摘要:
The method of the invention includes making dimethyinaphthalenes by first contacting, in an alkylation zone, at alkylation conditions, a toluene-containing stream with a pentene-containing stream in the presence of an acid alkylation catalyst. At least a portion of the toluene and pentenes react to form pentyltoluenes. At least a portion of the pentyltoluenes is then contacting in a reforming zone with reforming catalyst, at reforming conditions. At least a portion of the pentyltoluenes is converted to dimethylnaphthalenes.
摘要:
A process for making a lube base stock wherein an olefinic feedstock is separated into a light olefin fraction and a medium olefin fraction. The light olefin fraction is contacted with a first oligomerization catalyst in a first oligomerization zone to produce a first product. Both the medium olefin fraction and the first product are contacted with a second oligomerization catalyst in a second oligomerization zone to produce a second product. The second product is separated into a light byproduct fraction and a heavy product fraction that includes hydrocarbons in the lube base stock range.
摘要:
A process for making a lube base stock wherein a highly paraffinic feedstock (with boiling points within the range of from 258° to 1100° F.) is dehydrogenated to produce an olefinic feedstock, which is oligomerized to produce an oligomerized product, which is separated into a lighter fraction and a heavier fraction. That heavier fraction has a flash point within the lube base oil range.
摘要:
A process for making a lube base stock wherein a highly paraffinic feedstock is dehydrogenated to produce an olefinic feedstock. That olefinic feedstock is contacted with an oligomerization catalyst in an oligomerization zone to produce a product having a higher number average molecular weight than the olefinic feedstock. The product is separated into a light byproduct fraction and a heavy product fraction. The heavy product fraction comprises a lube base stock.
摘要:
A process for alkylating an aromatic compound comprising reacting at least one aromatic compound with a mixture of olefins selected from olefins having from about 8 to about 100 carbon atoms, in the presence of an acidic ionic liquid catalyst, wherein the resulting product comprises at least about 50 weight percent of a 1, 2, 4 tri-substituted aromatic compound or a 1, 2, 3 tri-substituted aromatic compound or mixtures thereof.
摘要:
A process for regenerating a spent ionic liquid catalyst including (a) applying a voltage across one or more pairs of electrodes immersed in a spent ionic liquid catalyst comprising conjunct polymer-metal halide complexes to provide freed conjunct polymers and a regenerated ionic liquid catalyst; and (b) separating the freed conjunct polymers from the regenerated ionic liquid catalyst is described. An alkylation process incorporating the regeneration process is also described.
摘要:
Methods and compositions for stabilizing the activity of catalytic compositions during catalytic processes, such as alkylation. A catalytic composition comprising a partially deactivated ionic liquid catalyst may be regenerated by reaction with a metal to form reactivated catalyst and an inorganic catalyst precursor; and the catalytic composition may be amended in-process by addition of an organic catalyst precursor for reaction with the inorganic catalyst precursor to form fresh ionic liquid catalyst. The organic catalyst precursor may be protected from water, e.g., during handling, by hydrophobic material(s).
摘要:
A process for regenerating a used acidic catalyst which has been deactivated by conjunct polymers by removing the conjunct polymers so as to increase the activity of the catalyst is disclosed. Methods for removing the conjunct polymers include hydrogenation, addition of a basic reagent and alkylation. The methods are applicable to all acidic catalysts and are described with reference to certain ionic liquid catalysts.
摘要:
A process for regenerating a used acidic ionic liquid catalyst comprising contacting the used ionic liquid catalyst with an isoparaffin-containing stream and Broensted acid in a reaction zone under alkylation conditions for a time sufficient to increase the activity of the ionic liquid catalyst is disclosed.
摘要:
A process for regenerating a used acidic ionic liquid catalyst comprising contacting the used ionic liquid catalyst with at least one metal in a regeneration zone in the absence of added hydrogen under regeneration conditions for a time sufficient to increase the activity of the ionic liquid catalyst is described. In one embodiment, regeneration is conducted in the presence of a hydrocarbon solvent.