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    HYBRID POLYOLS
    2.
    发明申请
    HYBRID POLYOLS 审中-公开
    混合聚合物

    公开(公告)号：US20160108166A1

    公开(公告)日：2016-04-21

    申请号：US14893214

    申请日：2014-05-08

    Applicant: ROHM AND HAAS COMPANY ,  DOW GLOBAL TECHNOLOGIES LLC

    Inventor： Joseph J. Zupancic ,  William H. Heath ,  Jorge Jimenez ,  Amira A. Marine ,  Pavel L. Shutov ,  David E. Vietti

    IPC: C08G18/48 ,  C08G18/72

    CPC classification number: C08G18/4879 ,  C08G18/10 ,  C08G18/4261 ,  C08G18/4866 ,  C08G18/4887 ,  C08G18/72 ,  C09J175/04 ,  C08G18/7657 ,  C08G18/73

    Abstract: Provided is a two-component composition comprising one or more polyisocyanate and one or more hybrid polyol comprising reaction residues of (i). one initiator polyol having N hydroxyl groups, wherein N is 2 or greater, and wherein the number-average molecular weight of said initiator polyol is 900 or lower, (ii). one or more anhydride, and (iii). two or more alkylene oxides having the structure wherein said R3 is hydrogen or an alkyl group, wherein the mole ratio of said reaction residues of anhydride to said reaction residues of initiator polyol is N:1 or less; and wherein the mole ratio of said reaction residues (iii) to said reaction residues of initiator polyol is 20:1 or less wherein at least one said reaction residue of an anhydride is attached directly to one of said reaction residues of a higher-alkylene oxide.

    Abstract translation: 提供了包含一种或多种多异氰酸酯和一种或多种包含（i）的反应残基的杂化多元醇的双组分组合物。 一种具有N个羟基的引发剂多元醇，其中N为2或更大，并且其中所述引发剂多元醇的数均分子量为900或更低，（ii）。 一种或多种酸酐，和（ⅲ）。 两个或多个具有其中所述R 3为氢或烷基的结构的环氧烷烃，其中酸酐与引发剂多元醇的所述反应残余物的摩尔比为N：1或更小; 并且其中所述反应残余物（iii）与所述引发剂多元醇的所述反应残基的摩尔比为20:1或更低，其中至少一个所述酸酐的所述反应残基直接连接在所述高级环氧烷的所述反应残基之一 。

    SINGLE-POT PROCESS FOR THE PRODUCTION OF POLYESTER-CO-CARBONATE POLYOLS
    9.
    发明申请
    SINGLE-POT PROCESS FOR THE PRODUCTION OF POLYESTER-CO-CARBONATE POLYOLS 有权
    用于生产聚碳酸酯多元醇的单一工艺

    公开(公告)号：US20150018512A1

    公开(公告)日：2015-01-15

    申请号：US14373955

    申请日：2013-02-04

    Applicant: Dow Global Technologies LLC

    Inventor： William H. Heath ,  Harpreet Singh ,  Amarnath Singh ,  Jorge Jimenez ,  Qiuyun Xu

    IPC: C08G64/30

    CPC classification number: C08G64/305 ,  C08G63/64

    Abstract: Polyester-co-carbonate polyols and methods for producing the same are provided. The method comprises reacting one or more alcohols having an OH functionality of two or more with one or more organic diacids to form a reaction mixture, adding a first amount of dialkyl carbonate to the reaction mixture to remove water remaining from the reaction mixture by azeotropic drying, adding a transesterification catalyst to the dialkyl carbonate containing reaction mixture and adding a second amount of dialkyl carbonate to the catalyst containing reaction mixture.

    Abstract translation: 提供了聚酯 - 碳酸酯多元醇及其制备方法。 该方法包括将一种或多种具有两个或多个OH官能团的醇与一种或多种有机二酸反应以形成反应混合物，向反应混合物中加入第一量的碳酸二烷基酯以通过共沸干燥除去残留在反应混合物中的水 向含碳酸二烷基酯的反应混合物中加入酯交换催化剂，并向含催化剂的反应混合物中加入第二量的碳酸二烷基酯。

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