公开(公告)号：US5491182A

公开(公告)日：1996-02-13

申请号：US280912

申请日：1994-07-27

申请人： Charles R. Key ,  Yen-Jer Shih

发明人： Charles R. Key ,  Yen-Jer Shih

IPC分类号： C08J5/08 ,  C03C25/28 ,  C08F212/08 ,  C08F218/08 ,  C08F220/18 ,  C08K9/08 ,  D06M13/02 ,  D06M13/188 ,  D06M13/503 ,  D06M13/507 ,  D06M15/263 ,  D06M15/333 ,  D06M101/00 ,  C08K9/04

CPC分类号： C03C25/28 ,  C03C25/285 ,  C08F212/08 ,  C08F218/08 ,  C08F220/18 ,  C08K9/08 ,  Y10T428/2938

摘要： The present invention is directed to sizing compositions for use on glass fibers which are used to reinforce lamination resins used in the formation of glass laminates. The sizing compositions contain a low molecular weight, polymer latex prepared by polymerizing at least one monomer(s) selected from the group consisting of acrylic acid, methacrylic acid, C.sub.1 -C.sub.18 alkyl esters of acrylic acid, C.sub.1 -C.sub.18 alkyl esters of methacrylic acid, glycidyl acrylate, glycidyl methacrylate, C.sub.1 -C.sub.4 hydroxyalkyl esters of acrylic acid, C.sub.1 -C.sub.4 hydroxyalkyl esters of methacrylic acid, vinyl esters of saturated aliphatic monocarboxylic acids containing up to 10 carbon atoms, (meth)acrylamide and their N-substituted derivatives, vinyl ethers, N-vinyl lactams, halogenated vinyl compounds, alkyl vinyl ketones, (meth)allyl ester of saturated aliphatic monocarboxylic acids, vinyl compounds such as vinyl pyrrole, olefins, diesters of itaconic, maleic and/or fumaric acid, and styrene. The polymers have a molecular weight effective to provide both improved wettability of the glass fibers by the lamination resins and improved clarity of reinforced glass laminates prepared from the sized glass fibers and the lamination resins, when compared to sizing compositions known heretofore. The invention is also directed to glass fibers treated with such compositions, and fiber-reinforced plastics prepared from such treated glass fibers.

摘要翻译： 本发明涉及用于玻璃纤维的上胶组合物，其用于加强用于形成玻璃层压材料的层压树脂。 上胶组合物含有低分子量的聚合物胶乳，其通过聚合至少一种选自丙烯酸，甲基丙烯酸，丙烯酸的C1-C18烷基酯，甲基丙烯酸的C1-C18烷基酯， ，丙烯酸缩水甘油酯，甲基丙烯酸缩水甘油酯，丙烯酸的C1-C4羟烷基酯，甲基丙烯酸的C1-C4羟烷基酯，含有至多10个碳原子的饱和脂肪族单羧酸的乙烯基酯，（甲基）丙烯酰胺及其N-取代的衍生物， 乙烯基醚，N-乙烯基内酰胺，卤代乙烯基化合物，烷基乙烯基酮，饱和脂族一元羧酸的（甲基）烯丙酯，乙烯基吡咯，烯烃，衣康酸二酯，马来酸和/或富马酸的乙烯基化合物和苯乙烯。 聚合物具有分子量，其有效地通过层压树脂提供玻璃纤维的改善的润湿性，并且与迄今为止已知的施胶组合物相比，可提高由尺寸的玻璃纤维和层压树脂制备的增强玻璃层压体的透明度。 本发明还涉及用这种组合物处理的玻璃纤维，以及由这种经处理的玻璃纤维制备的纤维增强塑料。

公开(公告)号：US5665470A

公开(公告)日：1997-09-09

申请号：US558299

申请日：1995-11-15

申请人： Charles R. Key ,  Yen-Jer Shih

发明人： Charles R. Key ,  Yen-Jer Shih

IPC分类号： C08J5/08 ,  C03C25/28 ,  C08F212/08 ,  C08F218/08 ,  C08F220/18 ,  C08K9/08 ,  D06M13/02 ,  D06M13/188 ,  D06M13/503 ,  D06M13/507 ,  D06M15/263 ,  D06M15/333 ,  D06M101/00 ,  C08K9/04

CPC分类号： C03C25/28 ,  C03C25/285 ,  C08F212/08 ,  C08F218/08 ,  C08F220/18 ,  C08K9/08 ,  Y10T428/2938

摘要： The present invention is directed to sizing compositions for use on glass fibers which are used to reinforce lamination resins used in the formation of glass laminates. The sizing compositions contain a low molecular weight, polymer latex prepared by polymerizing at least one monomer(s) selected from the group consisting of acrylic acid, methacrylic acid, C.sub.1 -C.sub.18 alkyl esters of acrylic acid, C.sub.1 -C.sub.18 alkyl esters of methacrylic acid, glycidyl acrylate, glycidyl methacrylate, C.sub.1 -C.sub.4 hydroxyalkyl esters of acrylic acid, C.sub.1 -C.sub.4 hydroxyalkyl esters of methacrylic acid, vinyl esters of saturated aliphatic monocarboxylic acids containing up to 10 carbon atoms, (meth)acrylamide and their N-substituted derivatives, vinyl ethers, N-vinyl lactams, halogenated vinyl compounds, alkyl vinyl ketones, (meth)allyl ester of saturated aliphatic monocarboxylic acids, vinyl compounds such as vinyl pyrrole, olefins, diesters of itaconic, maleic and/or fumaric acid, and styrene. The polymers have a molecular weight effective to provide both improved wettability of the glass fibers by the lamination resins and improved clarity of reinforced glass laminates prepared from the sized glass fibers and the lamination resins, when compared to sizing compositions known heretofore. The invention is also directed to glass fibers treated with such compositions, and fiber-reinforced plastics prepared from such treated glass fibers.

摘要翻译： 本发明涉及用于玻璃纤维的上胶组合物，其用于加强用于形成玻璃层压材料的层压树脂。 上胶组合物含有低分子量的聚合物胶乳，其通过聚合至少一种选自丙烯酸，甲基丙烯酸，丙烯酸的C1-C18烷基酯，甲基丙烯酸的C1-C18烷基酯， ，丙烯酸缩水甘油酯，甲基丙烯酸缩水甘油酯，丙烯酸的C1-C4羟烷基酯，甲基丙烯酸的C1-C4羟烷基酯，含有至多10个碳原子的饱和脂肪族单羧酸的乙烯基酯，（甲基）丙烯酰胺及其N-取代的衍生物， 乙烯基醚，N-乙烯基内酰胺，卤代乙烯基化合物，烷基乙烯基酮，饱和脂族一元羧酸的（甲基）烯丙酯，乙烯基吡咯，烯烃，衣康酸二酯，马来酸和/或富马酸的乙烯基化合物和苯乙烯。 聚合物具有分子量，其有效地通过层压树脂提供玻璃纤维的改善的润湿性，并且与迄今为止已知的施胶组合物相比，可提高由尺寸的玻璃纤维和层压树脂制备的增强玻璃层压体的透明度。 本发明还涉及用这种组合物处理的玻璃纤维，以及由这种经处理的玻璃纤维制备的纤维增强塑料。

公开(公告)号：US5219924A

公开(公告)日：1993-06-15

申请号：US722644

申请日：1991-06-28

申请人： Yen-Jer Shih

发明人： Yen-Jer Shih

IPC分类号： C08F2/32 ,  C08F210/02 ,  C08F218/04 ,  D21H19/58

CPC分类号： D21H19/58 ,  C08F210/02 ,  C08F218/04

摘要： An improved process for the production of paper coating binders wherein ethylene, vinyl ester and optional comonomers are polymerized using batch emulsion polymerization techniques and wherein the improvement comprises subjecting the emulsion to microfluidization to produce a particle size of less than about 0.5 microns prior to the emulsion polymerization step.

摘要翻译： 用于生产纸涂层粘合剂的改进方法，其中使用间歇乳液聚合技术聚合乙烯，乙烯基酯和任选的共聚单体，并且其中改进包括在乳液之前使乳液经受微流化以产生小于约0.5微米的粒度 聚合步骤。

公开(公告)号：US4668730A

公开(公告)日：1987-05-26

申请号：US762651

申请日：1985-08-05

申请人： Carmine P. Iovine ,  Yen-Jer Shih ,  Paul B. Foreman

发明人： Carmine P. Iovine ,  Yen-Jer Shih ,  Paul B. Foreman

IPC分类号： C08F265/00 ,  C08F2/16 ,  C08F265/06 ,  C09J133/04 ,  C09J151/00

CPC分类号： C08F265/06 ,  C09J151/003 ,  Y10T428/31895 ,  Y10T428/31906 ,  Y10T428/31913

摘要： Latex adhesives having a Tg of -60.degree. to 0.degree. C. characterized by superior rheological properties, are prepared without the use of additional thickeners from a colloid stabilized latex comprising: 65-90% by weight of the latex polymer solids of an acrylate or methacrylate ester monomer polymerized in 10-35% by weight of the latex solids of a polymeric colloid, the polymeric colloid having a Tg of -40.degree. to 0.degree. C., a number average molecular weight of 2,000 to 10,000 and comprising(a) 50 to 85% by weight of a monomer of the formula: ##STR1## where R' is hydrogen or methyl and R" is a C.sub.1 -C.sub.12 straight or branched chain alkyl group;(b) 10 to 50% by weight of an ethylenically unsaturated mono- or dicarboxylic acid;(c) 5 to 30% by weight of an acrylic or methacrylic ester of a polyalkylene oxide, and(d) 0 to 30% by weight of another ethylenically unsaturated copolymerizable monomer.

公开(公告)号：US4762866A

公开(公告)日：1988-08-09

申请号：US50259

申请日：1987-05-13

申请人： Yen-Jer Shih ,  Arthur B. Pruiksma ,  Paul R. Mudge

发明人： Yen-Jer Shih ,  Arthur B. Pruiksma ,  Paul R. Mudge

IPC分类号： C09J163/00 ,  C08F218/08 ,  C08J5/12 ,  C08L63/00 ,  C09J131/04 ,  C08L63/02 ,  C08L3/02 ,  C09J3/16 ,  B05D3/02

CPC分类号： C08J5/127 ,  C08F218/08 ,  C09J131/04 ,  C09J163/00 ,  C08J2375/04 ,  C08L63/00 ,  Y10S524/906

摘要： A two-part aqueous-based adhesive suitable for dry-bonding a polyether urethane foam to a rigid or semi-rigid substrate consists essentially of (a) an aqueous latex of an anionic emulsion polymer having a Tg of 0.degree. C. or below, preferably -5.degree. to -30.degree. C., an effective amount of a diepoxide or polyepoxide curing agent, and optionally, but preferably, an effective amount of a fugitive plasticizer. The polymer consists essentially of about 10-30% ethylene, 40 to 80% of vinyl acetate, 5-35% of a C.sub.4 -C.sub.8 -dialkyl maleate, and 4-10% of an ethylenically unsaturated acid monomer (e.g., acrylic acid). Suitable substrates include styrene board and fiberglass board.

摘要翻译： 适用于将聚醚聚氨酯泡沫干结合到刚性或半刚性基材的两部分水性粘合剂基本上由（a）Tg为0℃或更低的阴离子乳液聚合物的水性胶乳组成， 优选-5℃至-30℃，有效量的二环氧化物或聚环氧化物固化剂，以及任选但优选有效量的挥发性增塑剂。 聚合物基本上由约10-30％的乙烯，40-80％的乙酸乙烯酯，5-35％的C 4 -C 8 - 二烷基马来酸酯和4-10％的烯属不饱和酸单体（例如丙烯酸）组成， 。 合适的基材包括苯乙烯板和玻璃纤维板。

公开(公告)号：US4721748A

公开(公告)日：1988-01-26

申请号：US931585

申请日：1986-11-17

申请人： Carmine P. Iovine ,  Yen-Jer Shih ,  Paul B. Foreman

发明人： Carmine P. Iovine ,  Yen-Jer Shih ,  Paul B. Foreman

IPC分类号： C08F2/16 ,  C08F265/06 ,  C09J151/00

CPC分类号： C08F265/06 ,  C09J151/003

摘要： Latex adhesives having a Tg of -60.degree. to 0.degree.C. characterized by superior rheological properties, are prepared without the use of additional thickeners from a colloid stabilized latex comprising: 65-90% by weight of the latex polymer solids of an acrylate or methacrylate ester monomer polymerized in 10-35% by weight of the latex solids of a polymeric colloid, the polymeric colloid having a Tg of -40.degree. to 0.degree.C., a number average molecular weight of 2,000 to 10,000 and comprising(a) 50 to 85% by weight of a monomer of the formula: ##STR1## where R' is hydrogen or methyl and R" is a C.sub.1 -C.sub.12 straight or branched chain alkyl group;(b) 10 to 50% by weight of an ethylenically unsaturated mono- or dicarboxylic acid;(c) 5 to 30% by weight of an acrylic or methacrylic ester of a polyalkylene oxide, and(d) 0 to 30% by weight of another ethylenically unsaturated copolymerizable monomer.

摘要翻译： 制备Tg为-60°至0℃的胶乳粘合剂，其特征在于具有优异的流变性能，不用使用胶体稳定胶乳的另外的增稠剂，其包含：65-90重量％的胶乳聚合物固体的丙烯酸酯或 所述聚合物胶体的Tg为-40℃至0℃，数均分子量为2,000至10,000，并包含（a）聚合物胶体， 50至85重量％的下式的单体：其中R'是氢或甲基，R“是C1-C12直链或支链烷基; （b）10至50重量％的烯属不饱和单或二羧酸; （c）5-30重量％的聚亚烷基氧化物的丙烯酸或甲基丙烯酸酯，和（d）0-30重量％的其它烯属不饱和可共聚单体。

公开(公告)号：US4487855A

公开(公告)日：1984-12-11

申请号：US466598

申请日：1983-02-15

申请人： Yen-Jer Shih ,  Mohamed S. El-Aasser ,  John W. Vanderhoff

发明人： Yen-Jer Shih ,  Mohamed S. El-Aasser ,  John W. Vanderhoff

IPC分类号： C08F8/30

CPC分类号： C08F8/30

摘要： The present invention relates to colored latex products, and especially to colored synthetic polymer emulsions, the finely divided colored polymers obtainable therefrom, and methods for making the colored polymer emulsions as well as the polymers as colored, finely divided solids.

摘要翻译： 本发明涉及着色胶乳产品，特别涉及着色合成聚合物乳液，可从其获得的细碎着色聚合物乳液，以及制备着色聚合物乳液以及作为有色细碎固体的聚合物的方法。

公开(公告)号：US4546140A

公开(公告)日：1985-10-08

申请号：US636899

申请日：1984-08-02

申请人： Yen-Jer Shih

发明人： Yen-Jer Shih

IPC分类号： C08L29/00 ,  C08J3/02 ,  C08J3/03 ,  C08K5/098 ,  C08L1/00 ,  C08L23/00 ,  C08L23/08 ,  C08L27/00 ,  C08L29/10 ,  C08L31/00 ,  C08L31/04 ,  C08L33/00 ,  C08L33/02 ,  C08L33/04 ,  C08L101/00 ,  C08K5/04 ,  C08K5/09

CPC分类号： C08K5/098 ,  C08J3/03

摘要： Shelf-stable, one-package aqueous latices, which are curable with or without the application of heat, consist essentially of an alkaline-curable, self-crosslinking emulsion polymer, selected organic metal salts, and water. The alkali, alkaline earth, or heavy metal salts of C.sub.1 -C.sub.6 organic acids (e.g., sodium acetate) are post-added to th polymer emulsion or present during the polymerization. The polymer typically comprises about 90-99.9% by weight of one or more vinyl polymerizable monomers (e.g., acrylates, vinyl esters, and ethylene) and 0.1-10% by weight of a polymerizable non-ionic or cationic self-crosslinking monomer containing halohydrin groups (e.g., 3-chloro-2-hydroxypropyl (meth)acrylate or the reaction product of epichlorohydrin and N,N-dimethylaminopropyl methacrylamide or methacrylate).

摘要翻译： 稳定的单包装水性胶乳，其可在不加或不加热的情况下固化，其基本上由碱可固化的，自交联的乳液聚合物，选择的有机金属盐和水组成。 将C1-C6有机酸（例如乙酸钠）的碱金属，碱土金属或重金属盐后加入到聚合物乳液中或在聚合期间存在。 聚合物通常包含约90-99.9重量％的一种或多种乙烯基可聚合单体（例如丙烯酸酯，乙烯基酯和乙烯）和0.1-10重量％的含有卤代醇的可聚合非离子或阳离子自交联单体 （例如（甲基）丙烯酸3-氯-2-羟丙酯或表氯醇与N，N-二甲基氨基丙基甲基丙烯酰胺或甲基丙烯酸酯的反应产物）。

公开(公告)号：US4489192A

公开(公告)日：1984-12-18

申请号：US539038

申请日：1983-10-05

申请人： Yen-Jer Shih ,  Carmine P. Iovine

发明人： Yen-Jer Shih ,  Carmine P. Iovine

IPC分类号： C08F20/00 ,  C08F2/22 ,  C08F2/24 ,  C08F2/38 ,  C08F20/34 ,  C08F20/52 ,  C08F218/02 ,  C08F218/04 ,  C08F220/36 ,  C08F220/60 ,  C08F246/00 ,  C08L33/24 ,  C08L33/14

CPC分类号： C08F218/04 ,  Y10T442/2861

摘要： High solids, low viscosity, alkaline-curable, thermosetting cationic vinyl ester based polymer latices, characterized by the high molecular weight of the polymer therein, are prepared by polymerizing at least 5% of selected vinyl esters (up to C.sub.6), 0.5-10% of a self-crosslinking cationic quaternary ammonium monomer, and optionally a vinyl polymerizable monomer such as butyl acrylate, ethylene, acrylamide, diallyl maleate, and/or 2-hydroxyethyl acrylate. The polymerization is carried out in the presence of water, a watersoluble cationic azo initiator, a water-soluble amino thiol salt chain transfer agent, and a cationic and/or nonionic surfactant. The latices are useful as formaldehyde-free binders for polyester nonwovens.

摘要翻译： 通过聚合至少5％的选择的乙烯基酯（至多C6），0.5-10％的高固含量，低粘度，碱可固化，热固性阳离子乙烯酯基聚合物胶乳，其特征在于其中聚合物的高分子量 ％的自交联阳离子季铵单体，以及任选的乙烯基可聚合单体，如丙烯酸丁酯，乙烯，丙烯酰胺，马来酸二烯丙酯和/或丙烯酸2-羟基乙酯。 聚合在水，水溶性阳离子偶氮引发剂，水溶性氨基硫醇盐链转移剂和阳离子和/或非离子表面活性剂的存在下进行。 胶乳可用作聚酯无纺布的无甲醛粘合剂。

公开(公告)号：US5981627A

公开(公告)日：1999-11-09

申请号：US959011

申请日：1992-10-09

申请人： Yen-Jer Shih ,  Arthur B. Pruiksma

发明人： Yen-Jer Shih ,  Arthur B. Pruiksma

IPC分类号： C08F263/04 ,  C08F265/04 ,  C08F269/00 ,  C08F283/10 ,  C08G59/50 ,  C09J151/00 ,  C08K3/20

CPC分类号： C08F263/04 ,  C08F265/04 ,  C08F269/00 ,  C08F283/10 ,  C08G59/5026 ,  C09J151/003

摘要： This invention relates to stable one-part latex compositions prepared by aqueous emulsion polymerization wherein a core-shell polymer is formed, the core formed by emulsion polymerization of an ethylenically unsaturated monomer in the presence of an epoxy resin and the shell polymer formed by emulsion polymerization of a hydroxy carboxyl containing monomer composition in the presence of the core, providing that the monomers in both the core and the shell do not contain amino functional groups, and post-adding to the formed core-shell polymer an organic compound having at least one amino functional group which is available for later reaction with the epoxy resin upon drying to produce a crosslinked polymer product.

摘要翻译： 本发明涉及通过水乳液聚合制备的稳定的单组分胶乳组合物，其中形成核 - 壳聚合物，在环氧树脂存在下通过烯属不饱和单体的乳液聚合形成的芯和通过乳液聚合形成的壳聚合物 在核心存在下，含有羟基羧基的单体组合物，条件是核和壳两者中的单体不含有氨基官能团，并且向所形成的核 - 壳聚合物后添加具有至少一个 氨基官能团，其可用于随后与环氧树脂反应以干燥以产生交联聚合物产物。