ramesh Varadaraj ,  Jan Bock ,  Max L. Robbins

    IPC分类号： B09C1/10 ,  C09K17/32 ,  C09K101/00 ,  C10G32/00 ,  C12P1/00 ,  C12S9/00 ,  C02F3/00 ,  C02F3/34

    CPC分类号： B09C1/10 ,  C12P1/00

    摘要： The bioremediation of hydrocarbon contaminated soil is enhanced by applying to the soil a hydrocarbon solution of a surfactant selected from the group consisting of: (a) mixture of a sorbitan ester of a C.sub.7 to C.sub.22 monocarboxylic acid and a polyoxyalkylene adduct of a sorbitan monoester of a C.sub.7 to C.sub.22 monocarboxylic acid, the adduct having from 6 to 50 polyoxyalkylene units, (b) an alkyl glycoside wherein the alkyl group has from about 8 to about 18 carbon atoms and the glycoside is a mono or diglycoside and (c) a mixture of (a) and (b) and (c) and thereafter applying microbial nutrients to the soil in amounts sufficient to promote the growth of indigenous microorganisms.

    摘要翻译： 通过向土壤施用选自以下的表面活性剂的烃溶液来增强碳氢化合物污染土壤的生物修复：（a）C7至C22单羧酸的脱水山梨糖醇酯与脱水山梨糖醇单酯的聚氧化烯加合物的混合物 C7至C22单羧酸，加合物具有6至50个聚氧化烯单元，（b）烷基糖苷，其中烷基具有约8至约18个碳原子，糖苷为单或二糖苷和（c）混合物 （a）和（b）和（c），然后以足以促进本地微生物生长的量将微生物营养素施用于土壤。

    Functional polycyclopentadiene resins via hydroboration process
    5.
    发明授权
    Functional polycyclopentadiene resins via hydroboration process 失效
    功能性聚环戊二烯树脂通过硼氢化工艺

    公开(公告)号：US5093433A

    公开(公告)日：1992-03-03

    申请号：US495676

    申请日：1990-03-19

    申请人： Tze-Chiang Chung ,  Encok Berluche ,  Jan Bock ,  Rodney V. Kastrup

    发明人： Tze-Chiang Chung ,  Encok Berluche ,  Jan Bock ,  Rodney V. Kastrup

    IPC分类号： C08F8/00 ,  C08F8/42

    CPC分类号： C08F8/00 ,  C08F8/42

    摘要： A process for preparing a functionalized petroleum resin which comprises the steps of: dissolving a petroleum resin having a norbornene moiety with a double bond in a solvent to form a solution; adding to the solution a borane compound having the formula: ##STR1## wherein R.sub.1 and R.sub.2 are alkyl or cycloalkyl groups having about 1 to about 10 carbonations; reacting said petroleum resin with said borane compound at about room temperature for a sufficient period of time to form a borane intermediate; and reacting said borane intermediate with a chemical agent to convert said borane intermediate into said functionalized petroleum resin.

    摘要翻译： 一种制备官能化石油树脂的方法，包括以下步骤：将具有双键的降冰片烯部分的石油树脂溶解在溶剂中以形成溶液; 向该溶液中加入具有下式的硼烷化合物：其中R 1和R 2是具有约1至约10个碳酸酯的烷基或环烷基; 在约室温下使所述石油树脂与所述硼烷化合物反应足够的时间以形成硼烷中间体; 并使所述硼烷中间体与化学试剂反应以将所述硼烷中间体转化成所述官能化石油树脂。

    Enhanced oil recovery with hydrophobically associating polymers containing sulfonate functionality
    6.
    发明授权
    Enhanced oil recovery with hydrophobically associating polymers containing sulfonate functionality 失效
    用含有磺酸酯官能团的疏水缔合聚合物提高采油率

    公开(公告)号：US4702319A

    公开(公告)日：1987-10-27

    申请号：US947285

    申请日：1986-12-29

    申请人： Jan Bock ,  Paul L. Valint ,  Salvatore J. Pace

    发明人： Jan Bock ,  Paul L. Valint ,  Salvatore J. Pace

    IPC分类号： C09K8/588 ,  E21B43/22

    CPC分类号： C09K8/588 ,  Y10S507/936

    摘要： This invention relates to a method for enhanced recovery of petroleum from a subterranean oil-bearing formation. More particularly, this invention relates to secondary or tertiary recovery of oil employing a polymer thickened aqueous drive fluid. The polymeric viscosifier for the drive fluid is selected from a class of hydrophobically associating water soluble polymers containing one or more water soluble monomers and a water insoluble monomer or group. The water soluble groups are acrylamide and a salt of an ethylenically unsaturated sulfonic acid and the water insoluble group is a higher alkyl acrylamide. These polymers, when dissolved in an aqueous brine solution, have the ability to substantially increase the viscosity of the solution. The control of displacement fluid mobility results in more uniform sweep efficiency and improved oil recovery. In addition, aqueous solutions of these hydrophobically associating polymers exhibit enhanced viscosification, reduced salt sensitivity and other desirable rheological properties found useful in chemically enhanced oil recovery processes.

    摘要翻译： 本发明涉及一种从地下含油地层提高石油回收率的方法。 更具体地说，本发明涉及使用聚合物增稠的含水驱动流体的二次或三次回收油。 用于驱动流体的聚合物增粘剂选自一类含有一种或多种水溶性单体和水不溶性单体或疏水缔合的水溶性聚合物。 水溶性基团是丙烯酰胺和烯键式不饱和磺酸的盐，水不溶性基团是高级烷基丙烯酰胺。 当溶解在盐水溶液中时，这些聚合物具有显着增加溶液粘度的能力。 位移流体流动的控制导致更均匀的扫描效率和改善的油回收率。 此外，这些疏水缔合聚合物的水溶液表现出增强的粘度，降低的盐敏感性和其它在化学强化的油回收方法中有用的所需的流变学性质。

    Tetrapolymers of N-vinyl pyrrolidone/acrylamide/salt of acrylic acid/N-alkyl acrylamide
    7.
    发明授权
    Tetrapolymers of N-vinyl pyrrolidone/acrylamide/salt of acrylic acid/N-alkyl acrylamide 失效
    N-乙烯基吡咯烷酮/丙烯酰胺/丙烯酸/ N-烷基丙烯酰胺盐的四元共聚物

    公开(公告)号：US4663408A

    公开(公告)日：1987-05-05

    申请号：US814362

    申请日：1985-12-30

    申请人： Donald N. Schulz ,  Enock Berluche ,  John J. Maurer ,  Jan Bock

    发明人： Donald N. Schulz ,  Enock Berluche ,  John J. Maurer ,  Jan Bock

    IPC分类号： C08F8/12 ,  C09K8/12 ,  C09K8/588 ,  C08F20/06

    CPC分类号： C09K8/588 ,  C08F8/44 ,  C09K8/12

    摘要： The present invention relates to improved viscosification agents for an aqueous or brine solutions. Typically, the viscosification agents are tetrapolymers of N-vinyl pyrrolidone/acrylamide/salt of acrylic acid/N-alkyl acrylamide wherein said tetrapolymers have the formula: ##STR1## wherein w is about 1 to about 80 mole percent, more preferably about 5 to about 75 mole percent, and most preferably about 10 to about 70 mole percent; x is about 10 to about 90 mole percent, more preferably about 20 to about 80 mole percent, and most preferably about 30 to about 70 mole percent; and y is about 0.1 to about 10.0 mole percent, more preferably about 0.15 to about 5.0 mole percent; and most preferably about 0.2 to about 3.0 mole percent; z is about 1.0 to about 30.0 mole percent, more preferably about 2.0 to about 25.0 mole percent, and most preferably about 5.0 to about 20.0 mole percent; R is an alkyl group having about 6 to about 30 carbon atoms, more preferably about 7 to about 20, and most preferably about 8 to about 18; and M is a cation selected from the group consisting of monovalent cations, preferably Na.sup.+, K.sup.+ or R.sub.4 N.sup.+.

    摘要翻译： 本发明涉及用于水溶液或盐水溶液的改进的增粘剂。 通常，增粘剂是N-乙烯基吡咯烷酮/丙烯酰胺/丙烯酸/ N-烷基丙烯酰胺盐的四元共聚物，其中所述四元共聚物具有下式：其中w为约1至约80摩尔％，更优选约5至 约75摩尔％，最优选约10至约70摩尔％; x为约10至约90摩尔％，更优选约20至约80摩尔％，最优选约30至约70摩尔％ y为约0.1至约10.0摩尔％，更优选约0.15至约5.0摩尔％; 最优选约0.2至约3.0摩尔％; z为约1.0至约30.0摩尔％，更优选约2.0至约25.0摩尔％，最优选约5.0至约20.0摩尔％ R是具有约6至约30个碳原子，更优选约7至约20，最优选约8至约18的烷基; 并且M是选自一价阳离子，优选Na +，K +或R 4 N +的阳离子。

    Terpolymers of acrylamide, alkylacrylamide and betaine monomers
    8.
    发明授权
    Terpolymers of acrylamide, alkylacrylamide and betaine monomers 失效
    丙烯酰胺，烷基丙烯酰胺和甜菜碱单体的三元共聚物

    公开(公告)号：US4650848A

    公开(公告)日：1987-03-17

    申请号：US814252

    申请日：1985-12-30

    申请人： Donald N. Schulz ,  Ilan Duvdevani ,  Jan Bock ,  Enock Berluche

    发明人： Donald N. Schulz ,  Ilan Duvdevani ,  Jan Bock ,  Enock Berluche

    IPC分类号： C08F220/56 ,  C08F20/56

    CPC分类号： C08F220/56

    摘要： A water soluble terpolymer having the structure: ##STR1## wherein x is selected from the group consisting of ##STR2## wherein x is about 1 to about 95 mole percent; y is about 0.1 to about 5.0 mole percent; R.sub.1 is methyl or hydrogen; z is about 1 to about 30 mole percent; R.sub.2 is an alkyl group of 1-5 carbon atoms; R.sub.3 is an alkyl group of 3 to 4 carbon atoms; R.sub.4 is an alkyl group of 1-5 carbon atoms; and R.sub.5 is an alkyl group of 4-20.

    摘要翻译： 具有以下结构的水溶性三元共聚物：其中x选自由下列组成的组：其中x为约1至约95摩尔％; y为约0.1至约5.0摩尔％; R1是甲基或氢; z为约1至约30摩尔％; R2是1-5个碳原子的烷基; R3是3〜4个碳原子的烷基; R4是1-5个碳原子的烷基; R5为4-20的烷基。

    Microemulsion process for producing acrylamide-alkyl acrylamide copolymers
    10.
    发明授权
    Microemulsion process for producing acrylamide-alkyl acrylamide copolymers 失效
    用于制备丙烯酰胺 - 烷基丙烯酰胺共聚物的微乳液法

    公开(公告)号：US4521580A

    公开(公告)日：1985-06-04

    申请号：US526990

    申请日：1983-08-29

    申请人： S. Richard Turner ,  Donald B. Siano ,  Jan Bock

    发明人： S. Richard Turner ,  Donald B. Siano ,  Jan Bock

    IPC分类号： C08F220/56 ,  C09K8/588 ,  C08F20/56

    CPC分类号： C08F220/56 ,  C09K8/588

    摘要： The copolymerization of water soluble monomers with water insoluble monomers can be effected by dissolving the water insoluble monomer into a homogeneous mixture of oil, surfactant, and cosurfactant and then diluting this with water containing the water soluble monomer to yield a predominently aqueous, homogeneous, transparent dispersion of microemulsion droplets. The polymerization is initiated with water soluble free radical initiators to give copolymers that are free of visible particulates and such that the reaction product remains homogenous. The components are chosen to yield copolymers that are water soluble and which viscosify at low concentrations.

    摘要翻译： 水溶性单体与水不溶性单体的共聚可以通过将水不溶性单体溶解在油，表面活性剂和辅助表面活性剂的均匀混合物中，然后用含有水溶性单体的水稀释，以产生主要含水，均匀，透明 微乳液滴的分散。 聚合由水溶性自由基引发剂引发，得到不含可见颗粒的共聚物，使反应产物保持均匀。 选择这些组分以产生水溶性且在低浓度下增粘的共聚物。