公开(公告)号：US5241034A

公开(公告)日：1993-08-31

申请号：US913089

申请日：1992-07-14

申请人： Christian Herzig ,  Bernward Deubzer ,  David Huettner

发明人： Christian Herzig ,  Bernward Deubzer ,  David Huettner

IPC分类号： C08G77/20 ,  C08G77/22 ,  C08G77/38 ,  C08G77/50 ,  C08L83/05 ,  C08L83/07 ,  C08L83/14 ,  C09D183/04 ,  C09D183/05 ,  C09D183/07 ,  C09D183/14

CPC分类号： C08L83/14 ,  C08G77/50 ,  C09D183/14

摘要： Siloxane copolymers containing alkenyl groups are prepared by reacting an organic compound (1) containing at least two aliphatic double bonds of the general formulaR.sup.2 (CR.sup.3 .dbd.CH.sup.2).sub.xin which R.sup.2 is a divalent, trivalent or tetravalent hydrocarbon radical having from 1 to 25 carbon atoms per radical, R.sup.3 is a hydrogen atom or an alkyl radical having from 1 to 6 carbon atoms per radical and x is 2, 3 or 4, with an organopolysiloxane (2) having an average of more than one Si-bonded hydrogen atom per molecule, in the presence of a catalyst (3) which promotes the addition of Si-bonded hydrogen to an aliphatic double bond, in which the ratio between the aliphatic double bond in the organic compound (1) and the Si-bonded hydrogen in the organopolysiloxane (2) is such that the alkenyl containing siloxane copolymers thus obtained have an average of more than one alkenyl group per molecule of the formula --CR.sup.3 .dbd.CH.sup.2, in which R.sup.3 is the same as above.

摘要翻译： 含有烯基的硅氧烷共聚物是通过使含有至少两个通式R 2（CR 3 = CH 2）x的脂肪族双键的有机化合物（1）反应来制备的，其中R 2是具有1至25的二价，三价或四价烃基 每个基团的碳原子，R3是氢原子或每个基团具有1至6个碳原子并且x为2,3或4的烷基，与平均具有多于一个Si键合氢原子的有机聚硅氧烷（2） 在催化剂（3）的存在下，在有机化合物（1）中的脂族双键与Si键合氢之间的比例促进将Si键合的氢加成到脂族双键中的催化剂（3） 有机聚硅氧烷（2）使得由此获得的含烯基的硅氧烷共聚物每分子具有平均多于一个烯基的式-CR 3 = CH 2，其中R 3与上述相同。

公开(公告)号：US5703190A

公开(公告)日：1997-12-30

申请号：US697359

申请日：1996-08-23

申请人： Jochen Dauth ,  Christian Herzig ,  Bernward Deubzer ,  Klaus Schnitzer ,  David Huettner

发明人： Jochen Dauth ,  Christian Herzig ,  Bernward Deubzer ,  Klaus Schnitzer ,  David Huettner

IPC分类号： C08G77/20 ,  C08G77/22 ,  C08K5/01 ,  C08K5/05 ,  C08L83/04 ,  C08L83/05 ,  C08L83/07 ,  C09D183/04 ,  C09D183/07 ,  C08G77/06

CPC分类号： C08L83/04 ,  C08K5/01 ,  C08K5/05 ,  C09D183/04 ,  C08G77/045 ,  C08G77/12 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80

摘要： The present invention relates to crosslinkable compositions are described, containing (1) organosilicon compounds which have radicals containing aliphatic carbon-carbon multiple bonds, and (2) organosilicon compounds having Si-bonded hydrogen atoms, or (3) organosilicon compounds where radicals with aliphatic carbon-carbon multiple bonds and Si-bonded hydrogen atoms are present in the same compound, (4) catalysts which promote the addition of Si-bonded hydrogen onto aliphatic multiple bond, and (5) agents which retard the addition of Si-bonded hydrogen onto aliphatic multiple bond at room temperature, of the formula ##STR1## in which R.sup.1, R.sup.2, R.sup.4, R.sup.5 and R.sup.6 are identical or different and are a hydrogen atom or a monovalent, substituted or unsubstituted hydrocarbon radical having 1 to 12 carbon atoms per radical,R.sup.3 is a divalent hydrocarbon radical having 1 to 6 carbon atoms per radical, X is a radical of the formula --OH, --Cl, Br and --CN, and x and y are identical or different and are 0 or 1, with the proviso that there is at least one double bond.

摘要翻译： 本发明涉及可交联组合物，其含有（1）具有含有脂族碳 - 碳多键的基团的有机硅化合物，和（2）具有硅键合氢原子的有机硅化合物，或（3）有机硅化合物， 碳 - 碳多键和硅键合的氢原子存在于同一化合物中，（4）促进在脂肪族多键上加入Si键的氢的催化剂，和（5）阻止加入Si键的氢 在其中R 1，R 2，R 4，R 5和R 6相同或不同且为氢原子或具有1至12个碳原子的单价，取代或未取代的烃基的式（I） 每个基团的碳原子，R 3是每个基团具有1至6个碳原子的二价烃基，X是式-OH，-Cl，Br和-CN的基团，x和y相同或不同， 0或1，条件是存在至少一个双键。

公开(公告)号：US5621057A

公开(公告)日：1997-04-15

申请号：US455489

申请日：1995-05-31

申请人： Christian Herzig ,  Bernward Deubzer ,  Martina Bloechl ,  David Huettner ,  Walter Magee

发明人： Christian Herzig ,  Bernward Deubzer ,  Martina Bloechl ,  David Huettner ,  Walter Magee

IPC分类号： C08F283/12 ,  C08F290/00 ,  C08L83/04 ,  C08L83/07 ,  C09D4/00 ,  C08F26/00

CPC分类号： C08F283/124

摘要： Alkenyl ether-siloxane compositions comprising(A) an oligomeric or polymeric organosilicon compound having on average more than one alkenyloxy group of the formulaR.sup.2 --CH.dbd.CH--O-- (VI)(B) a monomeric maleic and/or fumaric acid compound of the formula ##STR1## in which R.sup.2 is a hydrogen atom or the methyl radical,R.sup.3 is identical or different and is a hydrogen atom, a hydrocarbon radical having 1 to 16 carbon atoms, which can be interrupted by oxygen, sulfur or oxygen- or silicon-containing units, a substituted hydrocarbon radical having 1 to 6 carbon atoms, a silyl radical or a siloxanyl radical,R.sup.4 is identical or different and is a hydrogen atom, chlorine, bromine, fluorine or an optionally substituted alkyl radical andZ is an oxygen atom or a radical --NR.sup.5 --, where R.sup.5 has one of the meanings given for R.sup.3,optionally(C) initiators which form free radicals and optionally(D) inhibitors for regulating the pot life.

摘要翻译： 烯基醚 - 硅氧烷组合物，其包含（A）具有平均多于一个式R 2 -CH = CH-O-（VI）的烯氧基的低聚或聚合有机硅化合物（B）（B）单体马来酸和/或富马酸化合物 该式为氢原子或甲基，R3相同或不同，为氢原子，可被氧，硫或含氧或含硅单元中断的碳原子数为1〜16的烃基， 具有1至6个碳原子的取代烃基，甲硅烷基或硅氧烷基，R4相同或不同，为氢原子，氯，溴，氟或任选取代的烷基，Z为氧原子或基团 - NR5-，其中R5具有R3给出的含义之一，任选的（C）引发剂，其形成自由基和任选的（D）抑制剂以调节适用期。

公开(公告)号：US06258913B1

公开(公告)日：2001-07-10

申请号：US09341485

申请日：1999-08-13

申请人： Christian Herzig ,  Robert Banfic ,  Reinhard Stallbauer ,  Bernward Deubzer ,  David Heuttner

发明人： Christian Herzig ,  Robert Banfic ,  Reinhard Stallbauer ,  Bernward Deubzer ,  David Heuttner

IPC分类号： C08G7708

CPC分类号： C08G77/50 ,  C08G77/20 ,  C09D183/14 ,  Y10T428/31663 ,  C08L83/00

摘要： The invention relates to novel polymeric organosilicon compounds comprising hydrocarbon radicals with at least one aliphatic carbon-carbon double bond in a terminal position. To produce these compounds, (A) compounds containing at least one aliphatic carbon-carbon double bond per molecule, in a terminal position, are reacted with (B) oligomeric or polymeric organosilicon compounds containing units of the general formula R1R2SiO1/2 and units of the general formula HRSiO and/or HSiO3/2 and possibly units of the general formula R2SiO, where R is a monovalent, possibly substituted, hydrocarbon radical with between 1 and 18 carbon atoms per radical, which is free of aliphatic carbon-carbon double bonds, and R1 is a monovalent hydrocarbon radical with between 1 and 18 carbon atoms per radical which has at least one aliphatic carbon-carbon double bond in a terminal position, subject to the condition that the sum of the units HRSiO and R1R2SiO1/2 on average is greater than 2.0 if (B) contains no HSiO3/2 units, and the number of R1 radicals per molecule is greater than the number of Si-bonded hydrogen atoms, in the presence of (C) catalysts promoting the addition of Si-bonded hydrogen to aliphatic double-bonds. The ratio of aliphatic double bonds in components (A) and (B) to Si-bonded hydrogen in component (B) is between 1.5 and 10, subject to the condition that the polymeric organosilicon compounds on average contain more than two hydrocarbon radicals with at least one aliphatic carbon-carbon double bond in a terminal position.

摘要翻译： 本发明涉及包含在最终位置具有至少一个脂族碳 - 碳双键的烃基的新型聚合物有机硅化合物。 为了制备这些化合物，（A）在每个分子中含有至少一个脂族碳 - 碳双键的化合物在末端与（B）含有通式R 1 R 2 SiO 1/2单元的低聚或聚合有机硅化合物反应， 通式HRSiO和/或HSiO3 / 2以及通式R2SiO的可能单元，其中R是每个基团具有1至18个碳原子的单价可能取代的烃基，其不含脂族碳 - 碳双键 并且R 1是每个基团具有1至18个碳原子的单价烃基，其在末端具有至少一个脂族碳 - 碳双键，条件是平均来说单位HRSiO和R 1 R 2 SiO 1/2的总和 如果（B）不含有HSiO3 / 2单元，并且在（C）催化剂的存在下，每分子的R1基团数目大于Si键合的氢原子的数目，则大于2.0，促进添加 硅键键合到脂肪族双键。 组分（B）中组分（A）和（B）中的脂族双键与Si键合的氢的比例为1.5至10，条件是聚合物有机硅化合物平均含有多于两个烃基， 在末端位置具有至少一个脂族碳 - 碳双键。

公开(公告)号：US5994490A

公开(公告)日：1999-11-30

申请号：US67871

申请日：1998-04-28

申请人： Bernward Deubzer ,  Christian Herzig

发明人： Bernward Deubzer ,  Christian Herzig

IPC分类号： B01J27/16 ,  C07B61/00 ,  C07C31/02 ,  C07C33/18 ,  C07C35/00 ,  C07F7/08 ,  C07F7/18 ,  C07F9/06 ,  C07F9/26 ,  C08G77/06 ,  C08G77/08 ,  C08G77/10 ,  C08G79/025

CPC分类号： C07F9/067 ,  C08G77/08 ,  C08G77/10 ,  C08G79/025

摘要： Compositions obtained by mixing oxygen-containing phosphazenes with tertiary alcohols at a temperature of from 0.degree. C. to 70.degree. C. and a pressure of from 900 to 1100 hPa are useful in processes for equilibrating and/or condensing organosilicon compounds.

摘要翻译： 在0℃至70℃的温度和900至1100hPa的压力下将含氧磷腈与叔醇混合获得的组合物可用于平衡和/或冷凝有机硅化合物的方法。

公开(公告)号：US5691435A

公开(公告)日：1997-11-25

申请号：US782871

申请日：1997-01-14

申请人： Christian Herzig ,  Bernward Deubzer ,  Martina Bloechl ,  Robert Banfic

发明人： Christian Herzig ,  Bernward Deubzer ,  Martina Bloechl ,  Robert Banfic

IPC分类号： C08L83/05 ,  C07F7/08 ,  C08G77/12 ,  C08G77/48 ,  C08K5/5419 ,  C08L83/07 ,  C09D183/04 ,  C09D183/05 ,  C09D183/07 ,  C09J183/07 ,  C08G77/08

CPC分类号： C08K5/5419 ,  C07F7/0896 ,  C08G77/12 ,  C08G77/485 ,  C09D183/04

摘要： The present invention provides crosslinkable compositions comprising (A) an organosilicon compound having radicals containing aliphatic carbon-carbon multiple bonds, (B) an organosilicon compound having Si-bonded hydrogen atoms, (C) a catalyst which promotes the addition of Si-bonded hydrogen onto aliphatic multiple bond, and optionally (D) an agent which retards the addition of Si-bonded hydrogen onto aliphatic multiple bond at room temperature and to the use of the crosslinkable compositions for producing coatings which repel tacky substances. The present invention also relates to organosilicon compounds having Si-bonded hydrogen atoms, and to a process for their preparation.

摘要翻译： 本发明提供可交联组合物，其包含（A）具有含有脂族碳 - 碳多重键的基团的有机硅化合物，（B）具有Si键合氢原子的有机硅化合物，（C）促进加入Si键合氢的催化剂 和任选的（D）在室温下将Si键合的氢加成到脂肪族多键上的试剂，以及使用可交联组合物来制造排斥粘性物质的涂层。 本发明还涉及具有Si键合的氢原子的有机硅化合物及其制备方法。

公开(公告)号：US5446119A

公开(公告)日：1995-08-29

申请号：US279382

申请日：1994-07-25

申请人： Christian Herzig ,  Willibald Burger ,  Bernward Deubzer ,  Martina Bloechl

发明人： Christian Herzig ,  Willibald Burger ,  Bernward Deubzer ,  Martina Bloechl

IPC分类号： B01J31/02 ,  B01J31/04 ,  C08G63/68 ,  C08G63/695 ,  C08G77/20 ,  C08G77/38 ,  C08G77/42 ,  C08G77/445 ,  C08G77/46 ,  C08G81/00 ,  C08G77/16

CPC分类号： C08G77/20 ,  C08G77/38 ,  C08G77/46

摘要： Organopolysiloxanes which contain ester groups and comprise units of the formula ##EQU1## in which R may be an identical or different monovalent, SiC-bonded hydrocarbon radical having 1 to 18 carbon atoms,A may be an identical or different radical of the formula ##STR1## in which R.sup.1, R.sup.2, R.sup.3, c, v, w, s, t,is 0 or an integer, the sum of s and tbeing an integer from 1 to 20,x is 0 or 1,y is 0 or 1, the sum of x and y being 1 or 2,a is 0, 1, 2 or 3, andb is 0, 1 or 2,with the proviso that the sum of a and b is less than or equal to 3 and the organopolysiloxane contains at least one radical A per molecule.

摘要翻译： 含有酯基并且包含式（I）的单元的有机聚硅氧烷，其中R可以是具有1至18个碳原子的相同或不同的一价SiC键合烃基，A可以是相同或不同的 式中，R1，R2，R3，c，v，w，s，t为0或整数，s和t之和为1〜20的整数，x为0或1 ，y为0或1，x和y之和为1或2，a为0,1,2或3，b为0,1或2，条件是a和b的和小于 或等于3，有机聚硅氧烷每分子含有至少一个基团A.

公开(公告)号：US06252101B1

公开(公告)日：2001-06-26

申请号：US09261823

申请日：1999-03-03

申请人： Christian Herzig ,  Bernward Deubzer ,  Johann Weis ,  Kamelia Karlou-Eyrisch ,  Oskar Nuyken

发明人： Christian Herzig ,  Bernward Deubzer ,  Johann Weis ,  Kamelia Karlou-Eyrisch ,  Oskar Nuyken

IPC分类号： C07F708

CPC分类号： C08G77/20 ,  C07F7/0838 ,  C08G77/38

摘要： The invention describes new organosilicon compounds containing alkenyl groups, comprising units of the formula A a ⁢ R b ⁡ ( R 1 ⁢ O ) c ⁢ SiO 4 - ( a + b + c ) 2 , ( I ) where R are identical or different and are each a monovalent hydrocarbon radical which is free of aliphatic carbon-carbon multiple bonds, has from 1 to 20 carbon atom(s) per radical and may contain from 1 to 4 oxygen atom(s), R1 are identical or different and are each a monovalent hydrocarbon radical which is free of aliphatic carbon-carbon multiple bonds and has from 1 to 8 carbon atom(s) per radical, a is 0 or 1, b is 0, 1, 2 or 3, c is 0, 1, 2 or 3, preferably 0, where the sum a+b+c≦3, A is a radical of the formula —(R2)d—Y(—CH═CHR3)2 where R2 is a divalent hydrocarbon radical which is free of aliphatic carbon-carbon multiple bonds and has from 1 to 6 carbon atom(s), R3 are identical or different and are each a hydrogen atom or are as defined for R, Y is a trivalent hydrocarbon radical which has from 2 to 20 carbon atoms and may contain from 1 to 4 oxygen atom(s) and d is 0 or 1, with the proviso that the organosilicon compounds have at least two units of the formula (I) and at least one radical A per molecule.

摘要翻译： 本发明描述了含有烯基的新的有机硅化合物，其包含式R的单元相同或不同，并且各自为不含脂族碳 - 碳多键的单价烃基，每个基团具有1-20个碳原子 并且可以含有1至4个氧原子，R 1相同或不同，并且各自为不含脂族碳 - 碳多重键并且每个基团具有1至8个碳原子的单价烃基， 是0或1，b为0,1,2或3，c为0,1,2或3，优选为0，其中和a + b + c = 3，A为式R 2的基团为 不含脂族碳 - 碳多重键且具有1至6个碳原子的二价烃基，R 3相同或不同，各自为氢原子或如对R所定义，Y为三价烃基，其中 具有2至20个碳原子并且可以含有1至4个氧原子，d为0或1，条件是 有机硅化合物具有至少两个式（I）单元和每个分子至少一个基团A.

公开(公告)号：US5693734A

公开(公告)日：1997-12-02

申请号：US495009

申请日：1995-06-27

申请人： Christian Herzig ,  Bernward Deubzer ,  Martina Bloechl ,  Inge Seeger-Feichtinger

发明人： Christian Herzig ,  Bernward Deubzer ,  Martina Bloechl ,  Inge Seeger-Feichtinger

IPC分类号： C07F7/04 ,  C07F7/08 ,  C07F7/18 ,  C08G77/14 ,  C08G77/22 ,  C08G77/38 ,  C08L83/04 ,  C09D183/00 ,  C09D183/04 ,  C09D183/06 ,  C08G77/04

CPC分类号： C08G77/38 ,  C07F7/0852 ,  C09D183/06

摘要： Organosilicon compounds containing furanyl groups which contain units of the formula ##EQU1## in which R is identical or different and is a hydrogen atom or monovalent, SiC-bonded, aliphatically saturated, optionally substituted hydrocarbon radical, which can be interrupted by oxygen atoms, R.sup.1 is identical or different and is an optionally substituted hydrocarbon radical having 1 to 8 carbon atoms, which can be interrupted by 1 to 3 oxygen atoms. A is identical or different and is an SiC-bonded furanyl radical of the formula ##STR1## where R.sup.2 has the meaning given above for the radical R and R.sup.3 is a divalent hydrocarbon radical having 2 to 30 carbon atoms, which can contain one or more groups, chosen from the group consisting of ##STR2## a is 0, 1, 2 or 3, b is 0, 1 or 2 and c is 0, 1 or 2, with the proviso that the sum a+b+c is less than or equal to 3 and the organosilicon compound contains at least one radical A per molecule.

摘要翻译： 含有呋喃基的有机硅化合物，其含有式（I）的单元，其中R相同或不同，并且是氢原子或可被氧中断的一价，SiC键合，脂族饱和，任选取代的烃基 原子，R 1相同或不同，并且是可以被1至3个氧原子间隔的具有1至8个碳原子的任选取代的烃基。 A是相同或不同的，并且是具有下式（II）的SiC键合的呋喃基，其中R2具有上述对于基团R的含义，且R 3是具有2至30个碳原子的二价烃基，其可以含有 选自由 a组成的组中的一个或多个基团是0,1,2或3，b是0,1或2，c是0,1或2，条件是和a + b + c小于或等于3，有机硅化合物每分子含有至少一个基团A.

公开(公告)号：US5525696A

公开(公告)日：1996-06-11

申请号：US327739

申请日：1994-10-24

申请人： Christian Herzig ,  Bernward Deubzer ,  Inge Seeger-Feichtinger

发明人： Christian Herzig ,  Bernward Deubzer ,  Inge Seeger-Feichtinger

IPC分类号： C08L83/04 ,  C08L83/05 ,  C08L83/07 ,  C09D183/04 ,  C09J183/00 ,  C09J183/05 ,  C09J183/07 ,  C08G77/08

CPC分类号： C08L83/04 ,  C09D183/04 ,  C08G77/12 ,  C08G77/20

摘要： Compositions which comprise(A) a polymeric organosilicon compound having 1 to 6 Si-bonded hydrogen atoms per molecule,(B) a polymeric organosilicon compound having at least two alkenyl groups per molecule and a viscosity of not more than 100 mm.sup.2 /s,(C) a polymeric organosilicon compound having on average at least 10 Si-bonded hydrogen atoms per molecule,(D) a catalyst and, optionally(E) an inhibitor,with the proviso thatthe molar ratio of all the Si-bonded hydrogen atoms to all the SiC-bonded alkenyl groups in the composition is on average less than 1,the composition comprises (B) in an amount such that the composition comprises on average at least 1.1 alkenyl radicals of (B) per Si-bonded hydrogen atom of (A)and the content of Si-bonded hydrogen atoms of (C) is 5% to 50%, based on the number of all the Si-bonded hydrogen atoms present.

摘要翻译： 包含（A）每分子具有1至6个Si键合的氢原子的聚合物有机硅化合物的组合物，（B）每分子具有至少两个烯基并且粘度不超过100mm 2 / s的聚合物有机硅化合物（ C）每分子平均具有至少10个Si键合氢原子的聚合物有机硅化合物，（D）催化剂和任选的（E）抑制剂，条件是所有Si键合的氢原子与 组合物中所有SiC键合的烯基平均小于1，组合物包含（B），其量使得组合物平均包含（B）的至少1.1个烯基（每个Si键合的氢原子的（B））（ A），（C）的Si键合氢原子的含量相对于存在的所有Si键合氢原子的数量为5〜50％。